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Electrophotographic element containing disazo compounds

Assignee: Ricoh Co Ltd
•
Filing: 1979-12-04
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Granted: 1982-09-07
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Expires: 1999-12-04
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Abstract

Abstract The present invention provides an electrophotographic element which comprises a charge generating layer and a charge transport layer formed, in order, on an electroconductive substrate, said charge generating layer comprising a disazo pigment expressed by the general formula: ##STR1## [wherein A represents ##STR2## represents a member selected from the group consisting of benzene ring, naphthalene ring, indole ring, carbazole ring, benzofuran ring and their substitutes; Ar 1 represents a member selected from the group consisting of benzene ring, naphthalene ring, dibenzofuran ring, carbazole ring and their substitutes; each of Ar 2 and Ar 3 represents a member selected from the group consisting of benzene ring, naphthalene ring and their substitutes; each of R 1 and R 3 represents a member selected from the group consisting of hydrogen, lower alkyl radical, phenyl radical and their substitutes; and R 2 represents a member selected from the group consisting of lower alkyl radical, carboxyl radical and alkyl ester thereof)] and a mixture of binder materials comprising polyvinyl butyral and acrylic resin.

Inventors

  • 👤 Akio Kozima
  • 👤 Eiichi Akutsu
  • 👤 Kiyomi Ichizuka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:58
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0664; G03G5/0675; G03G5/0679; G03G5/0683

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 270 words
An electrophotographic element comprising an electroconductive substrate, a charge generating layer and a charge transport layer, said charge generating layer comprising a disazo pigment having the general formula: ##STR8## wherein A is a member selected from the group consisting of ##STR9## is a fused ring selected from the group consisting of benzene ring, halobenzene ring, naphthalene ring, indole ring, carbazole ring and benzofuran ring; Ar 1 is a member selected from the group consisting of phenyl, methylphenyl, methoxyphenyl, chlorophenyl, nitrophenyl, ethoxyphenyl, methylchlorophenyl, dimethylphenyl, methoxychlorophenyl, methoxybromophenyl, methoxymethylphenyl, dimethoxyphenyl, dimethoxychlorophenyl, dimethylaminophenyl, cyanophenyl, carboxyphenyl, benzenesulfonic acid sodium salt, tert-butoxyphenyl, naphthyl, methoxydibenzofuryl and carbazolyl; each of Ar 2 and Ar 3 is a member selected from the group consisting of phenyl, naphthyl, methoxyphenyl, methylphenyl, acetylaminophenyl, dimethylaminophenyl, cyanophenyl, nitrophenyl, dinitrophenyl, chlorophenyl, trichlorobenzenesulfonic acid, benzenesulfonic acid and benzenesulfonamide; each of R 1 and R 3 is a member selected from the group consisting of hydrogen, methyl, ethyl, phenyl and chlorophenyl; and R 2 is a member selected from the group consisting of methyl, carboxyl and --COOC 2 H 5 , and a binder material consisting essentially of a mixture of polyvinyl butyral and acrylic resin, wherein the weight ratio of polyvinyl butyral to acrylic resin in said mixture is in the range of from 0.1:1 to 1:0.1, the amount of said mixture is 10 to 200% by weight, based on the weight of said disazo pigment, the thickness of said charge generating layer is in the range of from about 0.05 micron to about 2 microns and the thickness of said charge transport layer is in the range of about 5 microns to about 100 microns.
Claim 2
Dependent Claim 270 words
An electrophotographic element comprising an electroconductive substrate, a charge generating layer and a charge transport layer, said charge generating layer comprising a disazo pigment having the general formula: ##STR8## wherein A is a member selected from the group consisting of ##STR9## is a fused ring selected from the group consisting of benzene ring, halobenzene ring, naphthalene ring, indole ring, carbazole ring and benzofuran ring; Ar 1 is a member selected from the group consisting of phenyl, methylphenyl, methoxyphenyl, chlorophenyl, nitrophenyl, ethoxyphenyl, methylchlorophenyl, dimethylphenyl, methoxychlorophenyl, methoxybromophenyl, methoxymethylphenyl, dimethoxyphenyl, dimethoxychlorophenyl, dimethylaminophenyl, cyanophenyl, carboxyphenyl, benzenesulfonic acid sodium salt, tert-butoxyphenyl, naphthyl, methoxydibenzofuryl and carbazolyl; each of Ar 2 and Ar 3 is a member selected from the group consisting of phenyl, naphthyl, methoxyphenyl, methylphenyl, acetylaminophenyl, dimethylaminophenyl, cyanophenyl, nitrophenyl, dinitrophenyl, chlorophenyl, trichlorobenzenesulfonic acid, benzenesulfonic acid and benzenesulfonamide; each of R 1 and R 3 is a member selected from the group consisting of hydrogen, methyl, ethyl, phenyl and chlorophenyl; and R 2 is a member selected from the group consisting of methyl, carboxyl and --COOC 2 H 5 , and a binder material consisting essentially of a mixture of polyvinyl butyral and acrylic resin, wherein the weight ratio of polyvinyl butyral to acrylic resin in said mixture is in the range of from 0.1:1 to 1:0.1, the amount of said mixture is 10 to 200% by weight, based on the weight of said disazo pigment, the thickness of said charge generating layer is in the range of from about 0.05 micron to about 2 microns and the thickness of said charge transport layer is in the range of about 5 microns to about 100 microns.
Claim 3
Dependent Claim 27 words
An electrophotographic element according to claim 1, wherein the amount of said mixture is 20 to 100% by weight, based on the weight of said disazo pigment.
Claim 4
Dependent Claim 28 words
An electrophotographic element according to claim 1, wherein the thickness of said charge transport layer is in the range of from about 7 microns to about 25 microns.
Claim 5
Dependent Claim 20 words
An electrophotographic element according to claim 1, wherein said disazo pigment is a compound expressed by the following formula: ##STR10##
Claim 6
Dependent Claim 27 words
An electrophotographic element according to claim 1, wherein said disazo pigment is a member selected from the group of compounds expressed by the following formulas respectively: ##STR11##

References Cited (Backward Citations)

JPS4817354B1 Cited
US4026704A Cited
US3871882A Cited
US3977870A Cited
US3775105A Cited
US3837851A Cited
US4018607A Cited
US4052210A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-06 1986-03-08 1986-09-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-06 1990-03-08 1990-09-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-06 1994-03-08 1994-09-07 $7700.00 Window Closed / Lapsed

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