Patent US4294718A successfully refreshed from Google Patents.
US4294718A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Non-gelling inorganic salt crutcher slurries
Assignee: Colgate Palmolive Co
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Filing: 1980-03-10
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Granted: 1981-10-13
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Expires: 2000-03-10
Abstract
Abstract Gelation and setting of desirably miscible and pumpable crutcher slurries comprising sodium carbonate, sodium bicarbonate and sodium silicate in an aqueous medium are retarded and often prevented by the addition to such medium of a citric material, such as citric acid and/or water soluble citrate, and magnesium sulfate. Alternatively, magnesium citrate may be employed. The addition of the citric material and magnesium sulfate (or magnesium citrate) lengthens appreciably the workable crutcher time before setting, increasing it over such working time for similar crutcher mixes containing the citric material but not containing magnesium sulfate. The improved workability of the crutcher mix permits the making of higher solids content crutcher slurries, thereby resulting in significant energy savings and increases in production rates when the crutcher slurries are subsequently spray dried to free flowing inorganic salt base bead form, from which detergent compositions may be made by post-spraying with nonionic synthetic organic detergent in liquid state.
Inventors
- 👤 James A. Kaeser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 09:58
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/04; C11D3/046; C11D3/08; C11D3/10; C11D3/16; C11D3/20; C11D3/2075; C11D3/2086
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
193 words
A method of retarding or preventing the gelation of a miscible and pumpable crutcher slurry containing from about 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate, and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, which comprises preparing a crutcher slurry of the described composition containing from 0.1 to 2% of a citric material selected from the group consisting of citric acid, water soluble citrate and mixtures thereof, and from 0.1 to 1.4% of magnesium sulfate, with the total of such citric material and magnesium sulfate, in combination, being gelation retarding and at least 0.4% of the slurry, and mixing such composition in the crutcher during preparation thereof.
Claim 2
Independent Claim
193 words
A method of retarding or preventing the gelation of a miscible and pumpable crutcher slurry containing from about 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate, and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, which comprises preparing a crutcher slurry of the described composition containing from 0.1 to 2% of a citric material selected from the group consisting of citric acid, water soluble citrate and mixtures thereof, and from 0.1 to 1.4% of magnesium sulfate, with the total of such citric material and magnesium sulfate, in combination, being gelation retarding and at least 0.4% of the slurry, and mixing such composition in the crutcher during preparation thereof.
Claim 3
Dependent Claim
127 words
A method according to claim 1 wherein the crutcher slurry contains from 50 to 65% of solids and 50 to 35% of water, of which solids content 55 to 80% is sodium bicarbonate, 10 to 25% is sodium carbonate and 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.6, the ratio of sodium bicarbonate:sodium carbonate is within the range of 3:1 to 6:1, the ratio of sodium carbonate:sodium silicate is within the range of 2:5 to 5:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 4:1 to 8:1, and wherein the percentages of gelation preventing citric material and magnesium sulfate are in the ranges of 0.2 to 0.8 and 0.2 to 1.2, respectively.
Claim 4
Dependent Claim
48 words
A method according to claim 2 wherein the crutcher slurry is at a temperature in the range of 35 to 70° C., at atmospheric pressure, and the citric material and magnesium sulfate are incorporated in the slurry before addition thereto of at least some of the sodium silicate.
Claim 5
Dependent Claim
127 words
A method according to claim 3 wherein the crutcher slurry contains from 58 to 64% of solids and 42 to 36% of water, of which solids content 70 to 75% is sodium bicarbonate, 13 to 19% is sodium carbonate and 8 to 15% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.4, the ratio of sodium bicarbonate:sodium carbonate is within the range of 4:1 to 5:1, the ratio of sodium carbonate:sodium silicate is within the range of 1:1 to 3:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 5:1 to 7:1, and wherein the percentages of gelation preventing citric material and magnesium sulfate are in the ranges of 0.25 to 0.6 and 0.4 to 1.0, respectively.
Claim 6
Dependent Claim
54 words
A method according to claim 1 wherein mixing is at an elevated temperature, in the range of 40° to 70° C., the citric material and magnesium sulfate are incorporated in the slurry before the sodium silicate, and mixing is continued for at least one hour after completion of the making of the crutcher slurry.
Claim 7
Dependent Claim
65 words
A method according to claim 4 wherein the crutcher slurry temperature is from 40° to 60° C., mixing is effected at least two hours after completion of the making of the crutcher slurry, and at least a part of the crutcher mix is pumped out of the crutcher to a spray drying tower and is spray dried therein after said mixing after said two hours.
Claim 8
Dependent Claim
19 words
A method according to claim 6 wherein citric acid is the gelation preventing citric material in the crutcher slurry.
Claim 9
Dependent Claim
19 words
A method according to claim 6 wherein sodium citrate is the gelation preventing citric material in the crutcher slurry.
Claim 10
Dependent Claim
19 words
A method according to claim 1 wherein citric acid is the gelation preventing citric material in the crutcher slurry.
Claim 11
Dependent Claim
19 words
A method according to claim 1 wherein sodium citrate is the gelation preventing citric material in the crutcher slurry.
Claim 12
Dependent Claim
20 words
A method according to claim 1 wherein from 0.1 to 10% of the crutcher slurry is of adjuvant(s) and/or diluent(s).
Claim 13
Dependent Claim
170 words
A miscible and pumpable crutcher slurry comprising from 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, and a gelation retarding proportion of a combination of 0.1 to 2% of a citric material selected from the group consisting of citric acid, water soluble citrate and mixtures thereof, and from 0.1 to 1.4% of magnesium sulfate, with the total of such citric material and magnesium sulfate, in combination, being gelation retarding and at least 0.4% of the slurry.
Claim 14
Dependent Claim
170 words
A miscible and pumpable crutcher slurry comprising from 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, and a gelation retarding proportion of a combination of 0.1 to 2% of a citric material selected from the group consisting of citric acid, water soluble citrate and mixtures thereof, and from 0.1 to 1.4% of magnesium sulfate, with the total of such citric material and magnesium sulfate, in combination, being gelation retarding and at least 0.4% of the slurry.
Claim 15
Dependent Claim
125 words
A crutcher slurry according to claim 12 comprising 50 to 65% of solids and 50 to 35% of water, of which solids content 55 to 80% is sodium bicarbonate, 10 to 25% is sodium carbonate and 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.6, in which the ratio of sodium bicarbonate:sodium carbonate is within the range of 3:1 to 6:1, the ratio of sodium carbonate:sodium silicate is within the range of 2:5 to 5:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 4:1 to 8:1, and wherein the percentages of gelation preventing citric material and magnesium sulfate are in the ranges of 0.2 to 8 and 0.2 to 1.2, respectively.
Claim 16
Dependent Claim
126 words
A crutcher slurry according to claim 13 comprising from 58 to 64% of solids and 42 to 36% of water, of which solids content 70 to 75% is sodium bicarbonate, 13 to 19% is sodium carbonate and 8 to 15% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.4, in which the ratio of sodium bicarbonate:sodium carbonate is within the range of 4:1 to 5:1, the ratio of sodium carbonate:sodium silicate is within the range of 1:1 to 3:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 5:1 to 7:1, and wherein the percentages of gelation preventing citric material and magnesium sulfate are in the ranges of 0.25 to 0.6 and 0.4 to 1.0, respectively.
Claim 17
Dependent Claim
16 words
A crutcher slurry according to claim 14 containing from 0.1 to 10% of adjuvant(s) and/or diluent(s).
Claim 18
Dependent Claim
80 words
A method of making a particulate base material in bead form, suitable for absorbing nonionic detergent to make a built heavy duty synthetic organic detergent composition, which comprises making a miscible and pumpable slurry in a crutcher by the method of claim 1, pumping the slurry out of the crutcher in ungelled and readily pumpable state and spray drying the slurry to particulate bead form, during which spray drying a portion of the sodium bicarbonate is converted to sodium carbonate.
Claim 19
Dependent Claim
8 words
A product of the process of claim 16.
Claim 20
Dependent Claim
68 words
A product according to claim 17 comprising from about 40 to 60% of sodium bicarbonate, 15 to 45% of sodium carbonate, 10 to 20% of sodium silicate, 0.1 to 3% of sodium citrate, 0.1 to 2% of magnesium sulfate, 0 to 10% of adjuvant(s) and/or diluent(s) and 1 to 10% of moisture, with the proportion of sodium bicarbonate being from 1.2 to 4 times that of sodium carbonate.
Claim 21
Independent Claim
155 words
A method of retarding or preventing the gelation of a miscible and pumpable crutcher slurry containing from about 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, which comprises preparing a crutcher slurry of the described composition, in which there was included from 0.3 to 3% of magnesium citrate or acid citrate, and mixing such composition in the crutcher during preparation thereof.
Claim 22
Independent Claim
155 words
A method of retarding or preventing the gelation of a miscible and pumpable crutcher slurry containing from about 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, which comprises preparing a crutcher slurry of the described composition, in which there was included from 0.3 to 3% of magnesium citrate or acid citrate, and mixing such composition in the crutcher during preparation thereof.
Claim 23
Dependent Claim
117 words
A method according to claim 19 wherein the crutcher slurry contains from 50 to 65% of solids and 50 to 35% of water, of which solids content 55 to 80% is sodium bicarbonate, 10 to 25% is sodium carbonate and 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.6, the ratio of sodium bicarbonate:sodium carbonate is within the range of 3:1 to 6:1, the ratio of sodium carbonate:sodium silicate is within the range of 2:5 to 5:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 4:1 to 8:1, and wherein the percentage of magnesium citrate is in the range of 0.3 to 1.2.
Claim 24
Dependent Claim
126 words
A miscible and pumpable crutcher slurry comprising from from 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, and a gelation retarding proporation of magnesium citrate, from 0.3 to 3% of the slurry.
Claim 25
Dependent Claim
126 words
A miscible and pumpable crutcher slurry comprising from from 40 to 70% of solids and 60 to 30% of water, of which solids content, on a 100% solids basis, about 55 to 85% is sodium bicarbonate, about 5 to 25% is sodium carbonate and about 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.4 to 1:3, with the ratio of sodium bicarbonate:sodium carbonate being within the range of about 2:1 to 8:1, the ratio of sodium carbonate:sodium silicate being within the range of about 1:3 to 3:1, and the ratio of sodium bicarbonate:sodium silicate being within the range of about 2:1 to 10:1, and a gelation retarding proporation of magnesium citrate, from 0.3 to 3% of the slurry.
Claim 26
Dependent Claim
115 words
A crutcher slurry according to claim 21 comprising 50 to 65% of solids and 50 to 35% of water, of which solids content 55 to 80% is sodium bicarbonate, 10 to 25% is sodium carbonate and 5 to 25% is sodium silicate of Na 2 O:SiO 2 ratio within the range of 1:1.6 to 1:2.6, the ratio of sodium bicarbonate:sodium carbonate is within the range of 3:1 to 6:1, the ratio of sodium carbonate:sodium silicate is within the range of 2:5 to 5:2 and the ratio of sodium bicarbonate:sodium silicate is within the range of 4:1 to 8:1, and wherein the percentage of gelation preventing magnesium citrate is in the range of 0.3 to 1.2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-12 | 1985-04-13 | 1985-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-12 | 1989-04-13 | 1989-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-12 | 1993-04-13 | 1993-10-13 | $7700.00 | Window Closed / Lapsed |