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US4337187A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrocoating composition with polyhydroxyamine and polyesters or alkyds

Assignee: EIDP Inc
•
Filing: 1980-12-29
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Granted: 1982-06-29
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Expires: 2000-12-29
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Abstract

Abstract A cationic electrocoating composition containing a polyhydroxyamine and polyesters or alkyds and optionally a crosslinker resin.

Inventors

  • 👤 Isidor Hazan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:46
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/003; C08; C08F; C08F8/00; C08F8/02; C09D133/00; C09D133/04; C09D133/06; C09D133/14; C09D5/00; C09D5/44; C09D5/4407; C09D5/4411; C09D5/4473; C08L; C08L61/00; C08L61/20; C08L63/00; C08L67/00; C08L9/00; Y; Y10; Y10S; Y10S524/00; Y10S524/901

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 233 words
An aqueous cathodic electrodeposition coating composition comprising dispersion of a first polymer, a second polymer, enough of an organic acid to give the composition a pH about in the range of 6 to 7, and optionally a nitrogen resin crosslinker, said coating composition containing, by weight based on the first and second polymers, about 20-70% of a first polymer which is a copolymer comprising a backbone and a graft pendent to the backbone, said backbone containing amine functional groups and hydroxy functional groups, characterized in that said backbone contains at least about 0.13 equivalent of amine groups per 100 grams of first polymer and at least about 0.03 equivalent of hydroxyl groups per 100 grams of first polymer, and containing, by weight, the equivalent of about: (a) 35-90% amine functional monomers, (b) 10-60% hydroxy functional monomers, (c) 0-40% nonfunctional acrylic or methacrylic monomers, and (d) 0-5% chain-terminating monomers the total of (a), (b), (c) and (d) being 100% of said backbone, said graft comprising a monoglycidyl ester of at least one tertiary carboxylic acid containing 9-20 carbon atoms and being grafted to said amine groups in said backbone, said copolymer containing about 1-30% by weight of said graft, and, by weight based on the first and second polymers, about 80-30% of a second polymer which is polyester or alkyd having an acid number of about zero and containing hydroxy functionality or vinyl groups.
Claim 2
Dependent Claim 233 words
An aqueous cathodic electrodeposition coating composition comprising dispersion of a first polymer, a second polymer, enough of an organic acid to give the composition a pH about in the range of 6 to 7, and optionally a nitrogen resin crosslinker, said coating composition containing, by weight based on the first and second polymers, about 20-70% of a first polymer which is a copolymer comprising a backbone and a graft pendent to the backbone, said backbone containing amine functional groups and hydroxy functional groups, characterized in that said backbone contains at least about 0.13 equivalent of amine groups per 100 grams of first polymer and at least about 0.03 equivalent of hydroxyl groups per 100 grams of first polymer, and containing, by weight, the equivalent of about: (a) 35-90% amine functional monomers, (b) 10-60% hydroxy functional monomers, (c) 0-40% nonfunctional acrylic or methacrylic monomers, and (d) 0-5% chain-terminating monomers the total of (a), (b), (c) and (d) being 100% of said backbone, said graft comprising a monoglycidyl ester of at least one tertiary carboxylic acid containing 9-20 carbon atoms and being grafted to said amine groups in said backbone, said copolymer containing about 1-30% by weight of said graft, and, by weight based on the first and second polymers, about 80-30% of a second polymer which is polyester or alkyd having an acid number of about zero and containing hydroxy functionality or vinyl groups.
Claim 3
Dependent Claim 18 words
The composition of claim 1 containing about 35-50% of said first polymer and 50-65% of said second polymer.
Claim 4
Dependent Claim 73 words
The composition of claim 1 wherein said first polymer is a copolymer consisting essentially of, by weight, about: (a) 40-50% amine functional monomers, (b) 14-40% hydroxy functional monomers, (c) 5-20% nonfunctional acrylic or methacrylic monomers, and (d) 0.5-3% chain-terminating monomers, said first polymer containing at least about 0.25 equivalent of amine groups per 100 grams of first polymer and at least about 0.15 equivalent of hydroxyl groups per 100 grams of first polymer.
Claim 5
Dependent Claim 117 words
The composition of claim 1, 2 or 3 wherein in said first polymer, the amine functional monomers of (a) are selected from diethylaminoethyl methacrylate and acrylate, dimethylaminoethyl methacrylate and acrylate, tertbutylaminoethyl methacrylate and acrylate, dimethylaminopropyl methacrylamide and acrylamide 2-, 3-, and 4-vinylpyridine vinylimidazole aminoethyl methacrylate and acrylate, methylaminoethyl methacrylate and acrylate, ethylaminoethyl methacrylate and acrylate, hydroxyethylaminoethyl methacrylate and acrylate, di(hydroxyethyl)aminoethyl methacrylate and acrylate; the hydroxy-functional monomers of (b) are selected from hydroxyethyl acrylate and methacrylate and hydroxypropyl acrylate and methacrylate; the nonfunctional acrylic or methacrylic monomers of (c) are selected from styrene acrylate and methacrylate and alkyl acrylates and methacrylates with 1-10 carbon atoms in the alkyl, and the chain-terminating monomers are selected from mercaptoethanol and dodecylmercaptan.
Claim 6
Dependent Claim 56 words
The composition of claim 1, 2 or 3 wherein the first polymer contains, by weight, about: (a) 59% tertbutylethylamino methacrylate, (b) 28% hydroxyethyl methacrylate, (c) 12% ethyl acrylate, and (d) 1% mercaptoethanol, said polymer containing about 0.32 equivalent amine groups per 100 grams of polymer and about 0.22 equivalent hydroxyl groups per 100 grams of polymer.
Claim 7
Dependent Claim 25 words
The composition of claim 1, 2 or 3 wherein the first polymer contains, by weight, about: (a) 69% tertbutylethylamino methacrylate and (b) 31% hydroxyethyl methacrylate.
Claim 8
Dependent Claim 43 words
The composition of claim 1, 2 or 3 wherein said first polymer comprises a backbone having grafted onto it, based on the weight of said backbone, about 0-50% of a glycidyl ester of at least one tertiary carboxylic acid containing 9-11 carbon atoms.
Claim 9
Dependent Claim 42 words
The composition of claim 1, 2 or 3 wherein the crosslinker polymer is selected from benzoguanamine, urea formaldehyde and melamine formaldehyde and is present in an amount of about 30-70% by weight, based on the weight of the first and second polymers.
Claim 10
Dependent Claim 18 words
The composition of claim 8 wherein the crosslinker polymer is benzoguanamine, present in an amount of about 45-50%.
Claim 11
Dependent Claim 19 words
The composition of claim 1 wherein said composition has a pH about in the range of 6.5 to 7.0.
Claim 12
Dependent Claim 30 words
The composition of claim 1 wherein said copolymer is present in the form of dispersed particles having a higher pH at the surface of said particles than inside said particles.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-28 1985-12-28 1986-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-28 1989-12-28 1990-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-28 1993-12-28 1994-06-29 $7700.00 Window Closed / Lapsed

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