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US4271133A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for removing hydrogen cyanide from gaseous streams

Assignee: Union Carbide Corp
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Filing: 1980-03-31
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Granted: 1981-06-02
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Expires: 2000-03-31
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Abstract

Abstract This invention relates to a process for reducing the hydrogen cyanide content of a gaseous stream which comprises providing an adsorbent bed wherein the adsorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkali or alkaline earth metal, and contacting said process stream with said adsorbent bed at a temperature of from about ambient to about 350 DEG C. for a period of time sufficient to reduce the concentration of hydrogen cyanide in said gaseous stream to the desired value.

Inventors

  • 👤 Cyril Tellis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 21:54
CPC Classifications
C; C10; C10K; C10K1/00; C10K1/20; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/54

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 85 words
A process for reducing the hydrogen cyanide content of a gaseous stream which comprises: (a) providing an adsorbent bed wherein the adsorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkali or alkaline earth metal, and (b) contacting said process stream with said adsorbent bed at a temperature of from about ambient to about 350° C. for a period of time sufficient to reduce the concentration of hydrogen cyanide in said gaseous stream to the desired value.
Claim 2
Dependent Claim 85 words
A process for reducing the hydrogen cyanide content of a gaseous stream which comprises: (a) providing an adsorbent bed wherein the adsorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkali or alkaline earth metal, and (b) contacting said process stream with said adsorbent bed at a temperature of from about ambient to about 350° C. for a period of time sufficient to reduce the concentration of hydrogen cyanide in said gaseous stream to the desired value.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein the temperature of said adsorbent is from about 150° C. to about 300° C.
Claim 4
Dependent Claim 16 words
The process of claim 1 wherein said process stream additionally contains hydrogen sulfide as an impurity.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein said process stream additionally contains hydrogen chloride as an impurity.
Claim 6
Dependent Claim 33 words
The process of claim 1 wherein the concentration of hydrogen cyanide in the process stream prior to contacting said adsorbent bed is from about 1 to about 100 parts per million (by volume).
Claim 7
Dependent Claim 25 words
The process of claim 1 wherein the concentration of hydrogen cyanide in the process stream is reduced to below 0.1 parts per million (by volume).
Claim 8
Dependent Claim 91 words
A process for purifying a gaseous stream containing hydrogen cyanide, carbonyl sulfide, hydrogen sulfide and hydrogen chloride as impurities therein which comprises: (a) providing an adsorbent bed wherein the adsorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkali or alkaline earth metal, and (b) contacting said process stream with said adsorbent bed at a temperature of from about ambient to about 350° C. for a period of time sufficient to reduce the concentrations of each of said impurities to the desired value.
Claim 9
Dependent Claim 91 words
A process for purifying a gaseous stream containing hydrogen cyanide, carbonyl sulfide, hydrogen sulfide and hydrogen chloride as impurities therein which comprises: (a) providing an adsorbent bed wherein the adsorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkali or alkaline earth metal, and (b) contacting said process stream with said adsorbent bed at a temperature of from about ambient to about 350° C. for a period of time sufficient to reduce the concentrations of each of said impurities to the desired value.
Claim 10
Dependent Claim 35 words
The process of claim 7 wherein the concentration of carbonyl sulfide, hydrogen sulfide, hydrogen chloride and hydrogen cyanide in the gaseous stream prior to contacting said adsorbent bed is from about 1 to 100 ppmv.
Claim 11
Dependent Claim 23 words
The process of claim 7 wherein the concentration of each of said impurities in the gaseous stream is reduced to below 0.1 ppmv.
Claim 12
Dependent Claim 19 words
The process of claim 7 wherein the temperature of said adsorbent is from about 150° to about 300° C.

References Cited (Backward Citations)

US2239000A Cited
US2423689A Cited
US3492083A Cited
US3441370A Cited
US4009009A Cited
US4088736A Cited
US4128619A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-01 1984-12-01 1985-06-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-01 1988-12-01 1989-06-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-01 1992-12-01 1993-06-02 $7700.00 Window Closed / Lapsed

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