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US4331586A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel light stabilizers for polymers

Assignee: Wyeth Holdings LLC
•
Filing: 1981-07-20
•
Granted: 1982-05-25
•
Expires: 2001-07-20
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Abstract

Abstract Oligomers of the formula ##STR1## which contain at least one piperidinyl moiety in the repeating unit are useful as light stabilizers for polymers.

Inventors

  • 👤 William B. Hardy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:29
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/35

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 209 words
An oligomer of the formula (I) ##STR9## wherein X and X 1 , which are the same or different, represent hydrogen, C 1 -C 20 alkyl, or the radical (II) ##STR10## wherein R 1 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 , which are the same or different, represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; Z represents C 2 -C 20 alkylene, either straight-chained or branched, wherein the alkylene chain is optionally interrupted by oxy, thio, or ##STR11## radicals, wherein R 5 represents hydrogen, C 1 -C 20 alkyl, or the radical (II); C 5 -C 10 cycloalkylene, ##STR12## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; n is an integer greater than 1; and, Y represents a halogen atom, C 1 -C 8 alkylamino, di(C 1 -C 8 )alkylamino, pyrrolidyl, morpholino, or ##STR13## wherein X, X 1 , and Z are as previously defined; with the proviso that at least one piperidinyl moiety of formula (II) is present in the repeating unit.
Claim 2
Dependent Claim 209 words
An oligomer of the formula (I) ##STR9## wherein X and X 1 , which are the same or different, represent hydrogen, C 1 -C 20 alkyl, or the radical (II) ##STR10## wherein R 1 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 , which are the same or different, represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; Z represents C 2 -C 20 alkylene, either straight-chained or branched, wherein the alkylene chain is optionally interrupted by oxy, thio, or ##STR11## radicals, wherein R 5 represents hydrogen, C 1 -C 20 alkyl, or the radical (II); C 5 -C 10 cycloalkylene, ##STR12## C 6 -C 12 arylene, or C 8 -C 14 aralkylene; n is an integer greater than 1; and, Y represents a halogen atom, C 1 -C 8 alkylamino, di(C 1 -C 8 )alkylamino, pyrrolidyl, morpholino, or ##STR13## wherein X, X 1 , and Z are as previously defined; with the proviso that at least one piperidinyl moiety of formula (II) is present in the repeating unit.
Claim 3
Dependent Claim 13 words
The oligomer of claim 1 wherein X and X 1 are each ##STR14##
Claim 4
Dependent Claim 23 words
The oligomer of claim 2 wherein R 1 is hydrogen and R 2 , R 3 , and R 4 are each methyl.
Claim 5
Dependent Claim 14 words
The oligomer of claim 1 wherein Z is C 2 -C 20 straight-chained alkylene.
Claim 6
Dependent Claim 9 words
The oligomer of claim 3 wherein Z is hexamethylene.
Claim 7
Dependent Claim 32 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultra-violet stabilizingly effective amount of an oligomer of claim 1.
Claim 8
Dependent Claim 28 words
The method of claim 6 wherein the oligomer is incorporated in a concentration of from about 0.2 to 2% by weight based on the weight of the polymer.
Claim 9
Dependent Claim 11 words
The method of claim 6 wherein the polymer is a polyolefin.
Claim 10
Dependent Claim 10 words
The method of claim 8 wherein the polyolefin is polypropylene.
Claim 11
Dependent Claim 17 words
The method of claim 6 wherein the oligomer is that of claim 2, 3, 4 or 5.
Claim 12
Dependent Claim 13 words
The composition produced by the method of claim 6, 7, 8, or 9.
Claim 13
Dependent Claim 21 words
The composition produced by the method of claim 6 wherein the oligomer is that of claim 2, 3, 4 or 5.

References Cited (Backward Citations)

US4104248A Cited
US4086207A Cited
US4086204A Cited
US4260689A Cited
US4294963A Cited
US4234471A Cited
US4265805A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-24 1985-11-23 1986-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-24 1989-11-23 1990-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-24 1993-11-23 1994-05-25 $7700.00 Window Closed / Lapsed

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