Patent US4272607A successfully refreshed from Google Patents.
US4272607A
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Photosensitive resin composition
Assignee: Resonac Corp
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Filing: 1977-03-29
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Granted: 1981-06-09
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Expires: 1997-03-29
Abstract
Abstract A photosensitive resin composition comprising (a) a linear polymer or copolymer having tetrahydrofurfuryl groups at side chains, (b) one or more photopolymerizable unsaturated compounds having at least two terminal ethylene groups, and (c) one or more sensitizers which initiate polymerization of said unsaturated compounds by irradiation of active light, has excellent storage stability and photosensitivity. The composition can produce permanent protective films having excellent resistance to solvents, heat resistance and the like and can be used as a solder resist and the like.
Inventors
- 👤 Katsushige Tsukada
- 👤 Nobuyuki Hayashi
- 👤 Hideo Yamada
- 👤 Toshiaki Ishimaru
- 👤 Hajime Kakumaru
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 21:30
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/033; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
109 words
A photosensitive resin composition consisting essentially of (a) 20 to 70 parts by weight of a polymer selected from the group consisting of a linear polymer having tetrahydrofurfuryl groups at side chains and a linear copolymer having tetrahydrofurfuryl groups at side chains, wherein the tetrahydrofurfuryl groups at side chains is contained in the polymer in a proportion of at least 0.007 mole/100 g, (b) 20 to 60 parts by weight of one or more photopolymerizable unsaturated compounds having at least two terminal ethylene groups, and (c) 1 to 10 parts by weight of one or more sensitizers which initiate polymerization of said unsaturated compounds by irradiation of active light.
Claim 2
Dependent Claim
109 words
A photosensitive resin composition consisting essentially of (a) 20 to 70 parts by weight of a polymer selected from the group consisting of a linear polymer having tetrahydrofurfuryl groups at side chains and a linear copolymer having tetrahydrofurfuryl groups at side chains, wherein the tetrahydrofurfuryl groups at side chains is contained in the polymer in a proportion of at least 0.007 mole/100 g, (b) 20 to 60 parts by weight of one or more photopolymerizable unsaturated compounds having at least two terminal ethylene groups, and (c) 1 to 10 parts by weight of one or more sensitizers which initiate polymerization of said unsaturated compounds by irradiation of active light.
Claim 3
Dependent Claim
40 words
A composition according to claim 1, wherein said polymer is a linear polymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR5## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom.
Claim 4
Dependent Claim
113 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR6## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, and a compound of the formula: ##STR7## wherein X is as defined above; R 1 is a group of the formula ##STR8## in which n is an integer of 1 to 20; R 2 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 OR 2 .
Claim 5
Dependent Claim
46 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR9## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, and one or more vinyl monomers.
Claim 6
Dependent Claim
118 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR10## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, a compound of the formula: ##STR11## wherein X is as defined above; R 1 is a group of the formula ##STR12## in which n is an integer of 1 to 20; R 2 is a hydrogen atom, a lower alkyl group or a group of the formula CH 2 Cl; and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula CH 2 OR 2 , and one or more vinyl monomers.
Claim 7
Dependent Claim
20 words
A composition according to claim 2, wherein the linear polymer is a linear polymer of tetrahydrofurfuryl methacrylate or tetrahydrofurfuryl acrylate.
Claim 8
Dependent Claim
25 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of tetrahydrofurfuryl methacrylate and tetrahydrofurfuryl acrylate.
Claim 9
Dependent Claim
35 words
A composition according to claim 4, wherein the linear copolymer having tetrahydrofurfuryl groups at side chains is a linear copolymer of at least one of the compounds tetrahydrofurfuryl methacrylate and tetrahydrofurfuryl acrylate, and methyl methacrylate.
Claim 10
Dependent Claim
60 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are a mixture of an acrylic or methacrylic acid ester of polyvalent alcohol selected from the group consisting of pentaerythritol, trimethylolpropane and trimethylolethane and an acrylic or methacrylic acid ester of bivalent alcohol selected from the group consisting of polyethylene glycol, polyethylene glycol and polytetramethylene glycol.
Claim 11
Dependent Claim
32 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are a mixture of an acrylic acid ester of pentaerythritol and an acrylic acid ester of polypropylene glycol.
Claim 12
Dependent Claim
32 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compunds are a mixture of an acrylic acid ester of pentaerythritol and an acrylic acid ester of polyethylene glycol.
Claim 13
Dependent Claim
24 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are a mixture of trimethylolpropane triacrylate and polyethylene glycol diacrylate.
Claim 14
Dependent Claim
161 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR13## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, a compound of the formula: ##STR14## wherein X is as defined above; R 1 is a group of the formula ##STR15## in which n is an integer of 1 to 20; R 2 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 OR 2 , and a compound of the formula: ##STR16## wherein X is as defined above; R 4 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 ClR 5 is hydrogen or a lower alkyl group; and n is an integer of 1 to 20.
Claim 15
Dependent Claim
193 words
A composition according to claim 1, wherein the linear copolymer is a copolymer of (A) 2 to 90 parts by weight of a compound of the formula: ##STR17## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, (B) 1 to 20 parts by weight of a compound of the formula: ##STR18## wherein X is as defined above; R 1 is a group of the formula ##STR19## in which n is an integer of 1 to 20; R 2 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 OR 2 , (C) 0.02 to 1 part by weight of a compound of the formula: ##STR20## wherein X is as defined above; R 4 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; R 5 is a hydrogen or lower alkyl group; and n is an integer of 1 to 20, and (D) 0 to 85 parts by weight of one or more vinyl monomers.
Claim 16
Dependent Claim
33 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are low molecular weight polyester resins having at least one of acryloyl groups and methacryloyl groups at end groups.
Claim 17
Dependent Claim
25 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are a condensate of phthalic acid, diethylene glycol and acrylic acid.
Claim 18
Dependent Claim
26 words
A composition according to claim 1, wherein the one or more photopolymerizable unsaturated compounds are a condensate of trimethylolpropane, tetrahydrophthalic acid, diethylene glycol and acrylic acid.
Claim 19
Dependent Claim
168 words
A composition according to claim 1, wherein said polymer is a linear copolymer having tetrahydrofurfuryl groups at side chains of a compound of the formula: ##STR21## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom, a compound of the formula: ##STR22## wherein X is as defined above; R 1 is a group of the formula ##STR23## in which n is an integer of 1 to 20, R 2 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 OR 2 , and a compound of the formula: ##STR24## wherein X is as defined above; R 4 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; R 5 is hydrogen or a lower alkyl group; and n is an integer of 1 to 20, and 1 or more vinyl monomers.
Claim 20
Dependent Claim
45 words
A composition according to claim 18, wherein said one or more vinyl monomers are selected from the group consisting of alkyl acrylates or methacrylates, acrylic acid, methacrylic acid, itaconic acid, styrene, α-methyl styrene, glycidyl methacrylate, t-butylaminoethyl methacrylate, dimethylamino methacrylate, 2,3-dibromopropyl methacrylate, acrylamide, and tribromophenyl acrylate.
Claim 21
Dependent Claim
17 words
A composition according to claim 13, wherein said polymer has a molecular weight of 10,000 to 600,000.
Claim 22
Dependent Claim
187 words
A composition according to claim 14, wherein the linear copolymer is a copolymer of (A) 5 to 40 parts by weight of a compound of the formula: ##STR25## wherein X is a hydrogen atom, a lower alkyl group or a halogen atom; (B) 2-10 parts by weight of a compound of the formula: ##STR26## wherein X is as defined above; R 1 is a group of the formula ##STR27## in which n is an integer of 1 to 20; R 2 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; and R 3 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 OR 2 ; (C) 0.05-0.2 part by weight of a compound of the formula: ##STR28## wherein X is as defined above; R 4 is a hydrogen atom, a lower alkyl group or a group of the formula --CH 2 Cl; R 5 is hydrogen or a lower alkyl group; and n is an integer of 1 to 20; and (D) 0-85 parts by weight of one or more vinyl monomers.
Claim 23
Dependent Claim
26 words
A composition according to claim 1, wherein said one or more photopolymerizable unsaturated compounds comprise a mixture of trifunctional unsaturated compound and a bifunctional unsaturated compound.
Claim 24
Dependent Claim
34 words
A composition according to claim 1, wherein said one or more sensitizers is selected from the group consisting of benzophenone, Michler's ketone, benzoin, benzoin alkyl ethers, anthraquinone, alkyl substituted anthraquinones, benzil, and cobalt naphthenate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-08 | 1984-12-08 | 1985-06-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-08 | 1988-12-08 | 1989-06-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-08 | 1992-12-08 | 1993-06-09 | $7700.00 | Window Closed / Lapsed |