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US3640816A Expired / Lapsed US ⏱️ 0.0 years remaining

Multiple stage process for producing light liquids from coal

Assignee: RAG AG
•
Filing: 1969-12-08
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Granted: 1972-02-08
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Expires: 1989-12-08
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Abstract

Abstract A multiple stage process for producing light liquids from coal wherein a slurry of pulverized coal, a solvent therefor and hydrogen is charged under pressure into a first reaction zone where the temperature thereof is elevated and maintained at such level until substantially all of the coal is dissolved. Gases and light liquids produced by partial hydrogenation of the reaction products are separated from the heavy bottoms and the latter are charged to another reaction zone under pressure where the charge along with an added quantity of hydrogen are heated to a higher temperature than present in the first zone so as to hydrocrack the constituents and produce additional quantities of gases and light liquids which are then separated from the heavy bottoms. The gases and light liquids from each stage are selectively segregated in a separation and distillation unit. Two or more reaction zones in series relationship may be employed with the charges thereto being subjected to treatment conditions of successively increasing severity accomplished by successively higher temperatures, pressures or residence times or combinations thereof. The heavy bottoms from one or more of the stages may be recycled back to preceding stages if desired.

Inventors

  • 👤 Willard C Bull
  • 👤 Bruce K Schmid

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 22:05
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/006

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 34 words
A precesS as set forth in claim 1, wherein step (b) is continued until at least approximately 95 percent of the charge of coal to the first reaction zone is dissolved in said solvent.
Claim 2
Dependent Claim 81 words
A process as set forth in claim 1, wherein is included the steps of charging said admixture to said first reaction zone in accordance with step (a) under a pressure of from about 500 p.s.i. to approximately 3,000 p.s.i., raising the temperature of said admixture to a temperature level as provided in step (b) of from about 350* C. to approximately 500* C. and maintaining said admixture within said temperature range for a period of about 15 to approximately 30 min.
Claim 3
Dependent Claim 103 words
A process as set forth in claim 1, wherein is included the steps of charging a portion of said heavy bottoms from said first reaction mixture to said second reaction zone in accordance with step (d) under a pressure of from about 500 p.s.i. to approximately 3,000 p.s.i., raising the temperature of said charge to said second reaction zone to a temperature level as provided in step (e) within the range of from about 350* C. to approximately 525* C. and maintaining said charge to said second reaction zone within said temperature range for a period of about 5 to approximately 100 min.
Claim 4
Dependent Claim 173 words
A process as set forth in claim 1, wherein is included the steps of: g. charging a portion of said heavy bottoms from said second reaction mixture and a hydrogenation agent therefor consisting essentially of hydrogen, under a pressure of at least 500 p.s.i. to a third reaction zone; h. raising the temperature of said charge to said third reaction zone to at least 350* C. and maintaining said charge at such temperature for a period not to exceed 100 min. to dissolve at least a portion of any undissolved coal in said charge to said third reaction zone and to further hydrogenate a part of said coal dissolved therein to produce a third reaction mixture which includes gases, light liquids and heavy bottoms, the reaction conditions including pressure, temperature and residence time within said third reaction zone being more severe than the reaction conditions within said second reaction zone; and thereafter i. flash separating by pressure reduction said gases and said light liquids from said heavy bottoms of said third reaction mixture.
Claim 5
Dependent Claim 103 words
A process as set forth in claim 5, wherein is included the steps of charging a portion of said heavy bottoms of said second reaction mixture to said third reaction zone in accordance with step (g) under a pressure of from about 500 p.s.i. to approximately 3,000 p.s.i., raising the temperature of said charge to said third reaction zone to a temperature level as provided in step (h) within the range of from about 350* C. to approximately 550* C. and maintaining said charge to said third reaction zone within said temperature range for a period of about 5 to approximately 100 min.
Claim 6
Dependent Claim 52 words
A process as set forth in claim 1, wherein is included the step of treating a part of the heavy bottoms from the last reaction zone to remove solids therefrom and returning such solids-free heavy bottoms to the charge to at least one of the reaction zones as makeup for said solvent.
Claim 7
Dependent Claim 26 words
A process as set forth in claim 1, wherein said solvent is a solvent obtained from a previous processing of coal in accordance with said process.
Claim 8
Dependent Claim 42 words
A process as set forth in claim 1, wherein is included the steps of directing the reaction mixture from each reaction zone into a separator, and thereafter lowering the pressure on the reaction mixtures to flash off the gases and light hydrocarbons.
Claim 9
Dependent Claim 66 words
A process as set forth in claim 1, wherein is included the steps of continuously charging the reaction zones while simultaneously removing reaction mixtures therefrom and returning at least a part of the heavy bottoms from the last reaction zone to a preCeding reaction zone while charging the heavy bottoms from the first reaction zone and each reaction zone thereafter into the next successive reaction zone.

References Cited (Backward Citations)

US2707163A Cited
US3505202A Cited
US3505203A Cited
US3503864A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1975-02-07 1975-08-09 1976-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1979-02-07 1979-08-09 1980-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1983-02-07 1983-08-09 1984-02-08 $7700.00 Window Closed / Lapsed

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