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US4312985A Expired / Lapsed US ⏱️ 0.0 years remaining

Disperse dyes from heterocyclic acetonitriles

Assignee: Novartis Corp
•
Filing: 1980-08-29
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Granted: 1982-01-26
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Expires: 2000-08-29
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Abstract

Abstract Disclosed are disperse dyes for the dyeing of synthetic fibers such as cellulose acetate, triacetate, polyamide, and especially polyester and its blends, which have the general formula ##STR1## in which R 1 is selected from hydrogen, aryl, cyclohexyl, lower alkyl and lower alkyl substituted by Cl, CN, OC 2 H 4 OC 2 H 5 , ##STR2## lower alkoxy, aryl, NHCONHPh, OCONHPh, phthalimido, succinimido, or aryloxy, which aryloxy may be substituted by one or more of Cl, Br, NO 2 , CN, lower alkyl, lower alkoxy, aryl and aryloxy; R 2 is phenyl or phenyl substituted with 1-3 of lower alkyl, lower alkoxy, ##STR3## --CN, --Cl or --NO 2 ; R 3 is H, Cl, lower alkyl or lower alkoxy; R 1 and R 3 may form a 5 or 6 membered ring preferably substituted by 1-3 methyl groups; R 4 is H, Cl, lower alkyl or lower alkoxy; R 5 is selected from 3-pyridyl, 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl and 2-thienyl, which R 5 heterocycles may be substituted by Cl, Br, NO 2 , CN, aryl, aryl substituted by Cl, Br, NO 2 or CN, lower alkyl or COOR 6 wherein R 6 is lower alkyl or aryl; and n is 1-4.

Inventors

  • 👤 Keith Hunt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 13:30
CPC Classifications
C; C09; C09B; C09B23/00; C09B23/14; C09B23/143; C09B23/145

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 183 words
A compound of the formula ##STR164## in which R 1 is selected from hydrogen, aryl cyclohexyl, lower alkyl and lower alkyl substituted with Cl, CN, OC 2 H 4 OC 2 H 5 , ##STR165## lower alkoxy, aryl, NHCONHPh, OCONHPh, phthalimido, succinimido, aryloxy and aryloxy substituted with one or more of Cl, Br, NO 2 , CN, lower alkyl, lower alkoxy, aryl and aryloxy; R 2 is phenyl or phenyl substituted with 1-3 of lower alkyl, lower alkoxy, ##STR166## --CN, --Cl or --NO 2 ; R 3 is H, Cl, lower alkyl or lower alkoxy; R 1 and R 3 combined form --CH 2 CH 2 CH 2 -- unsubstituted or substituted with 1-3 methyl groups; R 4 is H, Cl, lower alkyl or lower alkoxy; R 5 is selected from 3-pyridyl, 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl and 2-thienyl, which R 5 heterocycles are unsubstituted or substituted with Cl, Br, NO 2 , CN, aryl, aryl substituted with Cl, Br, NO 2 or CN, lower alkyl, or COOR 6 wherein R 6 is lower alkyl or aryl; and n is 1-4.
Claim 2
Dependent Claim 183 words
A compound of the formula ##STR164## in which R 1 is selected from hydrogen, aryl cyclohexyl, lower alkyl and lower alkyl substituted with Cl, CN, OC 2 H 4 OC 2 H 5 , ##STR165## lower alkoxy, aryl, NHCONHPh, OCONHPh, phthalimido, succinimido, aryloxy and aryloxy substituted with one or more of Cl, Br, NO 2 , CN, lower alkyl, lower alkoxy, aryl and aryloxy; R 2 is phenyl or phenyl substituted with 1-3 of lower alkyl, lower alkoxy, ##STR166## --CN, --Cl or --NO 2 ; R 3 is H, Cl, lower alkyl or lower alkoxy; R 1 and R 3 combined form --CH 2 CH 2 CH 2 -- unsubstituted or substituted with 1-3 methyl groups; R 4 is H, Cl, lower alkyl or lower alkoxy; R 5 is selected from 3-pyridyl, 3-benzisothiazolyl, 2-benzothiazolyl, 2-benzoxazolyl, 2-quinoxalyl, 2-quinazolinonyl, 2-1,3,4-oxadiazolyl, 2-1,3,4-thiadiazolyl and 2-thienyl, which R 5 heterocycles are unsubstituted or substituted with Cl, Br, NO 2 , CN, aryl, aryl substituted with Cl, Br, NO 2 or CN, lower alkyl, or COOR 6 wherein R 6 is lower alkyl or aryl; and n is 1-4.
Claim 3
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR167##
Claim 4
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR168##
Claim 5
Dependent Claim 10 words
A compound according to claim 1 having the formula ##STR169##
Claim 6
Dependent Claim 10 words
A compound according to claim 1 havng the formula ##STR170##

References Cited (Backward Citations)

US2850520A Cited
US2953561A Cited
US3157663A Cited
US3890364A Cited
US3969346A Cited
US3917604A Cited
US3920720A Cited
US4077962A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-25 1985-07-27 1986-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-25 1989-07-27 1990-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-25 1993-07-27 1994-01-26 $7700.00 Window Closed / Lapsed

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