Photopolymerization of lactone-epoxide mixtures with aromatic diazonium salts as photocatalyst

Claim 2

A photopolymerizable composition comprising: a material photopolymerizable to higher molecular weights through the action of a cationic catalyst consisting essentially of a lactone monomer and a monomeric or prepolymeric epoxide, and as a latent catalyst precursor, a radiation-sensitive aromatic diazonium salt of a hexafluorophosphate which decomposes upon exposure to irradiation to provide a Lewis Acid effective to initiate polymerization of said material, said radiation-sensitive salt having had substantially no exposure to irradiation and being present in an amount sufficient to effect polymerization of said polymerizable material.

Claim 3

The composition of claim 1 wherein said lactone monomer is a lactone of the general formula: ##STR6## wherein R 1 and R 2 are hydrogen or an alkyl radical and y is the number of methylene groups and is an integer of 1 to 13.

Claim 4

The composition of claim 2 wherein y is 1.

Claim 5

The composition of claim 2 wherein y is 1 and R 1 and R 2 are hydrogen.

Claim 6

The composition of claim 4 wherein said salt is 2,5-diethoxy-4-(p-tolylthio) benzene diazonium hexafluorophosphate.

Claim 7

The composition of claim 5 wherein said lactone is beta-propiolactone.

Claim 8

The composition of claim 5 wherein said salt is present in an amount of from about 0.5 to 5% by weight of said polymerizable material.

Claim 9

The composition of claim 2 wherein y is 4.

Claim 10

The composition of claim 2 wherein R 1 and R 2 are hydrogen and y is 4.

Claim 11

The composition of claim 9 wherein said lactone is epsilon-caprolactone.

Claim 12

The process of polymerizing a material polymerizable to higher molecular weights through the action of a cationic catalyst consisting essentially of a lactone monomer and a monomeric or prepolymeric epoxide which comprises: forming a mixture of said material and a radiation-sensitive aromatic diazonium salt of a hexafluorophosphate which decomposes upon exposure to electromagnetic or electron-beam irradiation to provide a Lewis Acid effective to initiate polymerization of said material, and subsequently exposing the resulting mixture to irradiation to release said Lewis Acid in sufficient amounts to effect polymerization of said material.

Claim 13

The process of polymerizing a material polymerizable to higher molecular weights through the action of a cationic catalyst consisting essentially of a lactone monomer and a monomeric or prepolymeric epoxide which comprises: forming a mixture of said material and a radiation-sensitive aromatic diazonium salt of a hexafluorophosphate which decomposes upon exposure to electromagnetic or electron-beam irradiation to provide a Lewis Acid effective to initiate polymerization of said material, and subsequently exposing the resulting mixture to irradiation to release said Lewis Acid in sufficient amounts to effect polymerization of said material.

Claim 14

The process of claim 11 wherein said lactone monomer is a lactone of the general formula: ##STR7## wherein R 1 and R 2 are hydrogen or an alkyl radical and y is an integer of 1 to 13.

Claim 15

The process of claim 12 wherein said irradiation is electromagnetic radiation.

Claim 16

The process of claim 13 wherein said lactone is beta-propiolactone or epsilon-caprolactone.

Claim 17

The process of claim 14 wherein said salt is 2,5-diethoxy-4-(p-tolylthio) benezene diazonium hexafluorophosphate.