Thermal stabilization of polyalkylene terephthalate resin compositions

Claim 2

A molding composition comprising (a) polyalkylene terephthalate having an inherent viscosity of at least 0.4 wherein the alkylene moiety contains 2-4 carbon atoms, (b) 0-50% by weight of reinforcing material, said weight based on polyalkylene terephthalate and reinforcing material, (c) 1-25% by weight of an ionic hydrocarbon copolymer of an α-olefin of 2-5 carbon atoms and an α,β-ethylenically unsaturated carboxylic acid of 3-5 carbon atoms in which the carboxyl groups have been partially neutralized with metal cations, said weight based on polyalkylene terephthalate and copolymer, and (d) 0.1-5% by weight of a silicone resin of the general formula ##STR4## wherein R is lower alkyl or phenyl, R' and R" are each independently a hydrocarbyl group of 1-20 atoms and one of R' and R" can be hydrogen, and n is an integer of between about 5 and 500, said weight based on polyalkylene terephthalate and silicone resin.

Claim 3

The composition of claim 1 wherein the polyalkylene terephthalate is polyethylene terephthalate.

Claim 4

The composition of claims 1 or 2 wherein the ionic hydrocarbon copolymer is a copolymer of ethylene and methacrylic acid in which the carboxyl groups are partially neutralized with sodium or potassium.

Claim 5

The composition of claims 1 or 2 wherein the silicone resin is a poly(dimethylsiloxane) of between 10,000-100,000 centistokes viscosity.

Claim 6

The composition of claim 3 wherein the silicone resin is a poly(dimethylsiloxane) of between 10,000-100,000 centistokes viscosity.

Claim 7

A molding composition comprising (a) polyethylene terephthalate having an inherent viscosity of at least 0.4; (b) 0-50% by weight of reinforcing material, said weight based on polyethylene terephthalate and reinforcing material, (c) 1-12% by weight of an ionic hydrocarbon copolymer of an α-olefin, of 2-5 carbon atoms and an α,β-ethylenically unsaturated carboxylic acid of 3-5 carbon atoms in which the carboxyl groups have been partially neutralized with Na + of K + cations, said weight based on polyethylene terephthalate and copolymer, (d) 0.1-5% by weight of a silicone resin of the general formula ##STR5## wherein R is lower alkyl or phenyl, R' and R" are each independently a hydrocarbyl group of 1-20 atoms and one of R' and R" can be hydrogen, and n is an integer of between about 5 and 500, said weight based on polyethylene terephthalate and silicone resin, (e) 1-12 percent by weight of a low molecular weight compound selected from an organic ester, ketone, sulfone sulfoxide, nitrile or amide.

Claim 8

A molding composition comprising (a) polyethylene terephthalate having an inherent viscosity of at least 0.4; (b) 0-50% by weight of reinforcing material, said weight based on polyethylene terephthalate and reinforcing material, (c) 1-12% by weight of an ionic hydrocarbon copolymer of an α-olefin, of 2-5 carbon atoms and an α,β-ethylenically unsaturated carboxylic acid of 3-5 carbon atoms in which the carboxyl groups have been partially neutralized with Na + of K + cations, said weight based on polyethylene terephthalate and copolymer, (d) 0.1-5% by weight of a silicone resin of the general formula ##STR5## wherein R is lower alkyl or phenyl, R' and R" are each independently a hydrocarbyl group of 1-20 atoms and one of R' and R" can be hydrogen, and n is an integer of between about 5 and 500, said weight based on polyethylene terephthalate and silicone resin, (e) 1-12 percent by weight of a low molecular weight compound selected from an organic ester, ketone, sulfone sulfoxide, nitrile or amide.

Claim 9

The composition of claim 6 wherein the ionic hydrocarbon copolymer is a copolymer of ethylene and methacrylic acid in which the carboxyl groups are partially neutralized with sodium.

Claim 10

The compositions of claims 6 or 7 wherein the compound of component (e) is an organic ester of an aromatic carboxylic acid of 7-11 carbon atoms containing at least 1 carboxyl group per aromatic nucleus and an alcohol selected from those of the formula (HOCH 2 ) x R' wherein x is 1, 2 or 3 and R' is a hydrocarbon radical of 2-15 carbon atoms, of those of the formula HO(R"0) y R"' wherein y is a cardinal number between 1 and 15, R" is a hydrocarbon radical of 2-15 carbon atoms, and R"' is --H or a hydrocarbon radical of 2-20 carbon atoms.

Claim 11

The composition of claims 6 or 7 wherein the silicone resin is a poly(diemethylsiloxane) of between 10,000-100,000 centistokes viscosity.