Stabilizers for cycloaliphatic epoxide containing compositions

Claim 2

A stabilized curable composition comprising a cycloaliphatic epoxide, a Bronsted or Lewis acid catalyst and a stabilizing amount of a compound containing at least one nitrile and/or isocyanate group.

Claim 3

A composition as in claim 1, wherein the cycloaliphatic epoxide is a cycloaliphatic diepoxide.

Claim 4

A composition as in claim 2, wherein the cycloaliphatic epoxide is selected from 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis(3,4-epoxy-6-methylcyclohexylmethyl)adipate, bis(3,4-epoxycyclohexylmethyl)adipate, bis(2,3-epoxycyclopentyl)ether, vinyl cyclohexane diepoxide, 2-(3,4-epoxycyclohexyl)-5,5-spiro(2,3-epoxycyclohexane)-m-dioxane.

Claim 5

A composition as in claim 1, which contains an hydroxy containing compound.

Claim 6

A composition as in claim 4, wherein the hydroxy containing compound is a glycol or a polyol.

Claim 7

A composition as in claim 5, wherein the glycol or polyol is selected from ethylene glycol, diethylene glycol, 2,2,4-trimethyl-1,3-pentanediol, dipropylene glycol, propylene glycol, 2,2-dimethyl-1,3-propanediol, polypropylene glycol having an average molecular weight of about 150 to about 600, and having 2 to 4 terminal hydroxyl groups, triethylene glycol, 1,4-cyclohexanedimethanol, 2,2-dimethyl-3-hydroxypropyl 2,2-dimethyl-3-hydroxypropionate, 1,3-butanediol, tetraethylene glycol, trimethylol propane, 1,4-butanediol, 1,6-hexanediol, tripropylene glycol, 1,2,6-hexanetriol, 1,3-propanediol and the ethylene and propylene oxide adducts of 2,2-bis(4-hydroxyphenyl)propane.

Claim 8

A composition as in claim 5, wherein the polyol is selected from the polycaprolactone ester of a polyol in which from about 1 to about 5 mols of caprolactone are esterified with trimethylol propane or diethylene glycol.

Claim 9

A composition as in claim 5, wherein the polyol is an ester diol alkoxylate.

Claim 10

A composition as in claim 1, wherein the Bronsted or Lewis acid catalyst is selected from the stannous salt of trifluorosulfonic acid, diethylammonium salt of trifluorosulfonic acid, trifluorosulfonic acid, boron trifluoride etherate, and a boron trifluoride amine.

Claim 11

A composition as in claim 9 wherein the catalyst is (CF 3 SO 3 ) 2 Sn.

Claim 12

A composition as in claim 1, wherein the compound containing nitrile group is monomeric or polymeric.

Claim 13

A composition as in claim 11, wherein the monomeric nitrile is selected from alkyl nitriles, aromatic nitriles, vinyl nitriles and acrylonitrile.

Claim 14

A composition as in claim 12, wherein the monomeric nitrile is selected from acetonitrile, methoxyacrylonitrile, 1,5-dicyanopentane, isobutyronitrile, 4-phenylbutyronitrile, 2-chloroacrylonitrile, phenyl acetonitrile, hydracrylonitrile, o-tolunitrile, dodecyl nitrile, oleylnitrile, isophthalonitrile and phenyl-sulfonylacetonitrile.

Claim 15

A composition as in claim 12, wherein the monomeric nitrile is 2-ethylhexyl-2-cyano-3,3'-diphenyl acrylate.

Claim 16

A composition as in claim 11, wherein the polymeric nitrile is selected from styrene/acrylonitrile copolymer, acrylonitrile/butadiene copolymer and polyacrylonitrile.

Claim 17

A composition as in claim 1, wherein the compound containing an isocyanate group is a mono-, di- or polyfunctional isocyanate.

Claim 18

A composition as in claim 16, wherein the compound containing the isocyanate group is a polyfunctional aliphatic isocyanate having an isocyanate content of about 23 percent and an average equivalent weight of about 183.

Claim 19

A composition as in claim 16, wherein the compound containing the isocyanate group is selected from 4,4'-diphenylomethane diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate and 1,5-dicyanopentane.

Claim 20

A composition as in claim 1, wherein the stabilizing amount of the nitrile compound is from about 0.25 to about 50 equivalents of nitrile based in the moles of active catalyst.

Claim 21

A composition as in claim 19, wherein the stabilizing amount is from about 1 to about 20 equivalents of nitrile based on the moles of active catalyst.

Claim 22

A composition as in claim 1, wherein the stabilizing amount of the compound containing an isocyanate group is from about 1 to about 150 equivalents of isocyanate based on the moles of active catalyst.

Claim 23

A composition as in claim 21, wherein the stabilizing amount is from about 5 to about 150 equivalents of isocyanate based on the moles of active catalyst.

Claim 24

A composition as in claim 1, which contain a fiber selected from fiberglass, carbon fibers, and aromatic polyamide fibers.

Claim 25

A molded article produced from the composition of claim 1.

Claim 26

A molded article as in claim 24, which contains from about 15 to about 75 weight percent of fibers.

Claim 27

A molded article as in claim 25, wherein the fiber is fiberglass.