Multilayer printing plates and process for making same

Claim 2

In a process of making a printing plate having multiple layers of differing moduli from photopolymerizable material, the improvement comprising doctoring over a supported photographic negative which is protected by a cover film a printing layer of a liquid photopolymerizable composition comprising a printing layer of a liquid photopolymerizable composition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymeric material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and a photoinitiator; doctoring onto the liquid printing layer a base layer of a different liquid photopolymerizable composition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymer material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and an amount of photoinitiator greater than that in said printing layer such that said base layer has a photopolymerization rate about 1.5 to about 250 times that of said printing layer, said printing layer and base layer compositions having differing crosslinkability such that, upon exposure to actinic light, the layers have moduli differing by at least about 50 p.s.i.

Claim 3

A printing plate having multiple layers of differing moduli prepared by a process comprising: (a) doctoring over a supported photographis negative which is protected by a cover film a printing layer of a liquid photopolymerizable compsition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymeric material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and a photoinitiator; (b) doctoring onto the liquid printing layer a base layer of a different liquid photopolymerizable compsition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymeric material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and an amount of photoinitiator greater than that in said printing layer such that said second liquid layer has a photopolymerization rate about 1.5 to about 250 times that of said printing layer, said printing layer and base layer compositions having differing cross-linkability such that, upon exposure to actinic light, the layers have moduli differing at least about 50 p.s.i.; (c) covering said layers with a backing material; (d) exposing the layers to actinic light through the photographic negative to polymerize selected portions of the layers; and (e) removing the unpolymerized portions of the layers.

Claim 4

A printing plate having multiple layers of differing moduli prepared by a process comprising: (a) doctoring over a supported photographis negative which is protected by a cover film a printing layer of a liquid photopolymerizable compsition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymeric material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and a photoinitiator; (b) doctoring onto the liquid printing layer a base layer of a different liquid photopolymerizable compsition comprising at least one addition polymerizable compound having a normal boiling point above about 100° C., a molecular weight of less than about 1500 and at least one ethylenically unsaturated group capable of forming a high polymer by photoinitiated polymerization; at least one unsaturated polymeric material which is soluble in said addition polymerizable compound; at least one polymerization inhibitor; and an amount of photoinitiator greater than that in said printing layer such that said second liquid layer has a photopolymerization rate about 1.5 to about 250 times that of said printing layer, said printing layer and base layer compositions having differing cross-linkability such that, upon exposure to actinic light, the layers have moduli differing at least about 50 p.s.i.; (c) covering said layers with a backing material; (d) exposing the layers to actinic light through the photographic negative to polymerize selected portions of the layers; and (e) removing the unpolymerized portions of the layers.