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US4293670A
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Blends of poly(aryl ether) resins and polyetherimide resins
Assignee: BP Corp North America Inc
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Filing: 1979-12-26
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Granted: 1981-10-06
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Expires: 1999-12-26
Abstract
Abstract Described herein are molding compositions of blends of a poly(aryl ether) resin and a polyetherimide resin. These compositions have improved environmental stress crack resistance.
Inventors
- 👤 Lloyd M. Robeson
- 👤 Markus Matzner
- 👤 Louis M. Maresca
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 11:48
CPC Classifications
C; C08; C08L; C08L71/00; C08L79/00; C08L79/04; C08L79/08; Y; Y10; Y10S; Y10S525/00; Y10S525/905; Y10S525/906; Y10S525/928
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
271 words
A molding composition comprising a blend of from about 95 to about 5 weight percent of a poly(aryl ether) and from about 5 to about 95 weight percent of a polyetherimide of the following formulae: ##STR29## wherein a is an integer greater than 1, to about 10,000 or more, --O--R 4 --O-- is attached to the 3 or 4 and 3' and 4' positions and R 4 is selected from (a) a substituted or unsubstituted aromatic radical such as ##STR30## (b) a divalent radical of the formula: ##STR31## wherein R 6 is independently C 1 to C 6 alkyl, or halogen and R 7 is selected from --O--, ##STR32## alkylene of 1 to 6 carbon atoms, cycloalkylene of 4 to 8 carbon atoms, alkylidene of 1 to 6 carbon atoms or cycloalkylidene of 4 to 8 carbon atoms, R 5 is selected from an aromatic hydrocarbon radical having from 6-20 carbon atoms and halogenated derivatives thereof, or alkyl substituted derivatives thereof, wherein the alkyl group contains 1 to 6 carbon atoms, alkylene and cycloalkylene radicals having from 2 to 20 carbon atoms, C 2 -C 8 alkylene terminated polydiorganosiloxane and a divalent radical of the formula ##STR33## wherein R 6 and R 7 are as previously defined and R 7 may be a direct bond; ##STR34## wherein --O--Z< is a member selected from ##STR35## wherein R 8 is independently hydrogen, lower alkyl or lower alkoxy ##STR36## wherein the oxygen may be attached to either ring and located ortho or para to one of the bonds to the anhydride carbonyl group wherein a, R 4 and R 5 are as previously defined.
Claim 2
Dependent Claim
271 words
A molding composition comprising a blend of from about 95 to about 5 weight percent of a poly(aryl ether) and from about 5 to about 95 weight percent of a polyetherimide of the following formulae: ##STR29## wherein a is an integer greater than 1, to about 10,000 or more, --O--R 4 --O-- is attached to the 3 or 4 and 3' and 4' positions and R 4 is selected from (a) a substituted or unsubstituted aromatic radical such as ##STR30## (b) a divalent radical of the formula: ##STR31## wherein R 6 is independently C 1 to C 6 alkyl, or halogen and R 7 is selected from --O--, ##STR32## alkylene of 1 to 6 carbon atoms, cycloalkylene of 4 to 8 carbon atoms, alkylidene of 1 to 6 carbon atoms or cycloalkylidene of 4 to 8 carbon atoms, R 5 is selected from an aromatic hydrocarbon radical having from 6-20 carbon atoms and halogenated derivatives thereof, or alkyl substituted derivatives thereof, wherein the alkyl group contains 1 to 6 carbon atoms, alkylene and cycloalkylene radicals having from 2 to 20 carbon atoms, C 2 -C 8 alkylene terminated polydiorganosiloxane and a divalent radical of the formula ##STR33## wherein R 6 and R 7 are as previously defined and R 7 may be a direct bond; ##STR34## wherein --O--Z< is a member selected from ##STR35## wherein R 8 is independently hydrogen, lower alkyl or lower alkoxy ##STR36## wherein the oxygen may be attached to either ring and located ortho or para to one of the bonds to the anhydride carbonyl group wherein a, R 4 and R 5 are as previously defined.
Claim 3
Dependent Claim
73 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) has recurring units of the formula: O--E--O--E'-- wherein E is the residuum of the dihydric phenol and E' is the residuum of the benzenoid compound having an inert electron withdrawing group in at least one of the positions ortho and para to the valence bonds wherein both of said residuum are valently bonded to the ether oxygens through aromatic carbon atoms.
Claim 4
Dependent Claim
19 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) has repeating units of the formula: ##STR37##
Claim 5
Dependent Claim
19 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) has repeating units of the formula: ##STR38##
Claim 6
Dependent Claim
19 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) has repeating units of the formula: ##STR39##
Claim 7
Dependent Claim
15 words
A composition as in claim 1 wherein the polyetherimide is of the following formulae: ##STR40##
Claim 8
Dependent Claim
25 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) is used in amounts of from about 80 to about 20 weight percent.
Claim 9
Dependent Claim
24 words
A molding composition as defined in claim 1 wherein the polyetherimide is used in amounts of from about 20 to about 80 weight percent.
Claim 10
Dependent Claim
37 words
A molding composition as defined in claim 1 wherein the poly(aryl ether) is used in amounts of from 25 to 75 weight percent and the polyetherimide is used in amounts of from 75 to 25 weight percent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-05 | 1985-04-06 | 1985-10-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-05 | 1989-04-06 | 1989-10-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-05 | 1993-04-06 | 1993-10-06 | $7700.00 | Window Closed / Lapsed |