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US4331586A
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Novel light stabilizers for polymers
Assignee: Wyeth Holdings LLC
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Filing: 1981-07-20
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Granted: 1982-05-25
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Expires: 2001-07-20
Abstract
Abstract Oligomers of the formula ##STR1## which contain at least one piperidinyl moiety in the repeating unit are useful as light stabilizers for polymers.
Inventors
- 👤 William B. Hardy
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 22:58
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
209 words
An oligomer of the formula (I) ##STR9## wherein X and X 1 , which are the same or different, represent hydrogen, C 1 -C 20 alkyl, or the radical (II) ##STR10## wherein R 1 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 , which are the same or different, represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; Z represents C 2 -C 20 alkylene, either straight-chained or branched, wherein the alkylene chain is optionally interrupted by oxy, thio, or ##STR11## radicals, wherein R 5 represents hydrogen, C 1 -C 20 alkyl, or the radical (II); C 5 -C 10 cycloalkylene, ##STR12## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; n is an integer greater than 1; and, Y represents a halogen atom, C 1 -C 8 alkylamino, di(C 1 -C 8 )alkylamino, pyrrolidyl, morpholino, or ##STR13## wherein X, X 1 , and Z are as previously defined; with the proviso that at least one piperidinyl moiety of formula (II) is present in the repeating unit.
Claim 2
Dependent Claim
209 words
An oligomer of the formula (I) ##STR9## wherein X and X 1 , which are the same or different, represent hydrogen, C 1 -C 20 alkyl, or the radical (II) ##STR10## wherein R 1 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 , which are the same or different, represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; Z represents C 2 -C 20 alkylene, either straight-chained or branched, wherein the alkylene chain is optionally interrupted by oxy, thio, or ##STR11## radicals, wherein R 5 represents hydrogen, C 1 -C 20 alkyl, or the radical (II); C 5 -C 10 cycloalkylene, ##STR12## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; n is an integer greater than 1; and, Y represents a halogen atom, C 1 -C 8 alkylamino, di(C 1 -C 8 )alkylamino, pyrrolidyl, morpholino, or ##STR13## wherein X, X 1 , and Z are as previously defined; with the proviso that at least one piperidinyl moiety of formula (II) is present in the repeating unit.
Claim 3
Dependent Claim
13 words
The oligomer of claim 1 wherein X and X 1 are each ##STR14##
Claim 4
Dependent Claim
23 words
The oligomer of claim 2 wherein R 1 is hydrogen and R 2 , R 3 , and R 4 are each methyl.
Claim 5
Dependent Claim
14 words
The oligomer of claim 1 wherein Z is C 2 -C 20 straight-chained alkylene.
Claim 6
Dependent Claim
9 words
The oligomer of claim 3 wherein Z is hexamethylene.
Claim 7
Dependent Claim
32 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultra-violet stabilizingly effective amount of an oligomer of claim 1.
Claim 8
Dependent Claim
28 words
The method of claim 6 wherein the oligomer is incorporated in a concentration of from about 0.2 to 2% by weight based on the weight of the polymer.
Claim 9
Dependent Claim
11 words
The method of claim 6 wherein the polymer is a polyolefin.
Claim 10
Dependent Claim
10 words
The method of claim 8 wherein the polyolefin is polypropylene.
Claim 11
Dependent Claim
17 words
The method of claim 6 wherein the oligomer is that of claim 2, 3, 4 or 5.
Claim 12
Dependent Claim
13 words
The composition produced by the method of claim 6, 7, 8, or 9.
Claim 13
Dependent Claim
21 words
The composition produced by the method of claim 6 wherein the oligomer is that of claim 2, 3, 4 or 5.
References Cited (Backward Citations)
US4104248A
Cited
US4086207A
Cited
US4086204A
Cited
US4260689A
Cited
US4294963A
Cited
US4234471A
Cited
US4265805A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-24 | 1985-11-23 | 1986-05-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-24 | 1989-11-23 | 1990-05-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-24 | 1993-11-23 | 1994-05-25 | $7700.00 | Window Closed / Lapsed |