US4326944A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Rapid hydropyrolysis of carbonaceous solids
Assignee: BP Corp North America Inc
•
Filing: 1980-04-14
•
Granted: 1982-04-27
•
Expires: 2000-04-14
Abstract
Abstract A method is disclosed for recovering liquids and gases by a rapid hydropyrolysis of carbonaceous solids which comprises subjecting the carbonaceous material in a stream of carrier gas to a first pressure and a first temperature below the decomposition temperature of the carbonaceous material; reducing substantially in a single step the pressure on the stream of carbonaceous material from the first pressure to a second pressure, the ratio of the first pressure to the second pressure being at least 1.6, thereby accelerating the carrier gas in the stream of carbonaceous material; permitting the accelerated stream of carbonaceous material to expand as a free jet and mixing hot gas with the accelerated and expanded stream of carbonaceous material to raise the temperature of the carbonaceous material by heat exchange with the hot gas, to a second temperature of at least the aforesaid decomposition temperature, thereby initiating decomposition of the carbonaceous material; and reducing the temperature of the reaction mixture to below said decomposition temperature, with the total time for heating the carbonaceous material from the first temperature to the second temperature, decomposing the carbonaceous material and cooling the reaction mixture to below said decomposition temperature being from about 1 millisecond to about 10 seconds.
Inventors
- 👤 James S. Meyer
- 👤 Ken K. Robinson
- 👤 John M. Forgac
- 👤 David F. Tatterson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:12
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/06; C10G1/02; Y; Y10; Y10S; Y10S165/00; Y10S165/903
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
278 words
A process for treating crushed solid carbonaceous material to obtain therefrom liquid and gaseous products, comprising: subjecting the carbonaceous material in a stream of carrier gas to a first pressure in the range of from about 1 atmosphere to about 680 atmospheres, at a first temperature of from about ambient up to the decomposition temperature of the carbonaceous material, the carbonaceous material having a particle size in the range of from about 1 micron up to about 1 millimeter in the largest dimension; reducing substantially in a single step the pressure on the stream of carbonaceous material from the first pressure to a second pressure in the range of from about sub-atmospheric to about 272 atmospheres, the ratio of the first pressure to the second pressure being at least about 1.6, thereby accelerating the carrier gas in the stream of carbonaceous material to at least a sonic velocity; permitting the accelerated stream of carbonaceous material to expand as a free jet and mixing hot gas with the accelerated and expanded stream of carbonaceous material to raise the temperature of the carbonaceous material by heat exchange with the hot gas, to a second temperature in the range of the decomposition temperature to about 2204° C., and thereby initiating decomposition of the carbonaceous material to form a reaction mixture containing liquids and gases; and reducing the temperature of the reaction mixture to below the decomposition temperature, with the total time for heating the carbonaceous material from the first temperature to the second temperature, decomposing the carbonaceous material and cooling the reaction mixture to below the decomposition temperature being in the range of from about 1 millisecond to about 10 seconds.
Claim 2
Dependent Claim
278 words
A process for treating crushed solid carbonaceous material to obtain therefrom liquid and gaseous products, comprising: subjecting the carbonaceous material in a stream of carrier gas to a first pressure in the range of from about 1 atmosphere to about 680 atmospheres, at a first temperature of from about ambient up to the decomposition temperature of the carbonaceous material, the carbonaceous material having a particle size in the range of from about 1 micron up to about 1 millimeter in the largest dimension; reducing substantially in a single step the pressure on the stream of carbonaceous material from the first pressure to a second pressure in the range of from about sub-atmospheric to about 272 atmospheres, the ratio of the first pressure to the second pressure being at least about 1.6, thereby accelerating the carrier gas in the stream of carbonaceous material to at least a sonic velocity; permitting the accelerated stream of carbonaceous material to expand as a free jet and mixing hot gas with the accelerated and expanded stream of carbonaceous material to raise the temperature of the carbonaceous material by heat exchange with the hot gas, to a second temperature in the range of the decomposition temperature to about 2204° C., and thereby initiating decomposition of the carbonaceous material to form a reaction mixture containing liquids and gases; and reducing the temperature of the reaction mixture to below the decomposition temperature, with the total time for heating the carbonaceous material from the first temperature to the second temperature, decomposing the carbonaceous material and cooling the reaction mixture to below the decomposition temperature being in the range of from about 1 millisecond to about 10 seconds.
Claim 3
Dependent Claim
91 words
The process of claim 1 wherein the carbonaceous material is intimately contacted at the first temperature and the first pressure either with a material which at the second temperature and at the second pressure reacts with products from the decomposition to stabilize the decomposition products against recombination or further decomposition reactions, or with a material which produces the stabilizing material at the second temperature and second pressure, and wherein the carbonaceous material is transported in intimate contact with the stabilizing material or said producing material in the stream of carrier gas.
Claim 4
Dependent Claim
23 words
The process of claim 2 wherein the stabilizing material or the producing material is a component of the carrier gas in said stream.
Claim 5
Dependent Claim
71 words
The process of claim 2 wherein the carbonaceous material is subjected to a pretreatment of intimate contact with the stabilizing material or the producing material in the gaseous state at a pressure in excess of the first pressure and then the carbonaceous material, in intimate contact with the stabilizing material or the producing material, is entrained at the first pressure and at the first temperature in the stream of carrier gas.
Claim 6
Dependent Claim
24 words
The process of claim 4 wherein the stabilizing material or the producing material is additionally a component of the carrier gas in the stream.
Claim 7
Dependent Claim
51 words
The process of claim 2 wherein the stabilizing material includes hydrogen and the producing material is a gas which at the second temperature and second pressure supplies hydrogen and has a ratio of hydrogen atoms to carbon atoms greater than one and greater than the corresponding ratio for the carbonaceous material.
Claim 8
Dependent Claim
11 words
The process of claim 6 wherein the producing material is methane.
Claim 9
Dependent Claim
42 words
The process of claim 4 wherein, prior to being pretreated, the carbonaceous material is subjected to an elevated temperature less than the decomposition temperature of the carbonaceous material and at a pressure of from about 6.8×10 -4 atmosphere to about 0.068 atmosphere.
Claim 10
Dependent Claim
11 words
The process of claim 1 wherein the carbonaceous material is coal.
Claim 11
Dependent Claim
11 words
The process of claim 1 wherein the carrier gas is hydrogen.
Claim 12
Dependent Claim
37 words
The process of claim 1 wherein the weight ratio of carbonaceous material to carrier gas in the stream being equivalent to a corresponding ratio of from about 0.25 to about 200 when the carrier gas is hydrogen.
Claim 13
Dependent Claim
22 words
The process of claim 1 wherein the second pressure is in the range of from about 0.068 atmosphere to about 68 atmospheres.
Claim 14
Dependent Claim
20 words
The process of claim 1 wherein the ratio of the first pressure to the second pressure is at least 2.
Claim 15
Dependent Claim
24 words
The process of claim 1 wherein the second temperature is at least 482° C. and is reduced to a temperature below about 482° C.
Claim 16
Dependent Claim
24 words
The process of claim 14 wherein the second temperature is at least 649° C. and is reduced to a temperature below about 649° C.
Claim 17
Dependent Claim
20 words
The process of claim 1 wherein the hot gas is hydrogen or a gas resulting from the combustion of char.
Claim 18
Dependent Claim
31 words
The process of claim 1 wherein the mixing of the hot gas and the stream of carbonaceous material is effected by aspirating the hot gas into the stream of carbonaceous material.
Claim 19
Dependent Claim
22 words
The process of claim 1 wherein the total time is in the range of from about 2 milliseconds to about 50 milliseconds.
Claim 20
Dependent Claim
51 words
The process of claim 4 wherein the carbonaceous material is coal, the second temperature is at least 482° C. and is reduced to a temperature below about 482° C., the second pressure is in the range of from about 0.068 atmosphere to about 68 atmospheres, and the stabilizing material is hydrogen.
Claim 21
Dependent Claim
12 words
The process of claim 1 wherein the carbonaceous material is tar sands.
Claim 22
Dependent Claim
12 words
The process of claim 1 wherein the carbonaceous material is oil shale.
Claim 23
Dependent Claim
11 words
The process of claim 1 wherein the carbonaceous material is biomass.
References Cited (Backward Citations)
US1713794A
Cited
US2435746A
Cited
US2832545A
Cited
US3960700A
Cited
US4003820A
Cited
US3997423A
Cited
US4013543A
Cited
US4012311A
Cited
US4123349A
Cited
US4169128A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-04-26 | 1985-10-26 | 1986-04-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-04-26 | 1989-10-26 | 1990-04-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-04-26 | 1993-10-26 | 1994-04-27 | $7700.00 | Window Closed / Lapsed |