US4273668A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Arylsulfonium salt-solvent mixtures
Assignee: General Electric Co
•
Filing: 1979-06-18
•
Granted: 1981-06-16
•
Expires: 1999-06-18
Abstract
Abstract Onium salts of Group VIa elements which have an MF 6 - anion, where M is selected from P, As and Sb, have been found to be photoactive under ultraviolet light. These onium salts can be incorporated as cationic photoinitiators into a variety of cationically polymerizable materials when used in combination with propylene carbonate as an aryl sulfonium salt solvent mixture.
Inventors
- 👤 James V. Crivello
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 16:16
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/68; C08G59/687; C08G85/00; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; Y; Y10; Y10S; Y10S502/00; Y10S502/522
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
166 words
A stable aryl onium salt-solvent mixture comprising (A) 1% to 75% by weight of aryl onium salt of the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+ [MF.sub.6 ].sup.- and (B) 99% to 25% by weight of a cyclic carbonate selected from the class consisting of ethylene carbonate and propylene carbonate based on the total weight of (A) and (B), where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical, selected from alkyl, cycloalkyl and derivatives thereof, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure, selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur and selenium, M is selected from P, As and Sb, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 and the sum of a+b+c is equal to 3 or the valence of X.
Claim 2
Dependent Claim
166 words
A stable aryl onium salt-solvent mixture comprising (A) 1% to 75% by weight of aryl onium salt of the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+ [MF.sub.6 ].sup.- and (B) 99% to 25% by weight of a cyclic carbonate selected from the class consisting of ethylene carbonate and propylene carbonate based on the total weight of (A) and (B), where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical, selected from alkyl, cycloalkyl and derivatives thereof, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure, selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur and selenium, M is selected from P, As and Sb, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1 and the sum of a+b+c is equal to 3 or the valence of X.
Claim 3
Dependent Claim
16 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is a triphenylsulfonium salt.
Claim 4
Dependent Claim
15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluoroarsenate.
Claim 5
Dependent Claim
15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluoroantimonate.
Claim 6
Dependent Claim
15 words
A mixture in accordance with claim 1, where the aryl sulfonium salt is triphenylsulfonium hexafluorophosphate.
Claim 7
Dependent Claim
17 words
A mixture in accordance with claim 1, having 50% to 50% by weight of aryl sulfonium salt.
References Cited (Backward Citations)
US3305527A
Cited
US3542828A
Cited
US4080274A
Cited
US3794576A
Cited
US4058400A
Cited
US4154872A
Cited
US4156035A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-15 | 1984-12-15 | 1985-06-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-15 | 1988-12-15 | 1989-06-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-15 | 1992-12-15 | 1993-06-16 | $7700.00 | Window Closed / Lapsed |