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US4077962A Expired / Lapsed US ⏱️ 0.0 years remaining

Styryl dyestuffs

Assignee: Bayer AG
•
Filing: 1975-09-24
•
Granted: 1978-03-07
•
Expires: 1995-09-24
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Abstract

Abstract The invention relates to water-insoluble styryl dyestuffs of the formula ##STR1## in which A is aryl B is an alkylene bridge, D denotes the remaining members of a heterocycle Y denotes a non-ionic substituent, n is 0, 1, 2 or 3 and Z denotes a cyano group or a carboxylic acid ester group. The dyestuffs are outstanding suitable for the dyeing of synthetic fibre materials which are dyed in greenish-yellow shades with good fastness properties, especially good resistance to hydrolysis.

Inventors

  • 👤 Hermann Beecken

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 22:44
CPC Classifications
C; C09; C09B; C09B23/00; C09B23/14; C09B23/143; D; D06; D06P; D06P1/00; D06P1/16

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 145 words
Water-insoluble styryl dyestuffs of the formula ##STR127## wherein V 1 , V 2 and V 4 , independently of each other, are hydrogen, methyl, ethyl, propyl, or butyl; V 3 is hydrogen or chlorine; A is phenyl, phenyl substituted 1-5 times with chlorine or methyl, or phenyl monosubstituted with bromine cyclohexyl, phenyl, benzyl, α,α-dimethylbenzyl, methoxy, ethoxy, phenoxy, benzyloxy, tertiary-butyl, methylmercapto, phenylmercapto, chlorophenoxy, or methylphenoxy; B is C 2 - to C 5 -alkylene which is unsubstituted or substituted by C 1 -C 4 -alkoxy, C 3 -C 5 -alkenyloxy, benzyloxy, phenoxy, phenyl, or mono-, di-, or tri-substituted benzyloxy, phenxoy, or phenyl wherein the substituents are methyl, ethyl, bromo, or chloro; Z is cyano or --CO 2 R; R is methyl, ethyl, propyl, n-butyl, benzyl, cyclohexyl, p-chlorobenzyl, phenylethyl, γ-phenylpropyl, β-(p-tolyl)ethyl, isopropyl, ethoxyethyl, cyanoethyl, methoxypropyl, or phenoxyethyl, and Y is hydrogen, methyl, methoxy, ethyl, ethoxy, or chloro.
Claim 2
Dependent Claim 145 words
Water-insoluble styryl dyestuffs of the formula ##STR127## wherein V 1 , V 2 and V 4 , independently of each other, are hydrogen, methyl, ethyl, propyl, or butyl; V 3 is hydrogen or chlorine; A is phenyl, phenyl substituted 1-5 times with chlorine or methyl, or phenyl monosubstituted with bromine cyclohexyl, phenyl, benzyl, α,α-dimethylbenzyl, methoxy, ethoxy, phenoxy, benzyloxy, tertiary-butyl, methylmercapto, phenylmercapto, chlorophenoxy, or methylphenoxy; B is C 2 - to C 5 -alkylene which is unsubstituted or substituted by C 1 -C 4 -alkoxy, C 3 -C 5 -alkenyloxy, benzyloxy, phenoxy, phenyl, or mono-, di-, or tri-substituted benzyloxy, phenxoy, or phenyl wherein the substituents are methyl, ethyl, bromo, or chloro; Z is cyano or --CO 2 R; R is methyl, ethyl, propyl, n-butyl, benzyl, cyclohexyl, p-chlorobenzyl, phenylethyl, γ-phenylpropyl, β-(p-tolyl)ethyl, isopropyl, ethoxyethyl, cyanoethyl, methoxypropyl, or phenoxyethyl, and Y is hydrogen, methyl, methoxy, ethyl, ethoxy, or chloro.
Claim 3
Dependent Claim 9 words
The dyestuffs of claim 1 wherein Z is cyano.
Claim 4
Dependent Claim 47 words
Water-insoluble styryl dyestuffs according to claim 1, of the formula ##STR128## wherein A, V 1 , V 2 , V 3 and V 4 have the meanings mentioned in claim 1, B" represents --CH 2 --CH 2 --, ##STR129## and Y" represents H or CH 3 .
Claim 5
Dependent Claim 20 words
Water-insoluble styryl dyestuffs according to claim 1, of the formula ##STR130## wherein A has the meaning mentioned in claim 1.
Claim 6
Dependent Claim 11 words
Water-insoluble styryl dyestuff according to claim 1, of the formula ##STR131##
Claim 7
Dependent Claim 11 words
Water-insoluble styryl dyestuff according to claim 1, of the formula ##STR132##
Claim 8
Dependent Claim 11 words
Water-insoluble styryl dyestuff according to claim 1, of the formula ##STR133##
Claim 9
Dependent Claim 11 words
Water-insoluble styryl dyestuff according to claim 1, of the formula ##STR134##

References Cited (Backward Citations)

US3240783A Cited
US3247211A Cited
US3453280A Cited
US3595863A Cited
US4006178A Cited
US3917604A Cited
US4016191A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-06 1981-09-05 1982-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-06 1985-09-05 1986-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-06 1989-09-05 1990-03-07 $7700.00 Window Closed / Lapsed

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