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US4219628A Expired / Lapsed US ⏱️ 0.0 years remaining

Molding composition from polyester blends

Assignee: Eastman Chemical Co
•
Filing: 1979-04-02
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Granted: 1980-08-26
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Expires: 1999-04-02
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Abstract

Abstract Polyester composition characterized by a balance of physical properties more suitable for molding purposes than possible with the polyesters themselves, including blends of a polyester, poly(ethylene-co-propylene) rubber (EPR) and an ionomer of poly(ethylene-co-acrylic acid); the polyesters being selected from poly(tetramethylene terephthalate) (PBT), poly(1,4-cyclohexylenedimethylene terephthalate) (PCDT), and poly(1,4-cyclohexylenedimethylene terephthalate) (PCDT) modified with up to about 10 percent by weight of poly(oxyethylene) glycol having a molecular weight of about 500 to about 2000.

Inventors

  • 👤 Doyle A. Weemes
  • 👤 Robert W. Seymour

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:12
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 224 words
A polyester composition having a balance of properties suitable for molding purposes, said balance of properties including a flexural modulus of at least 200,000 psi, a heat deflection temperature at 264 psi of at least 50° C., a tensile strength of at least 5000 psi, a notched Izod impact strength at 23° C. of at least 0.7 foot-pounds per inch, an unnotched Izod impact strength at 23° C. of no break, and a Rockwell Hardness using the R scale of at least 90; said polyester composition comprising an admixture of (A) from about 70 to about 90 percent by weight of a polyester having an inherent viscosity of about 0.5 to about 1.5, and selected from (1) poly(tetramethylene terephthalate), (2) poly(1,4-cyclohexylenedimethylene terephthalate), and (3) poly(1,4-cyclohexylenedimethylene terephthalate) modified with up to about 10 percent by weight of poly(oxyethylene) glcyol having a molecular weight of about 500 to about 2000. (B) from about 25 to about 5 percent by weight of poly(ethylene-co-propylene) rubber having a melt flow at 230° C. ranging from about 0.1 to about 20.0 grams/10 minutes, and (C) from about 5 to about 25 percent by weight of an ionomer of poly(ethylene-co-acrylic acid) with about 50 percent of the acrylic acid converted to a metal salt and having a melt index at 190° C. ranging from about 3 to about 20 grams/10 minutes.
Claim 2
Dependent Claim 224 words
A polyester composition having a balance of properties suitable for molding purposes, said balance of properties including a flexural modulus of at least 200,000 psi, a heat deflection temperature at 264 psi of at least 50° C., a tensile strength of at least 5000 psi, a notched Izod impact strength at 23° C. of at least 0.7 foot-pounds per inch, an unnotched Izod impact strength at 23° C. of no break, and a Rockwell Hardness using the R scale of at least 90; said polyester composition comprising an admixture of (A) from about 70 to about 90 percent by weight of a polyester having an inherent viscosity of about 0.5 to about 1.5, and selected from (1) poly(tetramethylene terephthalate), (2) poly(1,4-cyclohexylenedimethylene terephthalate), and (3) poly(1,4-cyclohexylenedimethylene terephthalate) modified with up to about 10 percent by weight of poly(oxyethylene) glcyol having a molecular weight of about 500 to about 2000. (B) from about 25 to about 5 percent by weight of poly(ethylene-co-propylene) rubber having a melt flow at 230° C. ranging from about 0.1 to about 20.0 grams/10 minutes, and (C) from about 5 to about 25 percent by weight of an ionomer of poly(ethylene-co-acrylic acid) with about 50 percent of the acrylic acid converted to a metal salt and having a melt index at 190° C. ranging from about 3 to about 20 grams/10 minutes.
Claim 3
Dependent Claim 70 words
A polyester composition as defined in claim 1, wherein said admixture comprises about 75 to about 85 percent by weight of said polyester, at least 5 to about 20 percent by weight of said poly(ethylene-co-propylene) rubber, and at least 5 to about 20 percent by weight of said poly(ethylene-co-acrylic acid) such that the sum of the percents of poly(ethylene-co-propylene) rubber and poly(ethylene-co-acrylic acid) is between about 15 and about 25.
Claim 4
Dependent Claim 39 words
A polyester composition as defined in claim 1, wherein said poly(ethylene-co-propylene) rubber has a melt flow at 230° C. of about 0.1 gram/10 minutes and comprises about 45 percent by weight ethylene and about 55 percent by weight propylene.
Claim 5
Dependent Claim 38 words
A polyester composition as defined in claim 2, wherein said polyester comprises about 80 percent by weight of poly(tetramethylene terephthalate), said poly(ethylene-co-propylene) rubber comprises about 10 percent by weight and said ionomer comprises about 10 percent by weight.
Claim 6
Dependent Claim 59 words
A polyester composition as defined in claim 1, wherein the polyester of said admixture is said poly(tetramethylene terephthalate), said composition having a notched Izod impact strength at 23° C. of at least 1.5 foot-pounds per inch and at -40° C. of at least 0.8 foot-pounds per inch, and an unnotched Izod impact strength at -40° C. of no break.

References Cited (Backward Citations)

DE2139125A1 Cited
US4013613A Cited
US4122061A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-08-26 1984-02-25 1984-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-08-26 1988-02-25 1988-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-08-26 1992-02-25 1992-08-26 $7700.00 Window Closed / Lapsed

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