US4013543A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Upgrading solid fuel-derived tars produced by low pressure hydropyrolysis
Assignee: Cities Service Co
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Filing: 1975-12-15
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Granted: 1977-03-22
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Expires: 1995-12-15
Abstract
Abstract Crushed carbonaceous fuel is rapidly mixed with hot hydrogen, at 500° to 1,500° C. and 0 to 250 psig., in a reactor, and then, after a short reaction time, rapidly quenched. The total heat-up, reaction, and quench time is less than 2 seconds. This short residence time and rapid heat-up results in a high yield of carbonaceous tars. The carbonaceous tars are subsequently and directly introduced into a fluid coker to obtain gas, upgraded carbonaceous tars, and hot coke.
Inventors
- 👤 Marvin Greene
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:19
CPC Classifications
C; C10; C10B; C10B55/00; C10B55/02; C10B55/04; C10B55/08; C10B55/10; C10B57/00; C10B57/08; C10G; C10G1/00; C10G1/006; C10G1/06
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
119 words
A process of producing and upgrading carbonaceous tars comprising, in serial combination, a. adding liquid or crushed solid carbonaceous material to a reactor, b. adding hot hydrogen to the stream of carbonaceous material, c. reacting the hydrogen and the carbonaceous material at a pressure between atmospheric pressure and 250 psia. and a temperature between about 400° and about 2,000° C, d. quenching the mixture, with the total residence time for heat-up, reaction and quenching varying from about 2 milliseconds to about 2 seconds, e. processing said quenched reaction mixture to form a cold tar stream, and f. introducing said cold tar stream of step (e) into a fluid coking zone to obtain gas, upgraded carbonaceous tars, and hot coke.
Claim 2
Dependent Claim
119 words
A process of producing and upgrading carbonaceous tars comprising, in serial combination, a. adding liquid or crushed solid carbonaceous material to a reactor, b. adding hot hydrogen to the stream of carbonaceous material, c. reacting the hydrogen and the carbonaceous material at a pressure between atmospheric pressure and 250 psia. and a temperature between about 400° and about 2,000° C, d. quenching the mixture, with the total residence time for heat-up, reaction and quenching varying from about 2 milliseconds to about 2 seconds, e. processing said quenched reaction mixture to form a cold tar stream, and f. introducing said cold tar stream of step (e) into a fluid coking zone to obtain gas, upgraded carbonaceous tars, and hot coke.
Claim 3
Dependent Claim
20 words
The process of claim 1, wherein the crushed solid material has an average particle size smaller than about one-half inch.
Claim 4
Dependent Claim
25 words
The process of claim 1, wherein the ratio of hydrogen to carbonaceous material, in the carbonaceous material-hydrogen mixture, varies from about 0.05 to about 4.
Claim 5
Dependent Claim
21 words
The process of claim 1, wherein the heat-up time of said carbonaceous material is between about 500° C/sec. and 1,000,000° C/sec.
Claim 6
Dependent Claim
18 words
The process of claim 1, wherein the temperature of the quenched mixture does not exceed about 1200° C.
Claim 7
Dependent Claim
17 words
The process of claim 1, wherein the quenching material is hydrogen and the carbonaceous material is coal.
Claim 8
Independent Claim
128 words
A method of producing and upgrading coal tars comprising: a. introducing finely divided coal into a vessel in a continuous stream, said vessel having a pressure between atmospheric pressure and 250 psia; b. continuously adding hot hydrogen to the vessel so as to impinge said coal stream; c. maintaining said coal stream within said vessel at a temperature between about 400° and about 2,000° C. d. limiting the total residence time for heat-up, reaction and quenching to between about 2 milliseconds to about 2 seconds; e. thereafter quenching the hot hydrogen-coal stream with cold hydrogen, f. separating coal tars from said quenched hydrogen-coal stream, and g. introducing said coal tars of step (f) directly into a fluid coking zone to obtain gas, upgraded coal tars, and hot coke.
Claim 9
Independent Claim
128 words
A method of producing and upgrading coal tars comprising: a. introducing finely divided coal into a vessel in a continuous stream, said vessel having a pressure between atmospheric pressure and 250 psia; b. continuously adding hot hydrogen to the vessel so as to impinge said coal stream; c. maintaining said coal stream within said vessel at a temperature between about 400° and about 2,000° C. d. limiting the total residence time for heat-up, reaction and quenching to between about 2 milliseconds to about 2 seconds; e. thereafter quenching the hot hydrogen-coal stream with cold hydrogen, f. separating coal tars from said quenched hydrogen-coal stream, and g. introducing said coal tars of step (f) directly into a fluid coking zone to obtain gas, upgraded coal tars, and hot coke.
Claim 10
Dependent Claim
86 words
The method of claim 7, wherein a. the coal has an average particle size of less than about 1/2 inch, b. the hydrogen/coal weight ratio of the reaction mixture varies from about 0.005 to about 4, c. the reaction temperature varies from about 500°, to about 1,500° C., d. the total residence time of hydrogen and coal is not more than about 1 second, e. the cold hydrogen quench stream has a temperature below 1,200° C., and f. the separated liquid hydrocarbon stream is further processed.
Claim 11
Dependent Claim
27 words
The method of claim 7, wherein the separated coal tars are further processed, said coal tars having compounds which include between about 10 and 80 carbon atoms.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-21 | 1980-09-20 | 1981-03-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-21 | 1984-09-20 | 1985-03-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-21 | 1988-09-20 | 1989-03-22 | $7700.00 | Window Closed / Lapsed |