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US4333818A Expired / Lapsed US ⏱️ 0.0 years remaining

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen

Assignee: Honeywell UOP LLC
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Filing: 1981-01-26
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Granted: 1982-06-08
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Expires: 2001-01-26
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Abstract

Abstract A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable for use in the relatively high pressure hydrotreating of sulfur-containing feedstocks.

Inventors

  • 👤 Angelo C. Coste

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 02:32
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 297 words
A process for the catalytic reforming of a hydrocarbonaceous feedstock which comprises the steps of: (a) contacting said feedstock with a reforming catalyst in a reforming zone in the presence of hydrogen at reforming conditions to produce an effluent stream comprising hydrogen admixed with hydrocarbon conversion products; (b) separating said effluent in a first gas-liquid separation zone at a low pressure relative to said reforming zone and forming a gaseous phase comprising hydrogen admixed with light hydrocarbon conversion products and a liquid hydrocarbon phase comprising the heavier hydrocarbon conversion products; (c) compressing the gaseous phase from step (b) to a high pressure relative to said first gas-liquid separation zone; (d) admixing the gaseous phase from step (c) with at least a portion of the liquid hydrocarbon phase from step (b); (e) separating the resulting mixture in a second gas-liquid separation zone at said relatively high pressure and forming a gaseous phase comprising relatively pure hydrogen and a liquid hydrocarbon phase; (f) recycling a portion of the gaseous phase from step (e) to said reforming zone; (g) compressing the balance of the gaseous phase from step (e) to a pressure of from about 300 to about 800 psig.; (h) admixing the gaseous phase from step (g) with at least a portion of the liquid hydrocarbon phase from step (e); (i) separating the resulting mixture in a third gas-liquid separation zone at a pressure of from about 300 to about 800 psig. and forming a purified hydrogen stream and a liquid hydrocarbon stream comprising the hydrocarbon conversion products; (j) recovering the purified hydrogen stream; and, (k) introducing the liquid hydrocarbon stream into a fractionation zone at conditions to produce an overhead fraction comprising light hydrocarbon conversion products and a higher boiling reformate fraction comprising the heavier hydrocarbon conversion products.
Claim 2
Dependent Claim 297 words
A process for the catalytic reforming of a hydrocarbonaceous feedstock which comprises the steps of: (a) contacting said feedstock with a reforming catalyst in a reforming zone in the presence of hydrogen at reforming conditions to produce an effluent stream comprising hydrogen admixed with hydrocarbon conversion products; (b) separating said effluent in a first gas-liquid separation zone at a low pressure relative to said reforming zone and forming a gaseous phase comprising hydrogen admixed with light hydrocarbon conversion products and a liquid hydrocarbon phase comprising the heavier hydrocarbon conversion products; (c) compressing the gaseous phase from step (b) to a high pressure relative to said first gas-liquid separation zone; (d) admixing the gaseous phase from step (c) with at least a portion of the liquid hydrocarbon phase from step (b); (e) separating the resulting mixture in a second gas-liquid separation zone at said relatively high pressure and forming a gaseous phase comprising relatively pure hydrogen and a liquid hydrocarbon phase; (f) recycling a portion of the gaseous phase from step (e) to said reforming zone; (g) compressing the balance of the gaseous phase from step (e) to a pressure of from about 300 to about 800 psig.; (h) admixing the gaseous phase from step (g) with at least a portion of the liquid hydrocarbon phase from step (e); (i) separating the resulting mixture in a third gas-liquid separation zone at a pressure of from about 300 to about 800 psig. and forming a purified hydrogen stream and a liquid hydrocarbon stream comprising the hydrocarbon conversion products; (j) recovering the purified hydrogen stream; and, (k) introducing the liquid hydrocarbon stream into a fractionation zone at conditions to produce an overhead fraction comprising light hydrocarbon conversion products and a higher boiling reformate fraction comprising the heavier hydrocarbon conversion products.
Claim 3
Dependent Claim 28 words
The process of claim 1 further characterized with respect to step (a) in that said reforming conditions include a pressure of from about 50 to about 250 psig.
Claim 4
Dependent Claim 31 words
The process of claim 1 further characterized with respect to step (b) in that said relatively low pressure is from about 25 to about 50 psig. lower than the reforming pressure.
Claim 5
Dependent Claim 31 words
The process of claim 1 further characterized with respect to step (c) in that said relatively high pressure is at least as high as the pressure maintained in said reforming zone.
Claim 6
Dependent Claim 39 words
The process of claim 1 further characterized with respect to step (c) in that said relatively high pressure is from about 75 to about 300 psig. and at least as high as the pressure maintained in said reforming zone.
Claim 7
Dependent Claim 30 words
The process of claim 1 further characterized in that said first and said second gas-liquid separation zones are maintained at a temperature of from about 60° to about 120° F.
Claim 8
Dependent Claim 30 words
The process of claim 1 further characterized with respect to step (i) in that said gas-liquid separation is effected at a temperature of from about 30° to about 50° F.

References Cited (Backward Citations)

US3431195A Cited
US3470084A Cited
US3520800A Cited
US3520799A Cited
US3882014A Cited
US4159937A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-07 1985-12-07 1986-06-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-07 1989-12-07 1990-06-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-07 1993-12-07 1994-06-08 $7700.00 Window Closed / Lapsed

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