Patent US4292237A successfully refreshed from Google Patents.
US4292237A
Expired / Lapsed
US
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Polymeric ultraviolet light stabilizers containing hindered alkyl amines
Assignee: Goodrich Corp
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Filing: 1977-11-14
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Granted: 1981-09-29
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Expires: 1997-11-14
Abstract
Abstract An ultraviolet light sensitive polymer composition wherein resistance to photodegradation is enhanced by the inclusion therein of a stabilizer polymer having structural units corresponding to the following formula ##STR1## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer; x is 0, 1, 2 or 3 and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2. The above stabilizer polymer can be simply combined with, or engrafted upon, the ultraviolet light sensitive polymer. The stabilizer polymer may also be copolymerized with, or grafted upon other polymeric materials thereby enhancing its phase compatability with the ultraviolet light sensitive polymer. In certain instances, it is also possible to copolymerize the monomers from which are derived the ultraviolet light sensitive polymer and the stabilizer polymer.
Inventors
- 👤 Robert W. Layer
- 👤 Pyong N. Son
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 07:35
CPC Classifications
C; C08; C08F; C08F26/00; C08F26/06; C08F12/00; C08F12/02; C08F12/32; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08L; C08L101/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
225 words
A polymer composition comprising a polymer which is sensitive to degradation from ultraviolet light irradiation and, in an amount sufficient to enhance said polymers' resistance to such degradation, a stabilizer polymer having structural units corresponding to the following formula: ##STR5## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
Claim 2
Dependent Claim
225 words
A polymer composition comprising a polymer which is sensitive to degradation from ultraviolet light irradiation and, in an amount sufficient to enhance said polymers' resistance to such degradation, a stabilizer polymer having structural units corresponding to the following formula: ##STR5## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
Claim 3
Dependent Claim
17 words
The composition of claim 1 wherein the stabilizer polymer comprises structural units derived from the monomer, N-(2-acryloxyethyl)-2,2,4-trimethyl-decahydroquinoline.
Claim 4
Dependent Claim
18 words
The polymer composition of claim 1 wherein the stabilizer polymer comprises structural units derived from the monomer, N-(2-hydroxy-3-methacryloxypropyl)-2,2,4-trimethyldecahydroquinoline.
Claim 5
Dependent Claim
18 words
The polymer composition of claim 1 wherein the stabilizer polymer comprises structural units derived from the monomer, N-(2-methacryloxyethyl)-2,2,4-trimethyldecahydroquinoline.
Claim 6
Dependent Claim
19 words
The polymer composition of claim 2 wherein the stabilizer polymer also comprises structural units derived from the monomer 2-hydroxy-4-(2-hydroxy-3-methacryloxy)propoxybenzophenone.
Claim 7
Dependent Claim
19 words
The polymer composition of claim 4 wherein the stabilizer polymer also comprises structural units derived from the monomer acrylonitrile.
Claim 8
Dependent Claim
19 words
The polymer composition of claim 4 wherein the stabilizer polymer also comprises structural units derived from the monomer 2-hydroxy-4-(2-hydroxy-3-methacryloxy)propoxybenzophenone.
Claim 9
Independent Claim
223 words
A method for enhancing the resistance of a polymer to degradation by ultraviolet light, said method comprising incorporating within said ultraviolet light sensitive polymer a stabilizer effective amount of a polymer corresponding to the following structural formula: ##STR6## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
Claim 10
Independent Claim
223 words
A method for enhancing the resistance of a polymer to degradation by ultraviolet light, said method comprising incorporating within said ultraviolet light sensitive polymer a stabilizer effective amount of a polymer corresponding to the following structural formula: ##STR6## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
Claim 11
Dependent Claim
194 words
A polymer corresponding to the following structural formula ##STR7## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
Claim 12
Dependent Claim
194 words
A polymer corresponding to the following structural formula ##STR7## wherein R a , R b , and R c are independently selected from alkyl groups containing 1 to about 12 carbon atoms, a cyclohexyl group, or cyclohexylalkyl groups containing 7 to about 14 carbon atoms; A is selected from the group consisting of alkyl groups containing 1 to about 24 carbon atoms, hydroxyalkyl groups containing 1 to about 18 carbon atoms, alkoxy groups containing 1 to about 12 carbon atoms in the group, ester groups containing a total of from 2 to about 24 carbon atoms in the group, a cyclohexyl group, cyclohexylalkyl groups containing 7 to about 14 carbon atoms in the group, hydroxy groups, amino groups and aminoalkyl groups and alkyl-substituted amino and aminoalkyl groups wherein the alkyl contains 1 to about 12 carbon atoms; Z is a segment of the polymer backbone derived from an olefinic monomer, X is 0, 1, 2 or 3; and B is hydrogen, an alkyl group containing 1 to about 12 carbon atoms, a cyclohexyl group, or a cyclohexylalkyl group of 7 to about 14 carbon atoms in the group; and m is at least 2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1984-09-28 | 1985-03-30 | 1985-09-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-09-28 | 1989-03-30 | 1989-09-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-09-28 | 1993-03-30 | 1993-09-29 | $7700.00 | Window Closed / Lapsed |