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US4259432A
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Photopolymerizable compositions having combined photoinitiators
Assignee: Fujifilm Holdings Corp
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Filing: 1979-10-05
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Granted: 1981-03-31
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Expires: 1999-10-05
Abstract
Abstract In a photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises that said photopolymerization initiator is a combination of (a) p-dialkylamino aromatic carbonyl compounds represented by the general formulae (1) to (4), (b) 5-isoxazolones represented by the general formula (5) and (c) 2,4,6-substituted-1,3,5-triazines represented by the general formula (6): ##STR1## where R 1 , R 2 and R 3 each represents an alkyl group or a substituted alkyl group, which may be the same or different from one another, X represents a substituent having a Hammett's σ value in the range from -0.9 to 0.7, m represents 1 or 2, A 1 and A 2 each represents an alkyl group, a substituted alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an arylcarbonyl group or a hydrogen atom, which may be the same or different from each other, and R 4 , R 5 and R 6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different from each other, but at least one of them represents a mono-, di- or trihalomethyl group.
Inventors
- 👤 Syunichi Kondoh
- 👤 Akihiro Matsufuji
- 👤 Yuji Ohara
- 👤 Akira Umehara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 15:43
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/114; Y10S430/117
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
221 words
In a photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises that said photopolymerization initiator is a combination of (a) p-dialkylamino aromatic carbonyl compounds represented by the general formulae (1) to (4), (b) 5-isoxazolones represented by the general formula (5) and (c) 2,4,6-substituted-1,3,5-triazines represented by the general formula (6): ##STR48## where R 1 , R 2 and R 3 each represents an alkyl grop or a substituted alkyl group, which may be the same or different from one another, X represents a substituent having a Hammett's σ value in the range from -0.9 to 0.7, m represents 1 or 2, A 1 and A 2 each represents an alkyl group, a substituted alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an arylcarbonyl group or a hydrogen atom, which may be the same or different from each other, and R 4 , R 5 and R 6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different from each other, but at least one of R 4 , R 5 and R 6 represents a mono-, di- or trihalomethyl group.
Claim 2
Dependent Claim
221 words
In a photopolymerizable composition comprising (1) an addition-polymerizable compound having at least one ethylenically unsaturated double bond and (2) a photopolymerization initiator as essential components, the improvement which comprises that said photopolymerization initiator is a combination of (a) p-dialkylamino aromatic carbonyl compounds represented by the general formulae (1) to (4), (b) 5-isoxazolones represented by the general formula (5) and (c) 2,4,6-substituted-1,3,5-triazines represented by the general formula (6): ##STR48## where R 1 , R 2 and R 3 each represents an alkyl grop or a substituted alkyl group, which may be the same or different from one another, X represents a substituent having a Hammett's σ value in the range from -0.9 to 0.7, m represents 1 or 2, A 1 and A 2 each represents an alkyl group, a substituted alkyl group, an alkylcarbonyl group, an alkoxycarbonyl group, an aryl group, a substituted aryl group, an arylcarbonyl group or a hydrogen atom, which may be the same or different from each other, and R 4 , R 5 and R 6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different from each other, but at least one of R 4 , R 5 and R 6 represents a mono-, di- or trihalomethyl group.
Claim 3
Dependent Claim
26 words
The photopolymerizable composition of claim 1 additionally comprising an organic high molecular material having film-forming ability and compatibility with components (1) and (2) as a binder.
Claim 4
Dependent Claim
39 words
The photopolymerizable composition of claims 1 or 2, wherein R 1 , R 2 and R 3 represent an alkyl group having 1 to 18 carbon atoms which may be substituted by a halogen atom or a hydroxyl group.
Claim 5
Dependent Claim
192 words
The photopolymerizable composition of claims 1 or 2, wherein X represents a substituent selected from the group consisting of a hydrogen atom, a methyl group, an ethyl group, an isopropyl group, a tert-butyl group, a phenyl group, a trifluoromethyl group, a cyano group, an acetyl group, an ethoxycarbonyl group, a carboxyl group, a carboxylato group (--COO - ), an amino group, a methylamino group, a dimethylamino group, an ethylamino group, a diethylamino group, an acetylamino group, --PO 3 H, a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a pentyloxy group, a phenoxy group, a hydroxyl group, an acetoxy group, a methylthio group, an ethylthio group, an isopropylthio group, a mercapto group, an acetylthio group, a thiocyano group (--SCN), a methylsulfinyl group, an ethylsulfinyl group, a methylsulfonyl group, an ethylsulfonyl group, an aminosulfonyl group, a dimethylsulfonyl group (--S + (CH 3 ) 2 ), a sulfonato group (--SO 3 - ), a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, an iodyl group, a trimethylsilyl group (--Si(CH 3 ) 3 ), a triethylsilyl group and a trimethylstannyl group (--Sn(CH 3 ) 3 ).
Claim 6
Dependent Claim
40 words
The photopolymerizable composition of claim 4, wherein X represents a hydrogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a dimethylamino group, a diethylamino group, a chlorine atom, a bromine atom or a cyano group.
Claim 7
Dependent Claim
85 words
The photopolymerizable composition of claims 1 or 2, wherein A 1 and A 2 represent an alkyl group having 1 to 5 carbon atoms which may be substituted with a halogen atom or a hydroxyl group, an alkylcarbonyl group having 2 to 6 carbon atoms, an alkoxycarbonyl group having 2 to 6 carbon atoms, or an aryl group which may be substituted by a halogen atom, an alkyl group having 1 to 5 carbon atoms, or an alkoxy group having 1 to 5 carbon atoms.
Claim 8
Dependent Claim
69 words
The photopolymerizable composition of claims 1 or 2, wherein R 4 , R 5 and R 6 represent an alkyl group having 1 to 18 carbon atoms which may be substituted by a halogen atom or a hydroxyl group, an aryl group which may be substituted by a halogen atom, an alkyl group or an alkoxy group, or a phenyl or naphthyl-substituted C 1 to C 10 alkyl group.
Claim 9
Dependent Claim
34 words
The photopolymerizable composition of claims 1 or 2, wherein said photopolymerization initiator is present in an mount of about 0.01 to about 20% by weight based on the weight of the addition-polymerizable compound (1).
Claim 10
Dependent Claim
36 words
The photopolymerizable composition of claims 1 or 2, wherein the ratio of said component (a) to said component (b) and the ratio of said component (a) to said component (c) is about 30:1 to about 1:30.
Claim 11
Dependent Claim
21 words
The photopolymerizable composition of claim 2, wherein said binder renders the composition developable by stripping, water, or an aqueous alkaline solution.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-30 | 1984-09-29 | 1985-03-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-30 | 1988-09-29 | 1989-03-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-30 | 1992-09-29 | 1993-03-31 | $7700.00 | Window Closed / Lapsed |