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US4280005A Expired / Lapsed US ⏱️ 0.0 years remaining

Foamable polyester composition

Assignee: General Electric Co
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Filing: 1979-09-24
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Granted: 1981-07-21
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Expires: 1999-09-24
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Abstract

Abstract A foamable flame-retardant thermoplastic injection moldable composition comprising in admixture (a) a polyester resin, (b) a filler selected from the group consisting of fibrous glass or a mineral or mixtures thereof in an amount of from about 5 to about 50 weight percent, (c) a flame-retardant additive and (d) a minor amount of a foaming agent.

Inventors

  • 👤 Daniel W. Fox

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 14:27
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0085; C08J9/0014; C08J9/0066; C08J2367/00; C08J2367/02; Y; Y10; Y10S; Y10S260/00; Y10S260/24; Y10S521/00; Y10S521/907

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 158 words
A foamable thermoplastic injection moldable composition consisting of an admixture of: (a) a polyester resin selected from the group consisting of (1) a poly(ethylene terephthalate) resin or a copolyester thereof, (2) a combination of a poly(ethylene terephthalate) resin and a poly(1,4-butylene terephthalate) resin or copolyesters thereof and (3) a combination of a poly(1,4-butylene terephthalate) resin or a copolyester thereof and a linear aliphatic polyester resin; (b) a filler selected from the group consisting of fibrous glass or a mineral or mixtures thereof in an amount of from about 5 to about 50 weight percent; (c) a flame retardant additive in minor proportion but in an amount at least sufficient to render the polyester non-burning or selfextinguishing; and (d) a foaming agent selected from the group consisting of dinitrosopentamethylene tetramine, p-toluene sulfonyl semicarbozide, 5-phenyltetrazole, calcium oxalete and trihydrazine-s-triazene in an amount from 0.2 to 2.0 weight percent; said weight percent being based on the total weight of the resin.
Claim 2
Dependent Claim 158 words
A foamable thermoplastic injection moldable composition consisting of an admixture of: (a) a polyester resin selected from the group consisting of (1) a poly(ethylene terephthalate) resin or a copolyester thereof, (2) a combination of a poly(ethylene terephthalate) resin and a poly(1,4-butylene terephthalate) resin or copolyesters thereof and (3) a combination of a poly(1,4-butylene terephthalate) resin or a copolyester thereof and a linear aliphatic polyester resin; (b) a filler selected from the group consisting of fibrous glass or a mineral or mixtures thereof in an amount of from about 5 to about 50 weight percent; (c) a flame retardant additive in minor proportion but in an amount at least sufficient to render the polyester non-burning or selfextinguishing; and (d) a foaming agent selected from the group consisting of dinitrosopentamethylene tetramine, p-toluene sulfonyl semicarbozide, 5-phenyltetrazole, calcium oxalete and trihydrazine-s-triazene in an amount from 0.2 to 2.0 weight percent; said weight percent being based on the total weight of the resin.
Claim 3
Dependent Claim 62 words
The composition of claim 1 wherein the polyester resin combination (2) comprises (a) from about 1 to about 99 parts by weight of a poly(ethylene terephthalate) resin and (b) from about 99 to about 1 part by weight of a poly(1,4-butylene terephthalate) resin or a copolyester thereof with a minor amount of an aliphatic or aromatic dicarboxylic acid or an aliphatic polyol.
Claim 4
Dependent Claim 81 words
A flame retardant composition as defined in claim 1 wherein said flame retardant additive is a compound selected from the group consisting of a halogen-containing compound, a halogen-containing compound in admixture with an antimony compound; elemental phosphorus or a phosphorus compound; a halogen-containing compound in admixture with a phosphorus compound; a compound containing phosphorus-nitrogen bonds; or a mixture of the foregoing, and said compound is present in an amount of 0.5 to 50 weight percent based on the weight of resin.
Claim 5
Dependent Claim 108 words
A flame retardant composition as defined in claim 1 wherein said flame retardant additive is either (a) a low molecular weight polymer of a carbonate of a halogenated dihydric phenol, said polymer containing from 2 to 10 repeating units of the formula ##STR8## wherein R 1 and R 2 are hydrogen, (lower)alkyl or phenyl, X 1 and X 2 are bromo or chloro and m and r are from 1 to 4, said polymer having low volatility when heated above about 200° C., and a softening point of less than about 300° C., or (b) a combination of said polymer (a) and an inorganic or organic antimony-containing compound.
Claim 6
Dependent Claim 52 words
A flame retardant composition as defined in claim 4 wherein said low molecular weight polymer (a) is of the formula ##STR9## wherein the average number of repeating units, n, is from about 3 to 7, and the softening point of said polymer is in the range of from 200° to 260° C.
Claim 7
Dependent Claim 50 words
A flame retardant composition as defined in claim 3 wherein said flame retardant additive is either (a) a carbonate polymer which is the reaction product of a halogen substituted dihydric phenol and a dihydric phenol or (b) a combination of said polymer (a) and an inorganic or organic antimony-containing compound.
Claim 8
Dependent Claim 23 words
A flame retardant composition as defined in claim 6 wherein said carbonate polymer is the reaction product of a halogenated bisphenol-A and bisphenol-A.
Claim 9
Dependent Claim 16 words
The composition of claim 1 wherein the fibrous glass filler comprises finely divided fibrous glass filaments.
Claim 10
Dependent Claim 21 words
The composition of claim 1 wherein the fibrous glass filler consists of finely divided glass filaments treated with a binding agent.

References Cited (Backward Citations)

US3211678A Cited
US3474048A Cited
US3671487A Cited
US3725321A Cited
US4097421A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-20 1985-01-19 1985-07-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-20 1989-01-19 1989-07-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-20 1993-01-19 1993-07-21 $7700.00 Window Closed / Lapsed

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