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US4316940A Expired / Lapsed US ⏱️ 0.0 years remaining

High-solids polyester and aminoplast coating composition

Assignee: EIDP Inc
•
Filing: 1980-08-07
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Granted: 1982-02-23
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Expires: 2000-08-07
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Abstract

Abstract A curable, high-solids coating composition has film-forming constituents of a low molecular weight hydroxyl-functional polyester based on branched-chain glycols, an epoxy-resin/acid ester, and an aminoplast resin. The composition can be applied at commercially acceptable temperatures and environmentally acceptable solvent levels to form a durable film.

Inventors

  • 👤 Glenn D. Thornley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:43
CPC Classifications
C; C09; C09D; C09D167/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31786

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 206 words
A coating composition of a film-forming blend and a solvent for the blend wherein the blend is at least 50% by weight of the combined weight of the blend and the solvent and consists essentially of (a) 30-70% by weight, based on the weight of the blend, of a polyester polyol that is the reaction product of (1) pentaerythritol and at least one branched-chain glycol selected from the group consisting of neopentyl glycol, pinacol, and mixtures of these, wherein the molar ratio of glycol to pentaerythritol is from 2:1 to 6:1, (2) an aromatic or aliphatic monocarboxylic acid, or mixtures thereof, having no more than 18 carbon atoms, wherein the molar ratio of monocarboxylic acid to pentaerythritol is from 1:1 to 2.5:1, and (3) a mixture of an aromatic and a aliphatic dicarboxylic acid wherein the molar ratio of aromatic acid to aliphatic acid is from 2:1 to 6:1, wherein the polyol has a hydroxyl content of 5-9% by weight; (b) 4-35% by weight, based on the weight of the blend, of an epichlorohydrin-bisphenol-A epoxy resin, the esterification product of said resin with a monocarboxylic acid, or mixtures of these; and (c) 25-35% by weight, based on the weight of the blend, of an aminoplast resin.
Claim 2
Dependent Claim 206 words
A coating composition of a film-forming blend and a solvent for the blend wherein the blend is at least 50% by weight of the combined weight of the blend and the solvent and consists essentially of (a) 30-70% by weight, based on the weight of the blend, of a polyester polyol that is the reaction product of (1) pentaerythritol and at least one branched-chain glycol selected from the group consisting of neopentyl glycol, pinacol, and mixtures of these, wherein the molar ratio of glycol to pentaerythritol is from 2:1 to 6:1, (2) an aromatic or aliphatic monocarboxylic acid, or mixtures thereof, having no more than 18 carbon atoms, wherein the molar ratio of monocarboxylic acid to pentaerythritol is from 1:1 to 2.5:1, and (3) a mixture of an aromatic and a aliphatic dicarboxylic acid wherein the molar ratio of aromatic acid to aliphatic acid is from 2:1 to 6:1, wherein the polyol has a hydroxyl content of 5-9% by weight; (b) 4-35% by weight, based on the weight of the blend, of an epichlorohydrin-bisphenol-A epoxy resin, the esterification product of said resin with a monocarboxylic acid, or mixtures of these; and (c) 25-35% by weight, based on the weight of the blend, of an aminoplast resin.
Claim 3
Dependent Claim 28 words
The coating composition of claim 1 in which there is 50-70% by weight of (a), 4-15% by weight of (b), and in which (b) is said esterification product.
Claim 4
Dependent Claim 38 words
The coating composition of claim 2 wherein the branched-chain glycol is neopentyl glycol and the monocarboxylic acid of said polyester polyol is selected from the group consisting of benzoic acid, lauric acid, pelargonic acid, and mixtures of these.
Claim 5
Dependent Claim 52 words
The coating composition of claim 3 wherein the aromatic dicarboxylic acid is selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, and mixtures of these, and the aliphatic dicarboxylic acid is selected from the group consisting of succinic acid, glutaric acid, adipic acid, pimelic acid, and mixtures of these.
Claim 6
Dependent Claim 27 words
The coating composition of claim 4 wherein the polyester polyol is the reaction product of benzoic acid, pentaerythritol, neopentyl glycol, isophthalic acid, phthalic acid, and adipic acid.
Claim 7
Dependent Claim 22 words
The coating composition of claim 5 wherein the monocarboxylic acid of said esterification product is a fatty acid having 8-18 carbon atoms.
Claim 8
Dependent Claim 12 words
The coating composition of claim 6 wherein the aminoplast resin is hexamethoxymethylmelamine.
Claim 9
Dependent Claim 16 words
The coating composition of claim 1, 2, 3, 4, 5, 6, or 7 additionally containing pigment.
Claim 10
Dependent Claim 23 words
The coating composition of claim 1, 2, 3, 4, 5, 6, or 7 additionally containing an ultraviolet light stabilizer, an antioxidant, or both.
Claim 11
Dependent Claim 36 words
A substrate coated with a first cured coating composition according to claim 1 overlaid with a second cured coating composition according to claim 1 wherein said first composition contains pigment and said second composition is unpigmented.
Claim 12
Dependent Claim 16 words
The substrate of claim 10 wherein said first cured composition additionally contains an ultraviolet light stabilizer.
Claim 13
Dependent Claim 14 words
The substrate of claim 11 wherein said first cured composition additionally contains an antioxidant.
Claim 14
Dependent Claim 20 words
The substrate of claim 12 wherein said second cured coating composition contains an ultraviolet light stabilizer, an antioxidant, or both.

References Cited (Backward Citations)

US3098835A Cited
US3988288A Cited
US3992346A Cited
US3994851A Cited
US4046937A Cited
US3960979A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-22 1985-08-24 1986-02-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-22 1989-08-24 1990-02-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-22 1993-08-24 1994-02-23 $7700.00 Window Closed / Lapsed

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