Patent FR951618A successfully refreshed from Google Patents.
US4189366A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Radiation curable compositions containing 5-halo-6-halomethyluracil derivatives as photoinitiators
Assignee: Eastman Chemical Co
•
Filing: 1979-01-15
•
Granted: 1980-02-19
•
Expires: 1999-01-15
Abstract
Abstract Ethylenically unsaturated compositions such as acrylic and methacrylic acid esters, vinyl esters, vinyl halides, unsaturated amides such as acrylamide, vinyl aromatics such as styrene, and various aliphatic and aromatic polyesters containing any of the above or other modifying components such as maleic, fumaric, itaconic, citraconic and the like, are very effectively and rapidly cured with certain 5-halo-6-halomethyluracil photoinitiators. These curable systems have extensive utility in the surface coatings industry, particularly in regard to cured protective coatings.
Inventors
- 👤 Gordon C. Newland
- 👤 Edward U. Elam
- 👤 James G. Pacifici
- 👤 Hobert M. Beard, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 03:36
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31616; Y10T428/3162; Y10T428/31645; Y10T428/31649
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
122 words
A photocurable composition comprising ethylenically unsaturated, polymerizable material containing a total of from about 0.1% to about 5.0% based on monomer weight, of one or more photoinitiators of the formula: ##STR9## wherein R 1 and R 2 each is selected from hydrogen; straight or branched alkyl of 1-20 carbons which may be substituted with lower alkoxy or phenoxy; alicylic of 5-10 carbons; aromatic of 6-12 carbons which may be substituted with up to four lower alkyl groups; and ##STR10## groups wherein n is 1-20, R 3 is lower alkyl, aromatic of 6-12 carbons or the radical --O--R 4 where R 4 is lower alkyl or aromatic of 6-12 carbons; and wherein X and X 1 are each selected from chlorine and bromine.
Claim 2
Dependent Claim
122 words
A photocurable composition comprising ethylenically unsaturated, polymerizable material containing a total of from about 0.1% to about 5.0% based on monomer weight, of one or more photoinitiators of the formula: ##STR9## wherein R 1 and R 2 each is selected from hydrogen; straight or branched alkyl of 1-20 carbons which may be substituted with lower alkoxy or phenoxy; alicylic of 5-10 carbons; aromatic of 6-12 carbons which may be substituted with up to four lower alkyl groups; and ##STR10## groups wherein n is 1-20, R 3 is lower alkyl, aromatic of 6-12 carbons or the radical --O--R 4 where R 4 is lower alkyl or aromatic of 6-12 carbons; and wherein X and X 1 are each selected from chlorine and bromine.
Claim 3
Dependent Claim
127 words
The composition of claim 1 wherein said polymerizable material is selected from compounds of the formula ##STR11## wherein n is 1-4, R 5 is hydrogen or methyl and R 6 is selected from mono- , di-, tri-, and tetravalent aliphatic hydrocarbons of 1-10 carbons, divalent groups --(C r H 2r O)-- t C r H 2r -- in which r is 2-8 and t is 1 to 10, and divalent alkylene groups of from 2-10 carbons containing carbonyloxy linkages; vinyl and vinylidene halides; unsaturated amides of 3-20 carbons; vinyl aromatics; and polyesters prepared by the reaction of α,β-unsaturated dicarboxylic acid and/or their anhydrides with polyhydric alcohols, and such polyesters wherein part of the α,β-unsaturated dicarboxylic acid is replaced by saturated aliphatic dicarboxylic acids or aromatic dicarboxylic acids.
Claim 4
Dependent Claim
25 words
The composition of claim 1 wherein the photoinitiator is selected from one or more of: 5-chloro-6-chloromethyl-1,3-dimethyluracil; 5-chloro-6-chloromethyl-1-ethyl-3-methyluracil; 5-chloro-6-chloromethyl-3-methyluracil; 5-chloro-6-chloromethyl-3-phenyluracil; 6-bromomethyl-5-chloro-1,3-dimethyluracil; 5-chloro-6-chloromethyluracil; 5-chloro-6-bromomethyluracil; 5-chloro-6-bromomethyl-1,3-dimethyluracil; and 6-bromomethyl-5-chlorouracil.
Claim 5
Dependent Claim
22 words
The composition of claim 3 wherein the polymerizable material is selected from the alkyl and hydroxyalkyl esters of acrylic and methacrylic acids.
Claim 6
Dependent Claim
9 words
A photocured coating of the composition of claim 1.
Claim 7
Dependent Claim
10 words
A substrate coated with the photocured coating of claim 1.
References Cited (Backward Citations)
US3254082A
Cited
US4089815A
Cited
US4113592A
Cited
US4040923A
Cited
US4043887A
Cited
US4080382A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-02-18 | 1983-08-20 | 1984-02-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-02-18 | 1987-08-20 | 1988-02-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-02-18 | 1991-08-20 | 1992-02-19 | $7700.00 | Window Closed / Lapsed |