← Back to Patent Explorer
US4088629A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilization of synthetic polymers

Assignee: Bayer AG
•
Filing: 1976-10-06
•
Granted: 1978-05-09
•
Expires: 1996-10-06
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Stabilizers according to the invention are used for stabilizing synthetic polymers against discoloration and degradation under the effect of visible and/or UV light, heat and/or atmospheric influences.

Inventors

  • 👤 Paul Uhrhan
  • 👤 Reinhard Lantzsch
  • 👤 Harald Oertel
  • 👤 Ernst Roos
  • 👤 Dieter Arlt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:36
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 385 words
A process for stabilizing a synthetic polymer which comprises adding to the polymer a stabilizing amount of a compound of the formula: ##STR15## or a tautomer thereof wherein X is of the formula: ##STR16## wherein A is hydrogen, alkyl having 1 to 20 carbon atoms, alkenyl or alkinyl having 3 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms or --CH 2 --CHR 4 --OH wherein R 4 is hydrogen, methyl or phenyl; R 1 and R 2 are the same or different and are each alkyl having 1 to 12 carbon atoms or R 1 and R 2 together with the ring carbon atom to which they are attached form a cycloalkyl ring with 5 to 12 ring carbon atoms; R 3 is hydrogen, alkyl having b 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms, β-cyanoethyl, β-alkoxy carbonyl ethyl having 1 to 3 carbon atoms in the alkoxy moiety, aryl having 6 to 14 carbon atoms, --CH 2 --CHR 4 --OH wherein R 4 is hydrogen, methyl or phenyl, or ##STR17## wherein A, R 1 and R 2 are as defined above; Z has the same meaning as X or is --NUV wherein U and V are the same or different and are each hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms or aryl having 6 to 14 carbon atoms, or said aryl substituted by alkyl having 1 to 8 carbon atoms, alkoxy having 1 to 4 carbon atoms, hydroxy, nitro, chlorine or by bromine and wherein the radical U may also be R 5 -W wherein R 5 is aryl having 6 or 10 ring carbon atoms, said aryl substituted by chlorine, bromine, methyl or by methoxy, alkyl having 1 to 8 carbon atoms or aralkyl having 7 to 12 carbon atoms; W is --CO or --SO 2 and R 6 is hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 7 carbon atoms, aralkyl having 7 to 12 carbon atoms, aryl having 6 to 14 carbon atoms or said aryl substituted by alkyl having 1 to 8 carbon atoms, alkoxy having 1 to 4 carbon atoms, hydroxy, nitro, chlorine or by bromine.
Claim 2
Dependent Claim 385 words
A process for stabilizing a synthetic polymer which comprises adding to the polymer a stabilizing amount of a compound of the formula: ##STR15## or a tautomer thereof wherein X is of the formula: ##STR16## wherein A is hydrogen, alkyl having 1 to 20 carbon atoms, alkenyl or alkinyl having 3 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms or --CH 2 --CHR 4 --OH wherein R 4 is hydrogen, methyl or phenyl; R 1 and R 2 are the same or different and are each alkyl having 1 to 12 carbon atoms or R 1 and R 2 together with the ring carbon atom to which they are attached form a cycloalkyl ring with 5 to 12 ring carbon atoms; R 3 is hydrogen, alkyl having b 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms, β-cyanoethyl, β-alkoxy carbonyl ethyl having 1 to 3 carbon atoms in the alkoxy moiety, aryl having 6 to 14 carbon atoms, --CH 2 --CHR 4 --OH wherein R 4 is hydrogen, methyl or phenyl, or ##STR17## wherein A, R 1 and R 2 are as defined above; Z has the same meaning as X or is --NUV wherein U and V are the same or different and are each hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms or aryl having 6 to 14 carbon atoms, or said aryl substituted by alkyl having 1 to 8 carbon atoms, alkoxy having 1 to 4 carbon atoms, hydroxy, nitro, chlorine or by bromine and wherein the radical U may also be R 5 -W wherein R 5 is aryl having 6 or 10 ring carbon atoms, said aryl substituted by chlorine, bromine, methyl or by methoxy, alkyl having 1 to 8 carbon atoms or aralkyl having 7 to 12 carbon atoms; W is --CO or --SO 2 and R 6 is hydrogen, alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 7 carbon atoms, aralkyl having 7 to 12 carbon atoms, aryl having 6 to 14 carbon atoms or said aryl substituted by alkyl having 1 to 8 carbon atoms, alkoxy having 1 to 4 carbon atoms, hydroxy, nitro, chlorine or by bromine.
Claim 3
Dependent Claim 130 words
The process of claim 1 wherein R 1 and R 2 are the same or different and are alkyl having 1 to 4 carbon atoms or together with the ring carbon atom to which they are attached form a cyclohexyl ring; A is hydrogen or alkyl having 1 to 4 carbon atoms; R 3 is hydrogen, alkyl having 1 to 8 carbon atoms, cyclohexyl, methyl cyclohexyl, benzyl, β-cyanoethyl, 2-methoxy carbonyl ethyl or β-hydroxy ethyl; U and V are the same or different and are hydrogen, alkyl having 3 to 8 carbon atoms, cyclohexyl, benzyl or said aryl; R 5 is phenyl, chlorophenyl, bromophenyl, tolyl, methoxyphenyl, naphthyl or benzyl; W is --CO and R 6 is hydrogen, alkyl having 3 to 12 carbon atoms, cyclohexyl, phenyl, naphthyl, tolyl, chlorophenyl or nitrophenyl.
Claim 4
Dependent Claim 75 words
The process of claim 1 wherein R 1 and R 2 are methyl; A is hydrogen or methyl; R 3 is hydrogen, methyl, cyclohexyl, benzyl, β-cyanoethyl or β-hydroxy ethyl; U and V are the same or different and are propyl, isopropyl, butyl, isobutyl, t.-butyl, hexyl, cyclohexyl, phenyl, tolyl, t.-butyl phenyl, chlorophenyl or naphthyl; R 5 is phenyl, chlorophenyl, tolyl or methoxy phenyl; W is --CO and R 6 is hydrogen, phenyl, chlorophenyl, nitrophenyl or naphthyl.
Claim 5
Dependent Claim 27 words
The process of claim 1 wherein the compound of said formula is added in an amount of from 0.01 to 5% by weight, based on the polymer.
Claim 6
Dependent Claim 27 words
The process of claim 1 wherein the compound of said formula is added in an amount of from 0.05 to 3.5% by weight, based on the polymer.
Claim 7
Dependent Claim 27 words
The process of claim 1 wherein the compound of said formula is added in an amount of from 0.05 to 2.5% by weight, based on the polymer.
Claim 8
Dependent Claim 11 words
A synthetic polymer stabilized by the process claimed in claim 1.
Claim 9
Dependent Claim 27 words
The synthetic polymer of claim 7 containing from 0.01 to 5% by weight of said compound of said formula, based on the weight of said synthetic polymer.

References Cited (Backward Citations)

US3072663A Cited
US3274230A Cited
US3864765A Cited
US3937711A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-08 1981-11-07 1982-05-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-08 1985-11-07 1986-05-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-08 1989-11-07 1990-05-09 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag