← Back to Patent Explorer
US4273668A Expired / Lapsed US ⏱️ 0.0 years remaining

Arylsulfonium salt-solvent mixtures

Assignee: General Electric Co
•
Filing: 1979-06-18
•
Granted: 1981-06-16
•
Expires: 1999-06-18
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Onium salts of Group VIa elements which have an MF 6 - anion, where M is selected from P, As and Sb, have been found to be photoactive under ultraviolet light. These onium salts can be incorporated as cationic photoinitiators into a variety of cationically polymerizable materials when used in combination with propylene carbonate as an aryl sulfonium salt solvent mixture.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:16
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/68; C08G59/687; C08G85/00; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; Y; Y10; Y10S; Y10S502/00; Y10S502/522

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 166 words
A stable aryl onium salt-solvent mixture comprising (A) 1% to 75% by weight of aryl onium salt of the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+ [MF.sub.6 ].sup.- and (B) 99% to 25% by weight of a cyclic carbonate selected from the class consisting of ethylene carbonate and propylene carbonate based on the total weight of (A) and (B), where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical, selected from alkyl, cycloalkyl and derivatives thereof, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure, selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur and selenium, M is selected from P, As and Sb, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 and the sum of a+b+c is equal to 3 or the valence of X.
Claim 2
Dependent Claim 166 words
A stable aryl onium salt-solvent mixture comprising (A) 1% to 75% by weight of aryl onium salt of the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+ [MF.sub.6 ].sup.- and (B) 99% to 25% by weight of a cyclic carbonate selected from the class consisting of ethylene carbonate and propylene carbonate based on the total weight of (A) and (B), where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical, selected from alkyl, cycloalkyl and derivatives thereof, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure, selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur and selenium, M is selected from P, As and Sb, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 and the sum of a+b+c is equal to 3 or the valence of X.
Claim 3
Dependent Claim 16 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is a triphenylsulfonium salt.
Claim 4
Dependent Claim 15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluoroarsenate.
Claim 5
Dependent Claim 15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluoroantimonate.
Claim 6
Dependent Claim 15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluorophosphate.
Claim 7
Dependent Claim 17 words
A mixture in accordance with claim 1, having 50% to 50% by weight of aryl sulfonium salt.

References Cited (Backward Citations)

US3305527A Cited
US3542828A Cited
US4080274A Cited
US3794576A Cited
US4058400A Cited
US4154872A Cited
US4156035A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-15 1984-12-15 1985-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-15 1988-12-15 1989-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-15 1992-12-15 1993-06-16 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag