Patent US4884244A successfully refreshed from Google Patents.
Patent US4293466A successfully refreshed from Google Patents.
US4293466A
Expired / Lapsed
US
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Piperidine phosphite stabilizers for polymers and polymers stabilized thereby
Assignee: Montedison SpA
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Filing: 1978-12-05
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Granted: 1981-10-06
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Expires: 1998-12-05
Abstract
Abstract New derivatives of N,N'-4-piperidyl-tetraalkyl-substituted alkylene diamines are disclosed. These new compounds are useful for stabilizing thermoplastic polymers, in particular polyolefins, against sunlight, heat and oxidation. A process for producing the new compounds is also disclosed, as well as the use thereof as stabilizers of polymers and polymeric compositions.
Inventors
- 👤 Piero Di Battista
- 👤 Renzo Fontanelli
- 👤 Francesco Gratani
- 👤 Giuseppe Nelli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-10 01:51
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/52; C08K5/529; C07; C07F; C07F9/00; C07F9/02; C07F9/547; C07F9/553; C07F9/576; C07F9/59
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
211 words
Compositions comprising synthetic thermoplastic polymers stabilized to sunlight, to heat and to ageing, and having incorporated therein, in an amount sufficient to prevent degradation of the polymer, a compound having general formula: ##STR6## wherein: each of R 1 , R 2 , R 3 and R 4 , which may be the same or different, may be an alkyl having 1 to 4 carbon atoms; R 5 may be a hydrogen atom or an alkyl having 1 to 4 carbon atoms; A is an alkylene group having 2 to 12 carbon atoms or a cycloalkylene group containing 3 to 12 carbon atoms; x is an integer from 1 to 10, and R 6 , R 7 , R 8 and R 9 , which may be the same or different, are each a linear or branched alkyl group having 1 to 20 carbon atoms or a simple or substituted aryl group having 6 to 20 carbon atoms or R 6 and R 7 together and R 8 and R 9 together may form a linear or branched alkylene group having 2 to 20 carbon atoms, or a simple or substituted arylene group having 6 to 20 carbon atoms or a simple or substituted cycloalkylene group having 3 to 20 carbon atoms.
Claim 2
Dependent Claim
211 words
Compositions comprising synthetic thermoplastic polymers stabilized to sunlight, to heat and to ageing, and having incorporated therein, in an amount sufficient to prevent degradation of the polymer, a compound having general formula: ##STR6## wherein: each of R 1 , R 2 , R 3 and R 4 , which may be the same or different, may be an alkyl having 1 to 4 carbon atoms; R 5 may be a hydrogen atom or an alkyl having 1 to 4 carbon atoms; A is an alkylene group having 2 to 12 carbon atoms or a cycloalkylene group containing 3 to 12 carbon atoms; x is an integer from 1 to 10, and R 6 , R 7 , R 8 and R 9 , which may be the same or different, are each a linear or branched alkyl group having 1 to 20 carbon atoms or a simple or substituted aryl group having 6 to 20 carbon atoms or R 6 and R 7 together and R 8 and R 9 together may form a linear or branched alkylene group having 2 to 20 carbon atoms, or a simple or substituted arylene group having 6 to 20 carbon atoms or a simple or substituted cycloalkylene group having 3 to 20 carbon atoms.
Claim 3
Dependent Claim
75 words
Compositions according to claim 1, in which, in formula (I), R 1 , R 2 , R 3 and R 4 are methyl; R 5 is hydrogen; x is an integer from 2 to 6; each of R 6 , R 7 , R 8 and R 9 is an alkyl having 10 to 16 carbon atoms or R 6 and R 7 together and R 8 and R 9 together form an arylene group.
Claim 4
Dependent Claim
31 words
Compositions according to claim 1, in which the compound of general formula (I) is present in an amount ranging from 0.01 to 5% by weight on the weight of the polymer.
Claim 5
Dependent Claim
12 words
Compositions according to claim 1, in which the polymer is a polyolefin.
Claim 6
Dependent Claim
31 words
Compositions according to claim 4, in which the compound of general formula (I) is present in an amount ranging from 0.01 to 2% by weight on the weight of the polyolefin.
Claim 7
Dependent Claim
15 words
Compositions according to claim 1, in which the polymer is polyvinyl chloride or polyvinylidene chloride.
Claim 8
Dependent Claim
31 words
Compositions according to claim 6, in which the compound of general formula (I) is contained in an amount ranging from 0.01 to 1% by weight on the weight of the polymer.
Claim 9
Dependent Claim
15 words
Compositions according to claim 1, in which the polymer is a polyurethane or a polyamide.
Claim 10
Dependent Claim
31 words
Compositions according to claim 8, in which the compound of general formula (I) is contained in an amount ranging from 0.01 to 5% by weight on the weight of the polymer.
Claim 11
Dependent Claim
41 words
Compositions according to claim 1, in which compound I is employed in admixture with at least one additive selected from the group consisting of oxy-benzotriazoles, oxy-benzophenones, Ni-stabilizers, metal soaps, phenolic antioxidants, phosphites, thioesters, hydroquinone derivatives, triazines, acyl-amino phenols, and benzyl phosphonates.
Claim 12
Dependent Claim
24 words
Compositions according to claim 10, in which the ratio of additive or additives to the compound of formula (I) is from 0.5:1 to 3:1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-05 | 1985-04-06 | 1985-10-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-05 | 1989-04-06 | 1989-10-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-05 | 1993-04-06 | 1993-10-06 | $7700.00 | Window Closed / Lapsed |