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US4316013A Expired / Lapsed US ⏱️ 0.0 years remaining

Substituted heterocyclic methine dyes

Assignee: Novartis Corp
•
Filing: 1980-08-29
•
Granted: 1982-02-16
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Expires: 2000-08-29
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Abstract

Abstract Disclosed are disperse dyes for the dyeing of synthetic fibers such as cellulose acetate, triacetate, polyamide and especially polyester and its blends, which have the general formula ##STR1## in which R 1 and R 2 may be the same or different and are selected, for example, from hydrogen, aryl, benzyl, cyclohexyl, and C 1 -C 6 alkyl optionally substituted by Cl, CN, OC 2 H 4 OC 2 H 5 , C 1 -C 4 alkoxy, aryl, ##STR2## NHCONHPh, OCONHPh, phthalimido, succinimido or mercaptobenzthiazolyl, and R 1 and R 2 may form a 5- or 6-membered ring with the ##STR3## which ring may or may not contain a S, N, or O atom; R 3 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; R 2 and R 3 may form a 5 or 6 membered ring preferably substituted by 1-3 methyl groups; R 4 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; and R 5 is selected from 3-pyridyl, 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl and 2-thienyl, which R 5 heterocycles may be substituted by Cl, Br, NO 2 , CN, aryl, aryl substituted by Cl, Br, NO 2 or CN, C 1 -C 4 alkyl or COOR 6 wherein R 6 is C 1 -C 4 alkyl or aryl.

Inventors

  • 👤 Keith Hunt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 12:38
CPC Classifications
C; C09; C09B; C09B23/00; C09B23/14; C09B23/143; C09B23/145

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 202 words
A compound of the formula ##STR44## in which R 1 and R 2 are the same or different and selected from hydrogen, aryl, benzyl, cyclohexyl, C 1 -C 6 alkyl, C 1 -C 6 alkyl substituted with Cl, CN, OC 2 H 4 OC 2 H 5 , C 1 -C 4 alkoxy, aryl, ##STR45## in which the aryl, and the C 1 -C 10 alkyl of the preceding substituent are unsubstituted or substituted with Cl, Br, CN, NO 2 , CO--alkyl, CO--aryl, alkoxy, aryloxy, CO--O--alkyl or CO--O--aryl, ##STR46## NHCONHPh, OCONHPh, phthalimido, succinimido and mercaptobenzothiazolyl; ##STR47## is selected from piperidino, morpholino, thiomorpholino, and piperazino; R 3 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; ring A is unsubstituted or substituted with 1-3 methyl groups; R 4 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; and R 5 is selected from 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl, and these heterocycles substituted with Cl, Br, NO 2 , CN, aryl, aryl substituted with Cl, Br, NO 2 , or CN, C 1 -C 4 alkyl, or COOR 6 wherein R 6 is C 1 -C 4 alkyl or aryl.
Claim 2
Dependent Claim 202 words
A compound of the formula ##STR44## in which R 1 and R 2 are the same or different and selected from hydrogen, aryl, benzyl, cyclohexyl, C 1 -C 6 alkyl, C 1 -C 6 alkyl substituted with Cl, CN, OC 2 H 4 OC 2 H 5 , C 1 -C 4 alkoxy, aryl, ##STR45## in which the aryl, and the C 1 -C 10 alkyl of the preceding substituent are unsubstituted or substituted with Cl, Br, CN, NO 2 , CO--alkyl, CO--aryl, alkoxy, aryloxy, CO--O--alkyl or CO--O--aryl, ##STR46## NHCONHPh, OCONHPh, phthalimido, succinimido and mercaptobenzothiazolyl; ##STR47## is selected from piperidino, morpholino, thiomorpholino, and piperazino; R 3 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; ring A is unsubstituted or substituted with 1-3 methyl groups; R 4 is H, Cl, Br, C 1 -C 4 alkyl or C 1 -C 4 alkoxy; and R 5 is selected from 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl, and these heterocycles substituted with Cl, Br, NO 2 , CN, aryl, aryl substituted with Cl, Br, NO 2 , or CN, C 1 -C 4 alkyl, or COOR 6 wherein R 6 is C 1 -C 4 alkyl or aryl.
Claim 3
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR48##
Claim 4
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR49##
Claim 5
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR50##
Claim 6
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR51##
Claim 7
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR52##

References Cited (Backward Citations)

US2850520A Cited
US2953561A Cited
US3157663A Cited
US3890364A Cited
US3969346A Cited
US3917604A Cited
US3920720A Cited
US4077962A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-15 1985-08-17 1986-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-15 1989-08-17 1990-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-15 1993-08-17 1994-02-16 $7700.00 Window Closed / Lapsed

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