Patent US4346196A successfully refreshed from Google Patents.
US4346196A
Expired / Lapsed
US
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Heat seal composition comprising a blend of metal neutralized polymers
Assignee: EIDP Inc
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Filing: 1980-09-10
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Granted: 1982-08-24
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Expires: 2000-09-10
Abstract
Abstract Heat seal compositions and articles including the compositions are disclosed. The compositions exhibit a broad temperature range for making heat seals of variable strengths and are useful as the sole heat seal composition in making flexible packages requiring both permanent and peelable seals.
Inventors
- 👤 George L. Hoh
- 👤 Donald A. Vassallo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 07:41
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0846; C08L23/0869; C08L23/0876; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; B; B29; B29C; B29C66/00; B29C66/90; B29C66/91; B29C66/912; B29C66/9121; B29C66/91221; C08L2666/00; C08L2666/02; C08L2666/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
189 words
A substantially homogeneous blend of polymeric materials comprising: (a) 20 to 80 percent, by weight, of a terpolymer having, as monomeric components, (i) 65 to 95 percent, by weight, ethylene, (ii) 4 to 30 percent, by weight, vinyl alkanoate or an ester selected from the group consisting of alkyl acrylate, and alkyl methacrylate wherein the alkanoic acid moiety of the alkanoate and the alkyl group have one to four carbon atoms, and (iii) 0.5 to 20 percent, by weight, ethylenically unsaturated monocarboxylic acid selected from the group consisting of acrylic acid and methacrylic acid; and (b) 20 to 80 percent, by weight, of an ionomer having, as monomeric components, (i) 75 to 99 percent, by weight, ethylene, (ii) 1 to 25 percent, by weight, ethylenically unsaturated monocarboxylic acid selected from the group consisting of acrylic acid and methacrylic acid wherein the sum of the weight percentages of comonomers (ii) and (iii) in the terpolymer is at least eight percentage points higher than the weight percentage of comonomer (ii) in the ionomer and wherein 5 to 40 percent of the carboxylic acid in the blend is neutralized by zinc ions.
Claim 2
Dependent Claim
189 words
A substantially homogeneous blend of polymeric materials comprising: (a) 20 to 80 percent, by weight, of a terpolymer having, as monomeric components, (i) 65 to 95 percent, by weight, ethylene, (ii) 4 to 30 percent, by weight, vinyl alkanoate or an ester selected from the group consisting of alkyl acrylate, and alkyl methacrylate wherein the alkanoic acid moiety of the alkanoate and the alkyl group have one to four carbon atoms, and (iii) 0.5 to 20 percent, by weight, ethylenically unsaturated monocarboxylic acid selected from the group consisting of acrylic acid and methacrylic acid; and (b) 20 to 80 percent, by weight, of an ionomer having, as monomeric components, (i) 75 to 99 percent, by weight, ethylene, (ii) 1 to 25 percent, by weight, ethylenically unsaturated monocarboxylic acid selected from the group consisting of acrylic acid and methacrylic acid wherein the sum of the weight percentages of comonomers (ii) and (iii) in the terpolymer is at least eight percentage points higher than the weight percentage of comonomer (ii) in the ionomer and wherein 5 to 40 percent of the carboxylic acid in the blend is neutralized by zinc ions.
Claim 3
Dependent Claim
21 words
The blend of claim 1 wherein the monomer, (ii), of the terpolymer is a vinyl alkanoate and the alkanoate is acetate.
Claim 4
Dependent Claim
22 words
The blend of claim 1 wherein the monomer, (ii), of the terpolymer is an alkyl acrylate and the alkyl group is isobutyl.
Claim 5
Dependent Claim
30 words
The blend of claim 1 wherein self-supported films of the blend material exhibit a peel seal (118 to 275 grams per centimeter) temperature range of at least 7 Celsius degrees.
Claim 6
Dependent Claim
30 words
The blend of claim 4 wherein self-supported films of the blend material exhibit a tear seal (275 grams per centimeter to tear) temperature range of at least 8 Celsius degrees.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-08-23 | 1986-02-22 | 1986-08-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-08-23 | 1990-02-22 | 1990-08-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-08-23 | 1994-02-22 | 1994-08-24 | $7700.00 | Window Closed / Lapsed |