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US4299732A
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Process for the production of amorphous aluminosilicates and their use as catalysts
Assignee: BP PLC
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Filing: 1979-10-01
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Granted: 1981-11-10
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Expires: 1999-10-01
Abstract
Abstract Amorphous aluminosilicates useful as catalysts, particularly for the decomposition of methanol to synthesis gas, are produced by reacting a source of silica, a source of alumina, a source of alkali metal, water and one or more polyamines other than a diamine. A class of effective polyamines is that known as polyethylene poly amines of which triethylene is representative. The catalytic activity of the aluminosilicate may be enhanced in particular by incorporation of the metals copper, zinc, gallium, bismuth, chromium, thorium, iron, cobalt, ruthenium, rhodium, nickel, palladium, iridium or platinum.
Inventors
- 👤 William J. Ball
- 👤 Keith W. Palmer
- 👤 David G. Stewart
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 13:53
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/72; B01J21/00; B01J21/12; B01J29/00; B01J29/04; B01J29/041; C; C01; C01B; C01B3/00; C01B3/02; C01B3/22; C01B33/00; C01B33/20; C01B33/26; Y; Y10; Y10S; Y10S502/00; Y10S502/506; Y10S502/509; Y10S502/511
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
45 words
A process for the production of an amorphous aluminosilicate which process comprises mixing, under reaction conditions which effect formation of said aluminosilicate, a source of silica, a source of alumina, a source of alkali metal, water and one or more polyamines other than a diamine.
Claim 2
Dependent Claim
45 words
A process for the production of an amorphous aluminosilicate which process comprises mixing, under reaction conditions which effect formation of said aluminosilicate, a source of silica, a source of alumina, a source of alkali metal, water and one or more polyamines other than a diamine.
Claim 3
Dependent Claim
47 words
A process according to claim 1 wherein said polyamine is selected from polyethylene polyamines having the formula: ##STR4## wherein x is an integer greater than 1 and R 1 is selected from hydrogen, alkyl groups containing from 1 to 6 carbon atoms, cycloaliphatic groups and aromatic groups.
Claim 4
Dependent Claim
19 words
A process according to claim 2 wherein R 1 in said polyethylene polyamine having the formula (I) is hydrogen.
Claim 5
Dependent Claim
12 words
A process according to claim 1 wherein said polyamine is triethylene tetramine.
Claim 6
Dependent Claim
42 words
A process according to claim 1 wherein said polyamine has the formula: ##STR5## wherein x is an integer greater than 1 and R 1 is selected from hydrogen, alkyl groups containing from 1 to 6 carbon atoms, cycloaliphatic groups and aromatic groups.
Claim 7
Dependent Claim
59 words
A process according to claim 1 wherein said polyamine has the formula: ##STR6## wherein y=a, b, c . . . z, in which a is an integer greater than 1 and b, c . . . z are either zero or integers, R 3 is hydrogen or a monovalent organic radical and R 4 is a divalent organic radical.
Claim 8
Dependent Claim
44 words
A process according to claim 1 wherein said polyamine has the formula: H.sub.2 N.(CH.sub.2).sub.2 [NH.CH.sub.2.CH(R.sup.5).CH.sub.2 ].sub.x NH.sub.2 (IV) wherein R 5 is either a hydrogen atom or a methyl radical and x is an integer having a value in the range 1 to 10.
Claim 9
Dependent Claim
44 words
A process according to claim 1 wherein said polyamine has the formula: H.sub.2 N[CH.sub.2.CH.(R.sup.5).CH.sub.2 NH].sub.w (CH.sub.2).sub.2 [NH.CH.sub.2.CH(R.sup.5).CH.sub.2 ].sub.z NH.sub.2 (V) wherein R 5 is either a hydrogen atom or a methyl radical and w and z are integers in the range 1 to 10.
Claim 10
Dependent Claim
45 words
A process according to claim 1 wherein said conditions which effect formation of said aluminosilicate are a temperature in the range 80° to 210° C., a pressure in the range 70 to 400 psig and a reaction time in the range 20 to 100 hours.
Claim 11
Dependent Claim
96 words
A process according to claim 1 wherein in said mixture the ratio of said silica source to said alumina source is in the range from 10:1 to 150:1 based on the equivalent moles of silica and alumina in the respective sources, said alkali metal source is present in an amount of from 50 to 0.02 moles of alkali metal per mole equivalent of total silica and alumina in the respective sources and said polyamine is present in an amount from 50 to 0.02 moles per mole equivalent of total silica and alumina in the respective sources.
Claim 12
Dependent Claim
59 words
A catalyst composition suitable for use in the production of synthesis gas from methanol which composition consists of an amorphous aluminosilicate as produced by the process claimed in claim 1 and from 0.1 to 20% by weight of at least one metal selected from copper, zinc, gallium, bismuth, chromium, thorium, iron, cobalt, ruthenium, rhodium, nickel, palladium, iridium and platinum.
References Cited (Backward Citations)
US4107195A
Cited
US4139600A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-11-09 | 1985-05-11 | 1985-11-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-11-09 | 1989-05-11 | 1989-11-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-11-09 | 1993-05-11 | 1993-11-10 | $7700.00 | Window Closed / Lapsed |