Coal conversion in the presence of added hydrogen sulfide

Claim 2

A process for liquefying coal or similar carbonaceous solids by converting said solids into lower molecular weight liquid hydrocarbons which comprises contacting said carbonaceous solids with molecular hydrogen under liquefaction conditions in a liquefaction zone in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide, wherein the pressure in said liquefaction zone is maintained between about 300 psig and 5000 psig.

Claim 3

A process as defined in claim 1 wherein the temperature in said liquefaction zone is between about 790° F. and about 860° F.

Claim 4

A process as defined in claim 1 wherein the pressure in said liquefaction zone is between about 1500 psig and about 2500 psig.

Claim 5

A process as defined in claim 1 wherein a sufficient amount of hydrogen sulfide is introduced into said liquefaction zone to yield a hydrogen sulfide concentration in said zone of between about 3 volume percent and about 10 volume percent based on the amount of hydrogen present in said zone.

Claim 6

A process as defined by claim 1 wherein said carbonaceous solids are contacted with molecular hydrogen in the absence of an externally added vapor phase hydrocarbon solvent.

Claim 7

A process as defined by claim 1 wherein the temperature in said liquefaction zone is between about 750° F. and about 900° F. and wherein a sufficient amount of hydrogen sulfide is introduced into said liquefaction zone to yield a hydrogen sulfide concentration in said zone of between about 1 volume percent and about 30 volume percent based on the amount of hydrogen present in said zone.

Claim 8

A process as defined by claim 1 wherein the solids residence time in said liquefaction zone is between about 20 minutes and about 200 minutes.

Claim 9

A process for liquefying coal or similar carbonaceous solids by converting said solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide under liquefaction conditions during sequential residence in two or more liquefaction zones arranged in series and operated such that (i) the temperature in each zone increases from the first to the final zone of the series, (ii) the total of the solids residence times in all except the final zone of the series is sufficient to produce an increase in liquid yield over that which would be obtainable by a single stage liquefaction carried out under the conditions in said final zone and (iii) the pressure in each zone is between about 300 psig and about 5000 psig, wherein said carbonaceous solids are partially converted into lower molecular weight liquid hydrocarbons in each of said liquefaction zones and the only hydrocarbon liquids added to each liquefaction zone subsequent to said first liquefaction zone are the liquids in the effluent from the preceding liquefaction zone; and (b) recovering liquid hydrocarbonaceous product from the effluent of said final liquefaction zone.

Claim 10

A process for liquefying coal or similar carbonaceous solids by converting said solids into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said carbonaceous solids with molecular hydrogen in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide under liquefaction conditions during sequential residence in two or more liquefaction zones arranged in series and operated such that (i) the temperature in each zone increases from the first to the final zone of the series, (ii) the total of the solids residence times in all except the final zone of the series is sufficient to produce an increase in liquid yield over that which would be obtainable by a single stage liquefaction carried out under the conditions in said final zone and (iii) the pressure in each zone is between about 300 psig and about 5000 psig, wherein said carbonaceous solids are partially converted into lower molecular weight liquid hydrocarbons in each of said liquefaction zones and the only hydrocarbon liquids added to each liquefaction zone subsequent to said first liquefaction zone are the liquids in the effluent from the preceding liquefaction zone; and (b) recovering liquid hydrocarbonaceous product from the effluent of said final liquefaction zone.

Claim 11

A process as defined in claim 8 wherein the total of the solids residence times in all except the final zone of the series is greater than about 40 minutes.

Claim 12

A process as defined in claim 8 wherein said first liquefaction zone is operated at a temperature between about 680° F. and about 750° F.

Claim 13

A process as defined in claim 8 wherein said carbonaceous solids comprise subbituminous coal.

Claim 14

A process as defined in claim 8 wherein the temperature in said first liquefaction zone is in the range between about 690° F. and about 720° F. and the solids residence time in said first liquefaction zone is between about 120 minutes and about 170 minutes.

Claim 15

A process as defined in claim 8 wherein the temperature in said final liquefaction zone is in the range between about 820° F. and about 860° F. and the solids residence time in said final liquefaction zone is between about 40 minutes and about 90 minutes.

Claim 16

A process as defined in claim 8 wherein two liquefaction zones are employed in step (a).

Claim 17

A process as defined in claim 8 wherein sufficient hydrogen sulfide is added to said first liquefaction zone to provide a concentration of hydrogen sulfide in all of said zones between about 1 volume percent and about 30 volume percent based on the amount of hydrogen gas present in said zones.

Claim 18

A process as defined by claim 8 wherein the temperature in said first liquefaction zone is between about 680° F. and 750° F., the temperature in said final liquefaction zone is greater than about 790° F., and wherein sufficient hydrogen sulfide is added to said first liquefaction zone to provide a concentration of hydrogen sulfide in all of said zones between about 1 volume percent and about 30 volume percent based on the amount of hydrogen gas present in said zones.

Claim 19

A process as defined by claim 16 wherein the solids residence time in said first liquefaction zone is greater than about 40 minutes and the solids residence time in said second liquefaction zone is between about 20 minutes and about 120 minutes.

Claim 20

A process as defined by claim 8 wherein the pressure in all of said liquefaction zones is between about 1500 psig and about 2500 psig.

Claim 21

A process for liquefying coal by converting said coal into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said coal with molecular hydrogen under liquefaction conditions at a temperature of at least about 650° F. and at a pressure between about 300 psig and about 5000 psig in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide in a first liquefaction zone to at least partially convert said coal into lower molecular weight liquid hydrocarbons thereby producing a liquefaction effluent; (b) subjecting said liquefaction effluent from said first liquefaction zone to liquefaction conditions in the presence of molecular hydrogen and hydrogen sulfide in a second liquefaction zone maintained at a pressure between about 300 psig and about 5000 psig and at a temperature above about 790° F. and greater than the temperature in said first liquefaction zone thereby further converting said coal into lower molecular weight liquid hydrocarbons, wherein the only hydrocarbon liquids added to said second liquefaction zone are those liquids in said liquefaction effluent from said first liquefaction zone and wherein a sufficient amount of hydrogen sulfide is added to said first liquefaction zone to provide a hydrogen sulfide concentration in said first and said second zones of between about 1 and about 30 volume percent based on the amount of hydrogen present in each zone; and (c) recovering liquid hydrocarbonaceous products from the effluent of said second liquefaction zone.

Claim 22

A process for liquefying coal by converting said coal into lower molecular weight liquid hydrocarbons which comprises: (a) contacting said coal with molecular hydrogen under liquefaction conditions at a temperature of at least about 650° F. and at a pressure between about 300 psig and about 5000 psig in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide in a first liquefaction zone to at least partially convert said coal into lower molecular weight liquid hydrocarbons thereby producing a liquefaction effluent; (b) subjecting said liquefaction effluent from said first liquefaction zone to liquefaction conditions in the presence of molecular hydrogen and hydrogen sulfide in a second liquefaction zone maintained at a pressure between about 300 psig and about 5000 psig and at a temperature above about 790° F. and greater than the temperature in said first liquefaction zone thereby further converting said coal into lower molecular weight liquid hydrocarbons, wherein the only hydrocarbon liquids added to said second liquefaction zone are those liquids in said liquefaction effluent from said first liquefaction zone and wherein a sufficient amount of hydrogen sulfide is added to said first liquefaction zone to provide a hydrogen sulfide concentration in said first and said second zones of between about 1 and about 30 volume percent based on the amount of hydrogen present in each zone; and (c) recovering liquid hydrocarbonaceous products from the effluent of said second liquefaction zone.

Claim 23

A process as defined in claim 19 wherein said coal comprises subbituminous coal.

Claim 24

A process as defined in claim 19 wherein said solids residence time in said first liquefaction zone is greater than about 40 minutes and said solids residence time in said second liquefaction zone is between about 20 and about 120 minutes.

Claim 25

A process as defined in claim 19 wherein the temperature in said first liquefaction zone is between about 680° F. and about 750° F. and the temperature in said second liquefaction zone is between about 790° F. and about 900° F.

Claim 26

A process as defined in claim 19 wherein a sufficient amount of hydrogen sulfide is added to said first liquefaction zone to provide a hydrogen sulfide concentration in said zone of between about 3 and about 10 volume percent and a hydrogen sulfide concentration in said second liquefaction zone of between about 3 volume percent and about 10 volume percent, said concentrations based on the amount of hydrogen present in each zone.

Claim 27

A process as defined by claim 19 wherein the solids residence time in said first liquefaction zone is greater than the solids residence time in said second liquefaction zone.