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Patent US4351811A successfully refreshed from Google Patents.
US4351811A
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Process for reducing an eliminating nitrogen oxides in an exhaust gas
Assignee: Hitachi Ltd
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Filing: 1978-07-19
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Granted: 1982-09-28
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Expires: 1998-07-19
Abstract
Abstract The concentrations of NO and NO2 in nitrogen oxides contained in an exhaust gas are adjusted to substantially equal mol concentrations, whereupon the exhaust gas is held in contact with a metallic oxide catalyst together with ammonia. Owing to the adjustment of the NO and NO2 concentrations in the nitrogen oxides, the reaction rate is enhanced, and the nitrogen oxides are reduced even at a low temperature. The adjustment of the concentrations of NO and NO2 in the nitrogen oxides is done by the oxidation of NO with ozone, the catalytic oxidation of NO with air or oxygen, the addition of nitric acid, the addition of NO or NO2, etc.
Inventors
- 👤 Shinpei Matsuda
- 👤 Akira Kato
- 👤 Shigeo Uno
- 👤 Youichi Sakuta
- 👤 Fumito Nakajima
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 10:03
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
162 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas containing nitrogen oxides, comprising the steps of: (a) adjusting the mol ratio of NO to NO 2 in the exhaust gas such that the exhaust gas contains approximately equal molar amounts of NO and NO 2 , (b) mixing the exhaust gas having the adjusted mol ratio of NO to NO 2 with an ammonia-containing gas, in which the mol ratio of ammonia to the total of NO and NO 2 in the exhaust gas is about 0.8 to 2:1, and (c) contacting the resultant mixture with a metallic oxide catalyst at a temperature in the range of 100°-550° C., thereby to reduce nitrogen oxides into nitrogen gas and water, said metallic oxide catalyst containing titanium oxide as its first constituent and an oxide of at least one element selected from the group consisting of iron, copper, nickel, cobalt, molybdenum, tungsten, vanadium, chromium and cerium as its active component.
Claim 2
Dependent Claim
162 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas containing nitrogen oxides, comprising the steps of: (a) adjusting the mol ratio of NO to NO 2 in the exhaust gas such that the exhaust gas contains approximately equal molar amounts of NO and NO 2 , (b) mixing the exhaust gas having the adjusted mol ratio of NO to NO 2 with an ammonia-containing gas, in which the mol ratio of ammonia to the total of NO and NO 2 in the exhaust gas is about 0.8 to 2:1, and (c) contacting the resultant mixture with a metallic oxide catalyst at a temperature in the range of 100°-550° C., thereby to reduce nitrogen oxides into nitrogen gas and water, said metallic oxide catalyst containing titanium oxide as its first constituent and an oxide of at least one element selected from the group consisting of iron, copper, nickel, cobalt, molybdenum, tungsten, vanadium, chromium and cerium as its active component.
Claim 3
Dependent Claim
93 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1, wherein the molar ratio of NO to NO 2 originally in said exhaust gas is greater than 1, and wherein, in adjusting the mol ratio of NO to NO 2 , ozone is added to the exhaust gas, whereby said ozone oxidizes the NO to NO 2 , the ozone being added in an amount such that the mol ratio of the ozone to the NO in the exhaust gas is about 0.4 to 1:1.
Claim 4
Dependent Claim
34 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 2, wherein the mol ratio of ozone to NO in the exhaust gas is 0.4 to 0.6:1.
Claim 5
Dependent Claim
71 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1, wherein the mol ratio of NO to NO 2 originally in the exhaust gas is greater than 1 and wherein, in adjusting the mol ratio of NO to NO 2 , oxygen is added to the exhaust gas in the presence of an oxidizing catalyst, whereby NO is oxidized to NO 2 .
Claim 6
Dependent Claim
69 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1, wherein the mol ratio of NO to NO 2 originally in the exhaust gas is greater than 1 and wherein, in adjusting the mol ratio of NO to NO 2 , nitric acid is added to the exhaust gas, whereby NO in the exhaust gas is oxidized to NO 2 .
Claim 7
Dependent Claim
46 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 5, wherein nitric acid is added to the exhaust gas in an amount such that the mol ratio of the nitric acid to NO is about 0.2 to 1:1.
Claim 8
Dependent Claim
35 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 6, wherein the mol ratio of nitric acid added to the exhaust to NO is 0.4 to 0.6:1.
Claim 9
Dependent Claim
218 words
A process for reducing the concentration of nitrogen oxides, containing nitric oxide as a great portion thereof, in an exhaust gas, comprising the steps of: (a) separating the exhaust gas into two streams, (b) adding oxygen to one of the streams in the presence of an oxidizing catalyst, whereby NO in said one of the streams is oxidized to NO 2 , (c) combining said one of the streams with the other, a sufficient amount of the NO in said one of the streams having been oxidized to NO 2 to adjust the mol ratio of NO to NO 2 such that the combined gas streams contain approximately equal amounts of NO and NO 2 ; (d) mixing the combined streams with an ammonia-containing gas, in which the molar ratio of the ammonia to the total of NO and NO 2 in the combined streams is about 0.8 to 2:1 and (e) contacting the resultant mixture with a metallic oxide catalyst at a temperature of 100° to 550° C., thereby to reduce nitrogen oxides into nitrogen gas and water, said metallic oxide catalyst containing titanium oxide as its first constituent and an oxide of at least one element selected from the group consisting of iron, copper, nickel, cobalt, molybdenum, tungsten, vanadium, chromium and cerium as its active component.
Claim 10
Dependent Claim
218 words
A process for reducing the concentration of nitrogen oxides, containing nitric oxide as a great portion thereof, in an exhaust gas, comprising the steps of: (a) separating the exhaust gas into two streams, (b) adding oxygen to one of the streams in the presence of an oxidizing catalyst, whereby NO in said one of the streams is oxidized to NO 2 , (c) combining said one of the streams with the other, a sufficient amount of the NO in said one of the streams having been oxidized to NO 2 to adjust the mol ratio of NO to NO 2 such that the combined gas streams contain approximately equal amounts of NO and NO 2 ; (d) mixing the combined streams with an ammonia-containing gas, in which the molar ratio of the ammonia to the total of NO and NO 2 in the combined streams is about 0.8 to 2:1 and (e) contacting the resultant mixture with a metallic oxide catalyst at a temperature of 100° to 550° C., thereby to reduce nitrogen oxides into nitrogen gas and water, said metallic oxide catalyst containing titanium oxide as its first constituent and an oxide of at least one element selected from the group consisting of iron, copper, nickel, cobalt, molybdenum, tungsten, vanadium, chromium and cerium as its active component.
Claim 11
Dependent Claim
54 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1, 2, 4, 6 or 8, wherein the mol ratio of NO to NO 2 is adjusted such that the mol ratio of NO to the sum of NO and NO 2 is about 0.4 to 0.6:1.
Claim 12
Dependent Claim
52 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 4 or 8, wherein said oxidizing catalyst comprises at least one selected from the group consisting of MnO 2 --TiO 2 , MnO 2 --Fe 2 O 3 , Pt--TiO 2 and CoO--TiO 2 .
Claim 13
Dependent Claim
37 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1 or 8, wherein the resultant mixture is contacted with said metallic oxide catalyst at a temperature of 150°-350° C.
Claim 14
Dependent Claim
40 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claims 4 or 8, wherein the NO is oxidized in the presence of the oxidizing catalyst at a temperature of 100° to 350° C.
Claim 15
Dependent Claim
38 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claim 1 or 8, wherein the mol ratio of ammonia to the total of NO and NO 2 is 0.8 to 1.2:1.
Claim 16
Dependent Claim
175 words
A process for reducing the concentration of nitrogen oxides, containing nitric oxide as a great portion thereof, in an exhaust gas comprising the steps of: (a) adding ozone to the exhaust gas, the molar ratio of the ozone added to the nitric oxide in the exhaust gas being 0.4 to 0.6:1, whereby NO is oxidized to NO 2 so as to adjust the mol ratio of NO to NO 2 in the exhaust gas such that the exhaust gas contains approximately equal amounts of NO and NO 2 , (b) mixing ammonia gas with the exhaust gas containing approximately equal amounts of NO and NO 2 , the amount of ammonia mixed with the exhaust gas being such that the mol ratio of the ammonia to the total of NO and NO 2 in the exhaust gas is 0.8 to 1.2:1, and (c) contacting the resultant mixture with a metallic oxide catalyst comprising TiO 2 --V 2 O 5 at a temperature of 200° C., thereby to reduce nitrogen oxides into nitrogen gas and water.
Claim 17
Dependent Claim
175 words
A process for reducing the concentration of nitrogen oxides, containing nitric oxide as a great portion thereof, in an exhaust gas comprising the steps of: (a) adding ozone to the exhaust gas, the molar ratio of the ozone added to the nitric oxide in the exhaust gas being 0.4 to 0.6:1, whereby NO is oxidized to NO 2 so as to adjust the mol ratio of NO to NO 2 in the exhaust gas such that the exhaust gas contains approximately equal amounts of NO and NO 2 , (b) mixing ammonia gas with the exhaust gas containing approximately equal amounts of NO and NO 2 , the amount of ammonia mixed with the exhaust gas being such that the mol ratio of the ammonia to the total of NO and NO 2 in the exhaust gas is 0.8 to 1.2:1, and (c) contacting the resultant mixture with a metallic oxide catalyst comprising TiO 2 --V 2 O 5 at a temperature of 200° C., thereby to reduce nitrogen oxides into nitrogen gas and water.
Claim 18
Dependent Claim
44 words
A process for reducing the concentration of nitrogen oxides in an exhaust gas as defined in claims 2, 4, 5, 8 or 14, wherein the mol ratio of NO 2 to NO originally in the exhaust gas is equal to or less than 0.1:1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |