Light colored homogeneous and aqueous alpha olefin sulfonate solutions

Claim 2

A process for preparing a light colored, homogeneous, aqueous, alpha-olefin sulfonate solution which does not develop turbidity when it is allowed to stand for a long period of time, which comprises the steps of: preparing an aqueous C 10 -C 20 alpha-olefin sulfonate solution containing less than 10% by weight of 4-hydroxyalkane sulfonate, based on the total weight of sulfonates in said solution; then adding to and dissolving in said solution an additional quantity of separately prepared 4-hydroxyalkane sulfonate derived from C 10 -C 20 alpha-olefin to increase the concentration of 4-hydroxyalkane sulfonate in said solution to a value in the range of from 10 to 30% by weight, based on the total weight of sulfonates in said solution.

Claim 3

A process according to claim 1 in which said separately prepared 4-hydroxyalkane sulfonate has been prepared by sulfonating C 10 -C 20 alpha-olefin with a sulfur trioxide/inert gas mixture to obtain a sulfonation product containing 1,2-sultone and 1,3-sultone, then heating said sulfonation product with stirring to a temperature in the range of from about 95° to about 100° C. to isomerize the 1,2-sultone and 1,3-sultone and transform same into 1,4-sultone, then neutralizing said sulfonation product with an aqueous alkali solution to obtain a neutralized sulfonation product, then mixing said neutralized sulfonation product with ethanol to obtain an ethanol solution of said neutralized sulfonation product, then extracting the 1,4-sultone from said ethanol solution with toluene to obtain an extract of 1,4-sultone in toluene, then distilling off toluene from said extract to recover the 1,4-sultone, then hydrolyzing the thus-recovered 1,4-sultone by mixing same with anhydrous NaOH and anhydrous toluene to obtain a hydrolysis product containing sodium 4-hydroxyalkane sulfonate, then recovering the sodium 4-hydroxyalkane sulfonate from said hydrolysis product and then drying it to obtain sodium 4-hydroxyalkane sulfonate crystals.

Claim 4

A process for preparing a light colored, homogeneous, alpha-olefin sulfonate solution which does not develop turbidity when it is allowed to stand for a long period of time, which comprises the steps of: sulfonating C 10 -C 20 alpha-olefin by flowing said alpha-olefin in the form of a thin film and contacting said thin film of alpha-olefin with sulfur trioxide/inert gas mixture containing from 2 to 20% by volume of sulfur trioxide, wherein the molar ratio of said sulfur trioxide to said alpha-olefin is from about 1.0 to about 1.2, at a temperature of from 40° C. to 70° C., to obtain a sulfonation reaction product, then neutralizing the sulfonation reaction product with an aqueous alkali solution and then hydrolyzing the neutralized sulfonation reaction product to obtain a light colored alpha-olefin sulfonate solution containing less than 10% by weight of 4-hydroxyalkane sulfonate, based on the total weight of sulfonates in said light colored alpha-olefin sulfonate solution; separately preparing 4-hydroxyalkane sulfonate by sulfonating C 10 -C 20 alpha-olefin with a sulfur trioxide/inert gas mixture to obtain a sulfonation product containing 1,2-sultone and 1,3-sultone, then heating said sulfonation product with stirring to a temperature in the range of from about 95° to about 100° C. to isomerize the 1,2-sultone and 1,3-sultone and transform same into 1,4-sultone, then neutralizing said sulfonation product with an aqueous alkali solution to obtain a neutralized sulfonation product, then extracting and recovering the 1,4-sultone from said neutralized sulfonation product, then hydrolyzing the thus-recovered 1,4-sultone with anhydrous NaOH to obtain a hydrolysis product containing sodium 4-hydroxyalkane sulfonate, then recovering the sodium 4-hydroxyalkane sulfonate from said hydrolysis product; and then adding to and dissolving in said light colored alpha-olefin sulfonate solution an additional quantity of said sodium 4-hydroxyalkane sulfonate to increase the concentration of 4-hydroxyalkane sulfonate in said light colored alpha-olefin sulfonate solution to a value in the range of from 10 to 30% by weight, based on the total weight of sulfonates in said light colored alpha-olefin sulfonate solution.

Claim 5

A process for preparing a light colored, homogeneous, alpha-olefin sulfonate solution which does not develop turbidity when it is allowed to stand for a long period of time, which comprises the steps of: sulfonating C 10 -C 20 alpha-olefin by flowing said alpha-olefin in the form of a thin film and contacting said thin film of alpha-olefin with sulfur trioxide/inert gas mixture containing from 2 to 20% by volume of sulfur trioxide, wherein the molar ratio of said sulfur trioxide to said alpha-olefin is from about 1.0 to about 1.2, at a temperature of from 40° C. to 70° C., to obtain a sulfonation reaction product, then neutralizing the sulfonation reaction product with an aqueous alkali solution and then hydrolyzing the neutralized sulfonation reaction product to obtain a light colored alpha-olefin sulfonate solution containing less than 10% by weight of 4-hydroxyalkane sulfonate, based on the total weight of sulfonates in said light colored alpha-olefin sulfonate solution; separately preparing 4-hydroxyalkane sulfonate by sulfonating C 10 -C 20 alpha-olefin with a sulfur trioxide/inert gas mixture to obtain a sulfonation product containing 1,2-sultone and 1,3-sultone, then heating said sulfonation product with stirring to a temperature in the range of from about 95° to about 100° C. to isomerize the 1,2-sultone and 1,3-sultone and transform same into 1,4-sultone, then neutralizing said sulfonation product with an aqueous alkali solution to obtain a neutralized sulfonation product, then extracting and recovering the 1,4-sultone from said neutralized sulfonation product, then hydrolyzing the thus-recovered 1,4-sultone with anhydrous NaOH to obtain a hydrolysis product containing sodium 4-hydroxyalkane sulfonate, then recovering the sodium 4-hydroxyalkane sulfonate from said hydrolysis product; and then adding to and dissolving in said light colored alpha-olefin sulfonate solution an additional quantity of said sodium 4-hydroxyalkane sulfonate to increase the concentration of 4-hydroxyalkane sulfonate in said light colored alpha-olefin sulfonate solution to a value in the range of from 10 to 30% by weight, based on the total weight of sulfonates in said light colored alpha-olefin sulfonate solution.