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Ferritic stainless steel and processing therefor

Assignee: Allegheny Ludlum Corp
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Filing: 1979-08-01
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Granted: 1981-09-01
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Expires: 1999-08-01
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Abstract

Abstract Careful control of chemistry, and in particular niobium, and of annealing temperatures provides a ferritic stainless steel of improved creep strength. Annealing is performed at a temperature of at least 1900° F., and in certain embodiments, at a temperature no higher than 1990° F.

Inventors

  • 👤 Paul R. Borneman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 15:19
CPC Classifications
C; C22; C22C; C22C38/00; C22C38/18; C22C38/26

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 225 words
A process for producing a creep resistant ferritic stainless steel, which comprises the steps of: preparing a steel melt containing, by weight, up to 0.1% carbon, up to 0.05% nitrogen, from 11 to 20% chromium, up to 5% aluminum, up to 5% molybdenum, up to 1.5% manganese, up to 1.5% silicon, up to 0.5% nickel, up to 0.5% copper, up to 0.6% titanium, and niobium and tantalum in accordance with the following: (a) 0.63 to 1.15% effective niobium, in the absence of tantalum (b) effective niobium and tantalum in accordance with the equation ##EQU11## when both niobium and tantalum are present; casting said steel; working said steel; and annealing said steel at a temperature of at least 1900° F. to provide said steel with a creep life to one percent elongation at 1600° F. under a load of 1200 pounds per square inch, of at least 160 hours; said effective niobium and tantalum being computed in accordance with the following: ##EQU12## If A is positive or zero: Then Effective Nb content=weight % Nb Effective Ta content=weight % Ta If A is negative: Then When Ta is absent Effective Nb content= ##EQU13## When Nb and Ta are present together ##EQU14## Then if B is positive or zero: Effective Nb content=B Effective Ta content=weight % Ta If B is negative: Effective Nb content=0 Effective Ta content= ##EQU15##
Claim 2
Dependent Claim 225 words
A process for producing a creep resistant ferritic stainless steel, which comprises the steps of: preparing a steel melt containing, by weight, up to 0.1% carbon, up to 0.05% nitrogen, from 11 to 20% chromium, up to 5% aluminum, up to 5% molybdenum, up to 1.5% manganese, up to 1.5% silicon, up to 0.5% nickel, up to 0.5% copper, up to 0.6% titanium, and niobium and tantalum in accordance with the following: (a) 0.63 to 1.15% effective niobium, in the absence of tantalum (b) effective niobium and tantalum in accordance with the equation ##EQU11## when both niobium and tantalum are present; casting said steel; working said steel; and annealing said steel at a temperature of at least 1900° F. to provide said steel with a creep life to one percent elongation at 1600° F. under a load of 1200 pounds per square inch, of at least 160 hours; said effective niobium and tantalum being computed in accordance with the following: ##EQU12## If A is positive or zero: Then Effective Nb content=weight % Nb Effective Ta content=weight % Ta If A is negative: Then When Ta is absent Effective Nb content= ##EQU13## When Nb and Ta are present together ##EQU14## Then if B is positive or zero: Effective Nb content=B Effective Ta content=weight % Ta If B is negative: Effective Nb content=0 Effective Ta content= ##EQU15##
Claim 3
Dependent Claim 14 words
A process according to claim 1, where the melt has up to 0.03% carbon.
Claim 4
Dependent Claim 14 words
A process according to claim 1, wherein the melt has up to 0.03% nitrogen.
Claim 5
Dependent Claim 15 words
A process according to claim 1, wherein the melt has from 0.5 to 4.5% aluminum.
Claim 6
Dependent Claim 14 words
A process according to claim 1, wherein the melt has up to 2.5% molybdenum.
Claim 7
Dependent Claim 29 words
A process according to claim 1, wherein the steel is annealed at a temperature of at least 1900° F. for a period of from 10 seconds to 10 minutes.
Claim 8
Dependent Claim 20 words
A process according to claim 1, wherein the steel is annealed at a temperature of from 1900° to 1990° F.
Claim 9
Dependent Claim 193 words
A ferritic stainless steel consisting essentially of, by weight, up to 0.1% carbon, up to 0.05% nitrogen, from 11 to 20% chromium, up to 5% aluminum, up to 5% molybdenum, up to 1.5% manganese, up to 1.5% silicon, up to 0.5% nickel, up to 0.5% copper, up to 0.6% titanium, and niobium and tantalum in accordance with the following: (a) 0.63 to 1.15% effective niobium, in the absence of tantalum (b) effective niobium and tantalum in accordance with the equation ##EQU16## when both niobium and tantalum are present, balance essentially iron; said effective niobium and tantalum being computed in accordance with the following: ##EQU17## If A is positive or zero: Then Effective Nb content=weight % Nb Effective Ta content=weight % Ta If A is negative: Then When Ta is absent Effective Nb content= ##EQU18## When Nb and Ta are present together ##EQU19## Then if B is positive: Effective Nb content=B Effective Ta content=weight % Ta If B is negative: Effective Nb content=0 Effective Ta content= ##EQU20## said steel having a creep life to one percent elongation at 1600° F. under a load of 1200 pounds per square inch, of at least 160 hours.
Claim 10
Dependent Claim 193 words
A ferritic stainless steel consisting essentially of, by weight, up to 0.1% carbon, up to 0.05% nitrogen, from 11 to 20% chromium, up to 5% aluminum, up to 5% molybdenum, up to 1.5% manganese, up to 1.5% silicon, up to 0.5% nickel, up to 0.5% copper, up to 0.6% titanium, and niobium and tantalum in accordance with the following: (a) 0.63 to 1.15% effective niobium, in the absence of tantalum (b) effective niobium and tantalum in accordance with the equation ##EQU16## when both niobium and tantalum are present, balance essentially iron; said effective niobium and tantalum being computed in accordance with the following: ##EQU17## If A is positive or zero: Then Effective Nb content=weight % Nb Effective Ta content=weight % Ta If A is negative: Then When Ta is absent Effective Nb content= ##EQU18## When Nb and Ta are present together ##EQU19## Then if B is positive: Effective Nb content=B Effective Ta content=weight % Ta If B is negative: Effective Nb content=0 Effective Ta content= ##EQU20## said steel having a creep life to one percent elongation at 1600° F. under a load of 1200 pounds per square inch, of at least 160 hours.
Claim 11
Dependent Claim 13 words
A ferritic stainless steel according to claim 8, having up to 0.03% carbon.
Claim 12
Dependent Claim 13 words
A ferritic stainless steel according to claim 8, having up to 0.03% nitrogen.
Claim 13
Dependent Claim 14 words
A ferritic stainless steel according to claim 8, having from 0.5 to 4.5% aluminum.
Claim 14
Dependent Claim 13 words
A ferritic stainless steel according to claim 8, having up to 2.5% molybdenum.
Claim 15
Dependent Claim 33 words
A ferritic stainless steel according to claim 8, having a creep life to one percent elongation at 1600° F. under a load of 1200 pounds per square inch, of at least 250 hours.
Claim 16
Dependent Claim 22 words
A ferritic stainless steel according to claim 8, wherein the effective tantalum content is less than four times the effective niobium content.
Claim 17
Dependent Claim 29 words
A ferritic stainless steel according to claim 8, wherein said steel is characterized by a structure wherein substantially all of the grains are about ASTM No. 5 or finer.

References Cited (Backward Citations)

US2191790A Cited
US2905577A Cited
US3499802A Cited
US3650731A Cited
US3926685A Cited
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US3852063A Cited
US3890143A Cited
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US4087287A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-31 1985-03-02 1985-09-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-31 1989-03-02 1989-09-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-31 1993-03-02 1993-09-01 $7700.00 Window Closed / Lapsed

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