Coal liquefaction process

Claim 2

A process for the liquefaction of coal, which comprises the steps of: (a) treating a slurry comprising coal and a diluent with a hydrogen sulfide-containing gas at a temperature ranging from 100° to about 482° C. and a pressure ranging from atmospheric to about 5000 psig, and (b) subjecting at least a portion of the resulting product effluent to coal liquefaction conditions in a coal liquefaction zone, substantially all of said hydrogen sulfide being removed from the treated product effluent prior to step (b).

Claim 3

The process of claim 1 wherein said hydrogen sulfide-containing gas of step (a) is substantially pure hydrogen sulfide.

Claim 4

The process of claim 1 wherein said hydrogen sulfide-containing gas of step (a) is a gaseous mixture comprising from about 1 to about 99 mole percent hydrogen sulfide.

Claim 5

The process of claim 3 wherein said gaseous mixture of step (a) also comprises hydrogen.

Claim 6

The process of claim 1 wherein said treatment of step (a) is conducted in the absence of added extraneous catalyst.

Claim 7

The process of claim 1 wherein said treatment of step (a) is conducted at a temperature ranging from about 150° to about 466° C.

Claim 8

The process of claim 1 wherein said treatment of step (a) is conducted at a pressure ranging from about 1000 to about 3000 psig.

Claim 9

The process of claim 1 wherein said diluent is a hydrogen donor diluent.

Claim 10

The process of claim 1 wherein said diluent is a non-hydrogen donor diluent.

Claim 11

The process of claim 1 wherein said diluent is a non-hydrogen donor heavy hydrocarbonaceous oil.

Claim 12

The process of claim 1 wherein said diluent is a hydrocarbonaceous compound or mixture of hydrocarbonaceous compounds having an atmospheric pressure boiling point ranging from about 176.67° C. to about 454.44° C.

Claim 13

The process of claim 1 wherein a hydrogen-containing gas is introduced into said coal liquefaction zone.

Claim 14

The process of claim 1 wherein said coal liquefaction conditions include a temperature ranging from about 343° to 538° C., and a total pressure ranging from about 350 to about 5000 psig.

Claim 15

The process of claim 1 wherein the effluent resulting from said coal liquefaction step (b) comprises an oil product and a solid residue and wherein at least a portion of the solid residue is separated from said effluent and at least a portion of the separated solid residue is recycled to said coal liquefaction zone.

Claim 16

The process of claim 14 wherein after said solid residue is recycled to said coal liquefaction zone, said step (a) treatment is discontinued.

Claim 17

A process for the liquefaction of coal, which comprises the steps of: (a) treating a slurry comprising coal and a non-hydrogen donor diluent, in the absence of added catalyst, with a hydrogen sulfide-containing gas at a temperature ranging from 100° to about 482° C. and a pressure ranging from atmospheric to about 5000 psig; (b) removing substantially all of said hydrogen sulfide from the resulting treated effluent, and (c) subjecting at least a portion of the product resulting from step (b) to coal liquefaction conditions in the presence of hydrogen.

Claim 18

A process for the liquefaction of coal, which comprises the steps of: (a) treating a slurry comprising coal and a non-hydrogen donor diluent, in the absence of added catalyst, with a hydrogen sulfide-containing gas at a temperature ranging from 100° to about 482° C. and a pressure ranging from atmospheric to about 5000 psig; (b) removing substantially all of said hydrogen sulfide from the resulting treated effluent, and (c) subjecting at least a portion of the product resulting from step (b) to coal liquefaction conditions in the presence of hydrogen.

Claim 19

The process of claim 16 wherein said non-hydrogen donor diluent is a heavy hydrocarbonaceous oil.

Claim 20

The process of claim 16 wherein said non-hydrogen donor diluent is a hydrocarbonaceous compound or a mixture of hydrocarbonaceous compounds having an atmospheric pressure boiling point ranging from about 176.67° to about 454.44° C.