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US4343606A
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Multi-stage process for combusting fuels containing fixed-nitrogen chemical species
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1980-02-11
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Granted: 1982-08-10
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Expires: 2000-02-11
Abstract
Abstract Fuels containing fixed-nitrogen chemical species are combusted in a multi-stage process. The process which converts substantially all of the fixed-nitrogen into molecular nitrogen (and thus avoids the formation of significant amounts of nitrogen oxides from the fixed-nitrogen) consists of four steps: (a) mixing said fuel with at least one first oxidizing agent in amounts such that the equivalence ratio of said fuel to said oxidizing agent is at least about 1.4; (b) partially combusting the mixture resulting from step (a) in at least one first stage at a first temperature of about 1850 DEG to about 2150 DEG K., with a residence time of at least 0.03 second; (c) mixing the combustion products resulting from step (b) with at least one second oxidizing agent in an amount such that the equivalence ratio of combustion products to the total amount of oxidizing agents in the mixture will be about 1.0 or less, such mixing taking place under conditions such that the temperature of the mixture will not exceed about 1800 DEG K.; and (d) completely combusting the mixture resulting from step (c) in at least one second stage at a second temperature of less than about 1800 DEG K.
Inventors
- 👤 David W. Blair
- 👤 William Bartok
- 👤 John P. Longwell
- 👤 Adel F. Sarofim
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 06:15
CPC Classifications
F; F23; F23C; F23C6/00; F23C6/04
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
176 words
A multi-stage process for combusting a fuel containing fixed-nitrogen chemical species which comprises the steps of: (a) mixing said fuel which is preheated with at least one first oxidizing agent which is preheated in amounts such that the equivalence ratio of said fuel to said oxidizing agent is at least about 1.6; (b) partially combusting the mixture resulting from step (a) in at least one first stage at a first temperature of about 1850° to about 2150° K., with a residence time of at least 0.03 second; (c) mixing the combustion products resulting from step (b) with at least one second oxidizing agent in an amount such that the equivalence ratio of combustion products to the total amount of oxidizing agents in the mixture will be about 1.0 or less, such mixing taking place under nonadiabatic means such that the temperature of the mixture will not exceed about 1800° K.; and (d) completely combusting the mixture resulting from step (c) in at least one second stage at a second temperature of less than about 1800° K.
Claim 2
Dependent Claim
176 words
A multi-stage process for combusting a fuel containing fixed-nitrogen chemical species which comprises the steps of: (a) mixing said fuel which is preheated with at least one first oxidizing agent which is preheated in amounts such that the equivalence ratio of said fuel to said oxidizing agent is at least about 1.6; (b) partially combusting the mixture resulting from step (a) in at least one first stage at a first temperature of about 1850° to about 2150° K., with a residence time of at least 0.03 second; (c) mixing the combustion products resulting from step (b) with at least one second oxidizing agent in an amount such that the equivalence ratio of combustion products to the total amount of oxidizing agents in the mixture will be about 1.0 or less, such mixing taking place under nonadiabatic means such that the temperature of the mixture will not exceed about 1800° K.; and (d) completely combusting the mixture resulting from step (c) in at least one second stage at a second temperature of less than about 1800° K.
Claim 3
Dependent Claim
19 words
The process according to claim 1 wherein the first temperature is in the range of 1900° to 2050° K.
Claim 4
Dependent Claim
15 words
The process according to claim 1 wherein the residence time is at least 0.05 second.
Claim 5
Dependent Claim
27 words
The process according to claim 1 wherein the equivalence ratio of the mixture resulting from step (a) is in the range of about 1.4 to about 2.2.
Claim 6
Dependent Claim
18 words
The process according to claim 4 wherein the equivalence ratio is in the range of 1.6 to 2.0.
Claim 7
Dependent Claim
13 words
The process according to claim 1 wherein the first oxidizing agent is air.
Claim 8
Dependent Claim
24 words
The process according to claim 6 wherein the air is preheated to less than about 1100° K. prior to its admixture with said fuel.
Claim 9
Dependent Claim
18 words
The process according to claim 1 wherein the fuel is a solid, liquid, gas, or a mixture thereof.
Claim 10
Dependent Claim
13 words
The process according to claim 1 wherein the second oxidizing agent is air.
Claim 11
Dependent Claim
19 words
The process according to claim 1 wherein the second temperature is in the range of 1200° to 1800° K.
Claim 12
Dependent Claim
17 words
The process according to claim 1 wherein the residence time is about 0.15 to about 0.25 seconds.
Claim 13
Dependent Claim
24 words
The process according to claim 6 wherein the air is preheated to less than about 900° K. prior to its admixture with said fuel.
Claim 14
Dependent Claim
14 words
The process according to claim 1 wherein said fuel is a liquid or gas.
Claim 15
Dependent Claim
19 words
The process according to claim 1 wherein the second temperature is in the range of 1300° to 1750° K.
Claim 16
Dependent Claim
193 words
A multi-stage process for combusting a fuel containing fixed-nitrogen chemical species in a combustion chamber which comprises the steps of: p1 (a) mixing the fuel with air which has been preheated to a temperature in the range of 450° to 1100° K., the air being present in an amount such that the equivalence ratio of fuel to air is in the range of 1.6 to 2.0; (b) partially combusting the mixture resulting from step (a) in the combustion chamber at a temperature in the range of 1900° to 2050° K. with a residence time of at least 0.05 second; (c) cooling the combustion products resulting from step (b) to a temperature of less than 1600° K.; (d) mixing the cooled combustion products resulting from step (c) with air in an amount such that the equivalence ratio of combustion products to the total amount of air present in the mixture will be less than 1.0; and (e) completely combusting the mixture resulting from step (d) in the same or different combustion chamber as that employed in step (b), such complete combustion taking place at a temperature in the range of 1200° to 1800° K.
Claim 17
Dependent Claim
193 words
A multi-stage process for combusting a fuel containing fixed-nitrogen chemical species in a combustion chamber which comprises the steps of: p1 (a) mixing the fuel with air which has been preheated to a temperature in the range of 450° to 1100° K., the air being present in an amount such that the equivalence ratio of fuel to air is in the range of 1.6 to 2.0; (b) partially combusting the mixture resulting from step (a) in the combustion chamber at a temperature in the range of 1900° to 2050° K. with a residence time of at least 0.05 second; (c) cooling the combustion products resulting from step (b) to a temperature of less than 1600° K.; (d) mixing the cooled combustion products resulting from step (c) with air in an amount such that the equivalence ratio of combustion products to the total amount of air present in the mixture will be less than 1.0; and (e) completely combusting the mixture resulting from step (d) in the same or different combustion chamber as that employed in step (b), such complete combustion taking place at a temperature in the range of 1200° to 1800° K.
Claim 18
Dependent Claim
13 words
The process of claim 15 wherein said fuel is a liquid or gas.
Claim 19
Dependent Claim
16 words
A process according to claim 6 wherein said air is enriched with 6-15 weight percent oxygen.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-08-09 | 1986-02-08 | 1986-08-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-08-09 | 1990-02-08 | 1990-08-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-08-09 | 1994-02-08 | 1994-08-10 | $7700.00 | Window Closed / Lapsed |