Absorbed hydrazide nucleating agents and photographic elements containing such agents

Claim 2

A silver halide emulsion comprised of silver halide grains capable of forming an internal latent image and, adsorbed to the surface of said silver halide grains, a nucleating amount of a triazole-substituted phenylhydrazide, wherein the phenyl moiety is triazole-substituted.

Claim 3

A silver halide emulsion according to claim 1 wherein said triazole-substituted phenylhydrazide is of the formula ##STR19## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting adsorption of the hydrazide to a silver halide grain surface.

Claim 4

A silver halide emulsion according to claim 1 wherein said triazole-substituted phenylhydrazide is of the formula ##STR20## wherein R 1 is hydrogen, an alkyl, cycloalkyl, haloalkyl, alkoxyalkyl or phenylalkyl substituent or a phenyl nucleus having a Hammett sigma-value-derived electron withdrawing characteristic more positive than -0.3, φ 1 is a m- or p-phenylene or an alkyl-, halo-, benzoxy- or alkoxy-substituted m- or p-phenylene group, A 1 is alkylene or oxyalkylene, ##STR21## A 3 is a triazolyl or benzotriazolyl nucleus; the alkyl and alkylene moieties in each instance having from 1 to 6 carbon atoms.

Claim 5

A silver halide emulsion according to claims 1, 2 or 3 wherein said triazole-substituted phenylhydrazide is present in a concentration of from 0.5 to 500 mg per mole of silver.

Claim 6

A silver halide emulsion according to claims 1, 2 or 3 wherein said silver halide grains are predominantly silver bromide and contain metal dopants occluded therein, which grains have been chemically sensitized on the surface thereof to a level which would produce a density of less than 0.4 when imagewise exposed and developed in a test surface developer for 5 minutes at 27° C. and to at least a level which would produce a density of greater than 0.5 in an undoped silver halide emulsion of the same grain size and halide composition when exposed and developed in the test surface developer, provided said emulsions are coated at a coverage of between about 3 and 4 grams per square meter.

Claim 7

A photographic element comprised of a support and, coated on said support, a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, absorbed to the surface of said silver halide grains, a nucleating amount of a triazole-substituted phenylhydrazide, wherein the phenyl moiety is trizole-substituted.

Claim 8

A photographic element comprised of a support and, coated on said support, a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, absorbed to the surface of said silver halide grains, a nucleating amount of a triazole-substituted phenylhydrazide, wherein the phenyl moiety is trizole-substituted.

Claim 9

A photographic element according to claim 6 wherein said triazole-substituted phenylhydrazide is of the formula ##STR22## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting absorption to a silver halide grain surface.

Claim 10

A photographic element according to claim 7 wherein said triazole-substituted phenylhydrazide is of the formula ##STR23## wherein R 1 is hydrogen, an alkyl, cycloalkyl, haloalkyl, alkoxyalkyl or phenylalkyl substituent or a phenyl nucleus having a Hammett sigma-value-derived electron withdrawing characteristic more positive than -0.3, φ 1 is a m- or p-phenylene or an alkyl-, halo-, benzoxy- or alkoxy-substituted m- or p-phenylene group, A 1 is alkylene or oxyalkylene, ##STR24## A 3 is a triazolyl or benzotriazolyl nucleus; the alkyl and alkylene moieties in each instance having from 1 to 6 carbon atoms.

Claim 11

A photographic element according to claims 6, 7 or 8 wherein said triazole-substituted phenylhydrazide is present in a concentration of from 1.0 to 100 mg per mole of silver.

Claim 12

A photographic element according to claims 6, 7 or 8 wherein said silver halide grains contain a metal dopant; provide a maximum optical density less than 0.25 when coated on a support at a density of from 3 to 4 grams per square meter, exposed to a light intensity scale for a fixed time of from 1×10 -2 to 1 second and developed for 5 minutes at 25° C. in the surface developer; and provide a maximum optical density at least 5 times greater than the above maximum density when the above procedure is repeated additionally including in the surface developer 0.5 gram per liter of potassium iodide to form an internal developer.

Claim 13

A process of obtaining a direct-positive image comprising imagewise exposing a photographic element comprised of a support and coated on the support a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, adsorbed to the surface of the silver halide grains, a nucleating amount of a traizole-substituted phenylhydrazide, wherein the phenyl moiety is traizole-substituted, and selectively developing the silver halide grains remaining unexposed.

Claim 14

A process of obtaining a direct-positive image comprising imagewise exposing a photographic element comprised of a support and coated on the support a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, adsorbed to the surface of the silver halide grains, a nucleating amount of a traizole-substituted phenylhydrazide, wherein the phenyl moiety is traizole-substituted, and selectively developing the silver halide grains remaining unexposed.

Claim 15

In an image transfer film unit which comprises a photographic element comprising a support and coated thereon at least one silver halide emulsion layer containing radiation-sensitive internal latent image-forming silver halide grains and, adsorbed to the surface of said silver halide grains, a nucleating agent, said photographic element including an image dye-providing material within or in contact with said silver halide emulsion layer, an image-receiving means positioned to receive image dye from said photographic element, an alkaline processing composition, means containing and adapted to release said alkaline processing composition for contact with said emulsion layer, and a silver halide developing agent located in at least one of the photographic element and the alkaline processing composition, the improvement wherein said nucleating agent is a triazole-substituted phenylhydrazide of the formula ##STR25## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting adsorption to a silver halide grain surface.

Claim 16

In an image transfer film unit which comprises a photographic element comprising a support and coated thereon at least one silver halide emulsion layer containing radiation-sensitive internal latent image-forming silver halide grains and, adsorbed to the surface of said silver halide grains, a nucleating agent, said photographic element including an image dye-providing material within or in contact with said silver halide emulsion layer, an image-receiving means positioned to receive image dye from said photographic element, an alkaline processing composition, means containing and adapted to release said alkaline processing composition for contact with said emulsion layer, and a silver halide developing agent located in at least one of the photographic element and the alkaline processing composition, the improvement wherein said nucleating agent is a triazole-substituted phenylhydrazide of the formula ##STR25## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting adsorption to a silver halide grain surface.

Claim 17

An improved image transfer film unit according to claim 12 wherein said film unit incorporates an antifoggant.

Claim 18

An improved image transfer film unit according to claim 13 wherein said antifoggant is a benzotriazole antifoggant.

Claim 19

An improved image transfer film unit according to claim 12 wherein said triazole-substituted phenylhydrazide is of the formula ##STR26## wherein R 1 is hydrogen, an alkyl, cycloalkyl, haloalkyl, alkoxyalkyl or phenylalkyl substituent or a phenyl nucleus having a Hammett sigma-value-derived electron withdrawing characteristic more positive than -0.3, φ 1 is m- or p-phenylene or an alkyl-, halo-, benzoxy- or alkoxy-substituted m- or p-phenylene group, A 1 is alkylene or oxyalkylene, ##STR27## A 3 is a triazolyl or benzotriazolyl nucleus; the alkyl and alkylene moieties in each instance including from 1 to 6 carbon atoms.

Claim 20

An image transfer film unit comprising (a) a photographic element comprising a support bearing (1) a layer containing a blue-sensitive silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile yellow image dye, (2) a layer containing a green-sensitized silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile magenta image dye, and (3) a layer containing a red-sensitized silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile cyan image dye, wherein each of said silver halide emulsions comprises silver halide grains having metal dopants occluded therein, said grains being substantially unfogged on their surfaces and being chemically sensitized on their surfaces (a) to a level which will provide a maximum density of less than 0.4 when developed in a test surface developer of the composition indicated below for 5 minutes at 27° C. after exposure to a light intensity scale for a fixed time of from 1×10 -2 to 1 second when said photosensitive composition is coated at a coverage of between about 3 and 4 grams of silver per square meter, and (b) to at least a level which would provide a maximum density of at least 0.5 using undoped silver halide grains of the same grain size and halide composition when coated, exposed and developed in like manner, (b) an image-receiving means positioned to receive image dye from said photographic element, (c) an aqueous alkaline processing composition, (d) means containing and adapted to release said alkaline processing composition into contact with said silver halide emulsions, (e) a silver halide surface developing agent located in said processing composition, and (f) from 1 to 100 mg per mole of silver of a nucleating agent adsorbed to said silver halide grains within at least one of said silver halide emulsion layer, said nucleating agent having the formula ##STR28## wherein R 2 is hydrogen or methyl, ##STR29## n is an integer of from 1 to 4, and D is alkyl of from 1 to 4 carbon atoms; the test surface developer consisting essentially of ______________________________________ Water (52° C.) 500.00 cc N-methyl-p-aminophenol sulfate 2.5 g Sodium sulfite, desiccated 30.0 g Hydroquinone 2.5 g Sodium metaborate 10.0 g Potassium bromide 0.5 g Water to make 1 liter. ______________________________________

Claim 21

An image transfer film unit comprising (a) a photographic element comprising a support bearing (1) a layer containing a blue-sensitive silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile yellow image dye, (2) a layer containing a green-sensitized silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile magenta image dye, and (3) a layer containing a red-sensitized silver halide emulsion having in contact therewith an immobile material capable of releasing a mobile cyan image dye, wherein each of said silver halide emulsions comprises silver halide grains having metal dopants occluded therein, said grains being substantially unfogged on their surfaces and being chemically sensitized on their surfaces (a) to a level which will provide a maximum density of less than 0.4 when developed in a test surface developer of the composition indicated below for 5 minutes at 27° C. after exposure to a light intensity scale for a fixed time of from 1×10 -2 to 1 second when said photosensitive composition is coated at a coverage of between about 3 and 4 grams of silver per square meter, and (b) to at least a level which would provide a maximum density of at least 0.5 using undoped silver halide grains of the same grain size and halide composition when coated, exposed and developed in like manner, (b) an image-receiving means positioned to receive image dye from said photographic element, (c) an aqueous alkaline processing composition, (d) means containing and adapted to release said alkaline processing composition into contact with said silver halide emulsions, (e) a silver halide surface developing agent located in said processing composition, and (f) from 1 to 100 mg per mole of silver of a nucleating agent adsorbed to said silver halide grains within at least one of said silver halide emulsion layer, said nucleating agent having the formula ##STR28## wherein R 2 is hydrogen or methyl, ##STR29## n is an integer of from 1 to 4, and D is alkyl of from 1 to 4 carbon atoms; the test surface developer consisting essentially of ______________________________________ Water (52° C.) 500.00 cc N-methyl-p-aminophenol sulfate 2.5 g Sodium sulfite, desiccated 30.0 g Hydroquinone 2.5 g Sodium metaborate 10.0 g Potassium bromide 0.5 g Water to make 1 liter. ______________________________________

Claim 22

A process of producing a transferred photographic dye image comprising imagewise exposing a photographic element comprised of a support and, coated on the support, a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, adsorbed to the surface of the silver halide grains, a nucleating amount of a triazole-substituted phenylhydrazide of the formula ##STR30## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting adsorption to the surfaces of the silver halide grains, said photographic element including an image dye-providing material which exhibits an alteration in mobility as a function of silver halide development within or in contact with said silver halide emulsion layer, selectively developing the silver halide grains remaining unexposed, and transferring mobile dye to a receiver to form a transferred dye image.

Claim 23

A process of producing a transferred photographic dye image comprising imagewise exposing a photographic element comprised of a support and, coated on the support, a silver halide emulsion layer comprising silver halide grains capable of forming an internal latent image and, adsorbed to the surface of the silver halide grains, a nucleating amount of a triazole-substituted phenylhydrazide of the formula ##STR30## wherein R is an acyl group, φ is a phenylene or substituted phenylene group, and A is a moiety comprised of a triazole nucleus capable of promoting adsorption to the surfaces of the silver halide grains, said photographic element including an image dye-providing material which exhibits an alteration in mobility as a function of silver halide development within or in contact with said silver halide emulsion layer, selectively developing the silver halide grains remaining unexposed, and transferring mobile dye to a receiver to form a transferred dye image.