US4355148A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Norbornene polymers containing bound phenolic antioxidant
Assignee: Goodrich Corp
•
Filing: 1980-09-18
•
Granted: 1982-10-19
•
Expires: 2000-09-18
Abstract
Abstract A polymeric composition of matter formed by ring opening polymerization using a metathesis catalyst comprising bound antioxidant which is a reaction product of a norbornene-type monomer and a norbornenyl phenolic antioxidant.
Inventors
- 👤 Robert W. Layer
- 👤 Linwood P. Tenney
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 04:40
CPC Classifications
C; C08; C08L; C08L65/00; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
161 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization using a metathesis catalyst of a norbornene-type monomer and 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers of a norbornenyl phenolic antioxidant defined as follows: ##STR6## where R 1 , R 2 , and R 3 are individually selected from hydrogen and alkyl groups of 1 and 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 6 is selcted from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, alkyl and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product.
Claim 2
Dependent Claim
161 words
A polymeric composition of matter comprising a reaction product obtained by ring opening polymerization using a metathesis catalyst of a norbornene-type monomer and 0.05 to 10 parts by weight per 100 parts of said norbornene-type monomers of a norbornenyl phenolic antioxidant defined as follows: ##STR6## where R 1 , R 2 , and R 3 are individually selected from hydrogen and alkyl groups of 1 and 3 carbon atoms; R 4 is selected from hydrogen, alkyl groups containing 1 to 12 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 5 is selected from alkyl groups of 1 to 6 carbon atoms, and alicyclic groups of 4 to 8 carbon atoms; R 6 is selcted from alkylene and alkenylene groups containing 1 to 8 carbon atoms; and R 7 is selected from hydrogen, alkyl and alkenyl groups of 1 to 8 carbon atoms, amount of said norbornenyl phenolic being sufficient to improve antioxidant properties of said reaction product.
Claim 3
Dependent Claim
76 words
Composition of claim 1 wherein R 1 , R 2 and R 3 are individually selected from hydrogen and methyl groups, R 4 is selected from alkyl groups of 1 to 6 carbon atoms, R 5 is selected from alkyl groups of 1 to 6 carbon atoms, R 6 is selected from alkylene and alkenylene groups of 1 to 4 carbon atoms, and R 7 is selected from alkyl groups of 1 to 4 carbon atoms.
Claim 4
Dependent Claim
25 words
Composition of claim 2 wherein said norbornene type monomers are selected from norbornenes, dicyclopentadienes, dihydrodicyclopentadienes, tetracyclododecenes and symmetrical and unsymmetrical trimers and tetramers of cyclopentadiene.
Claim 5
Dependent Claim
27 words
Composition of claim 3 wherein said norbornene-type monomers are selected from substituted and unsubstituted monomers, wherein said substituents are selected from ester, nitrile, phenyl, and halogen groups.
Claim 6
Dependent Claim
17 words
Composition of claim 2 wherein R 4 is in the open ortho position to the hydroxyl group.
References Cited (Backward Citations)
US4017669A
Cited
US3974092A
Cited
US3962187A
Cited
US4022954A
Cited
US4010140A
Cited
US4129557A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-18 | 1986-04-19 | 1986-10-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-18 | 1990-04-19 | 1990-10-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-18 | 1994-04-19 | 1994-10-19 | $7700.00 | Window Closed / Lapsed |