US4254012A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reinforced composites containing cyanato resins
Assignee: BASF Corp
•
Filing: 1979-09-12
•
Granted: 1981-03-03
•
Expires: 1999-09-12
Abstract
Abstract Fibrous-reinforced composites, such as prepregs and sheet moulding compounds, are made with a thermosettable cyanato resin, a photopolymerizable compound, and, if required, a heat-activated accelerator for heat-curing the resin. Fibers may be impregnated with a liquid mixture of the resin and the photopolymerizable compound, and irradiated to cause the mixture to solidify through photopolymerization. The product, when desired, e.g., after stacking to form a multilayer laminate, or after shaping, is heated to cure the resin. Alternatively, the liquid mixture is irradiated to form a solid film into which the fibers are pressed, and then, when required, the assembly is heated to cure the resin. The cyanato resins employed are of formula ##STR1## where R is an aliphatic, cycloaliphatic, or, preferably, an aromatic organic, group of not more than 18 carbon atoms, a is zero, or, if R is an aromatic group, may alternatively be an integer of 1 to 3, and b is an integer of 1 to 6 such that (a+b) is at least 2.
Inventors
- 👤 George E. Green
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 03:14
CPC Classifications
B; B32; B32B; B32B5/00; B32B5/22; B32B5/24; B32B5/26; C; C08; C08L; C08L79/00; C08L79/04; B32B38/00; B32B38/08; B32B2260/00; B32B2260/02; B32B2260/021; B32B2260/04; B32B2260/046; B32B2305/00; B32B2305/07; B32B2305/076; B32B2307/00; B32B2307/50; B32B2307/542; B32B2307/546
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
76 words
Thermosettable composites consisting of (a) a fibrous reinforcing material, (b) a cyanato resin of the general formula ##STR19## where R is an aliphatic, cycloaliphatic, or an aromatic organic group of not more than 18 carbon atoms, a is zero, or, if R is an aromatic group, may alternatively be an integer of 1 to 3, and b is an integer of 1 to 6 such that (a+b) is at least 2, and (c) a photopolymerised compound.
Claim 2
Dependent Claim
76 words
Thermosettable composites consisting of (a) a fibrous reinforcing material, (b) a cyanato resin of the general formula ##STR19## where R is an aliphatic, cycloaliphatic, or an aromatic organic group of not more than 18 carbon atoms, a is zero, or, if R is an aromatic group, may alternatively be an integer of 1 to 3, and b is an integer of 1 to 6 such that (a+b) is at least 2, and (c) a photopolymerised compound.
Claim 3
Dependent Claim
18 words
The composites of claim 1, which also contain (d), a heat-activated accelerator for heat-curing of the cyanato resin.
Claim 4
Dependent Claim
14 words
The composites of claim 1, in which the cyanato resin (b) is a prepolymer.
Claim 5
Dependent Claim
153 words
The composites of claim 1, in which R denotes the residue, after removal of all the phenolic hydroxyl groups, of a phenol of formula ##STR20## where R 1 is a hydrogen or a halogen atom, an alkyl or alkoxy group of 1 to 4 carbon atoms, or a phenyl group, or two R 1 groups may, together with the indicated benzene ring, form a naphthalene ring, R 2 is a carbon-carbon bond, an alkylene group of 1 to 5 carbon atoms, an oxygen or sulfur atom, or a carbonyl or sulfonyl group, R 3 is a hydrogen or halogen atom, an alkyl or alkoxy group of 1 to 4 carbon atoms, a phenyl group, or a group of formula ##STR21## c is an integer of value (5-d), d is an integer of value 1 to 3, e is an integer of value (4-f), and f is an integer of value 1 or 2.
Claim 6
Dependent Claim
44 words
The composites of claim 1, in which the cyanato resin is m- or p-dicyanatobenzene, 1,3,5-tricyanatobenzene, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1,8-, 2,6-, or 2,7-dicyanatonaphthalene, 1,3,6-tricyanatonaphthalene, 4,4'-dicyanatodiphenyl, 2,2'-dicyanato-1,1'-dinaphthyl, 2,5-dicyanatoluene, 2-chloro-1,4-dicyanatobenzene, 2,4-dicyanatoacetophenone, 2-nitro-1,3-dicyanatobenzene, bis(4-cyanatophenyl)methane, bis(4-cyanatophenyl) ether, 4,4'-dicyanatobenzophenone, or 2,2-bis(4-cyanatophenyl)propane, or a prepolymer of any of these.
Claim 7
Dependent Claim
50 words
The composites of claim 1, in which R denotes an aromatic group and part of the cyanato resin is replaced by a cyanamide of formula R.sup.26 (NHCN).sub.t XXVIII where R 26 is an aliphatic, cycloaliphatic, heterocyclic, or aromatic organic radical and t is an integer of from 2 to 5.
Claim 8
Dependent Claim
50 words
The composites of claim 1, in which R denotes an aromatic group and part of the cyanato resin is replaced by an N-cyanosulphonamide of formula R.sup.27 (SO.sub.2 NHCN).sub.t XXIX where R 27 denotes an aliphatic, cycloaliphatic, or aromatic organic radical and t is an integer of from 2 to 5.
Claim 9
Dependent Claim
18 words
The composites of claim 1, in which the component (c) has been photopolymerised through a free-radical chain reaction.
Claim 10
Dependent Claim
34 words
The composites of claim 1, in which the component (c) has been produced by photopolymerisation of a compound having one carbon-carbon ethylenic linkage, or more than one carbon-carbon ethylenic linkage provided they are conjugated.
Claim 11
Dependent Claim
53 words
The composites of claim 1, in which component (c) has been obtained by photopolymerisation of an acrylate ester containing at least one group of the general formula VII, VIII, or IX ##STR22## where R 4 is a hydrogen, chlorine, or bromine atom, or an alkyl hydrocarbon group of 1 to 4 carbon atoms.
Claim 12
Dependent Claim
220 words
The composites of claim 10, in which the acrylate ester which has been photopolymerised is neopentyl glycol diacrylate or is of the formula ##STR23## where R 19 denotes --H, --OH, or --OOCCH═CH 2 , R 20 denotes --H, --CH 3 , --C 2 H 5 , --CH 2 OH, or --CH 2 OOCCH═CH 2 , R 21 denotes --H, --Cl, --CH 3 , or --C 2 H 5 , R 22 denotes an organic radical of valence q, linked through a carbon atom or carbon atoms thereof to the indicated q terminal oxygen atoms, R 23 denotes an organic radical of valence q, linked through a carbon atom thereof, other than the carbon atom of a carbonyl group, R 24 denotes CH 3 --, C 2 H 5 --, or CH 2 ═CHCOOCH 2 --, R 25 denotes either an alkyl group of 1 to 6 carbon atoms, an alkyl group of 1 to 6 carbon atoms substituted by one hydroxyl group, or a dialkylaminoalkyl group containing in all 3 to 12 carbon atoms, k is zero or 1, m is an integer of 1 to 8, n is an integer of 1 to 20, p is zero or a positive integer, provided that k and p are not both zero, and q is an integer of 1 to 4.
Claim 13
Dependent Claim
29 words
The composites of claim 1, in which the component (c) has been photopolymerised by reaction of an excited molecule of the monomer with an unexcited molecule of the monomer.
Claim 14
Dependent Claim
64 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two azido, coumarin, stilbene, disubstituted maleimide, pyridinone, chalcone, propenone, or pentadienone groups, or at least two acrylic acid groups which are substituted in their 3-position by groups having carbon-carbon ethylenic unsaturation or aromaticity in conjugation with the ethylenic double bond of the acrylic group.
Claim 15
Dependent Claim
51 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula N.sub.3 --R.sup.5 -- X or N.sub.3 --SO.sub.2 --R.sup.5 -- XI where R 5 is a mononuclear or dinuclear aromatic radical of 6 to 12 carbon atoms.
Claim 16
Dependent Claim
43 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula ##STR24## where R 6 is an oxygen atom, a carbonyloxy group, a sulfonyl group, or a sulfonyloxy group.
Claim 17
Dependent Claim
78 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula ##STR25## where R 7 is the residue, containing up to 8 carbon atoms in all, of a five or six-membered nitrogen-containing heterocyclic ring, fused to a benzene or naphthalene nucleus, and linked through a carbon atom of the said heterocyclic ring adjacent to a nitrogen hetero atom thereof to the indicated benzene nucleus.
Claim 18
Dependent Claim
52 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula ##STR26## directly attached to carbon atoms, where each R 8 is an alkyl group of 1 to 4 carbon atoms, a chlorine atom, or a phenyl group.
Claim 19
Dependent Claim
57 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains, directly attached to carbon atoms, at least two groups of the formula ##STR27## where R 9 is an aliphatic or cycloaliphatic radical of 1 to 8 carbon atoms and g is zero or an integer of 1 to 4.
Claim 20
Dependent Claim
183 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula ##STR28## where each R 10 is a halogen atom, or an alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkoxy, cycloalkoxy, alkenoxy, cycloalkenoxy, carbalkoxy, carbocycloalkoxy, carbalkenoxy, or carbocycloalkenoxy group, such organic groups containing 1 to 9 carbon atoms, or is a nitro group, or a carboxyl, sulfonic, or phosphoric acid group in the form of a salt, g is zero or an integer of 1 to 4, R 11 represents a grouping of formula ##STR29## wherein R 14 and R 15 are each individually a hydrogen atom, an alkyl group, or an aryl group, or conjointly denote a polymethylene chain of 2 to 4 methylene groups, R 16 and R 17 are each a hydrogen atom, an alkyl group, or an aryl group, R 12 represents a valence bond or a hydrogen atom, h and j are each zero, 1, or 2, with the proviso that they are not both zero, and R 13 denotes a sulfur atom or an oxygen atom.
Claim 21
Dependent Claim
76 words
The composites of claim 1, in which the compound which has been photopolymerised to furnish component (c) contains at least two groups of the formula R.sup.18 CH═C(R.sup.4)COO-- XXI where R 18 is an aliphatic or mononuclear aromatic, araliphatic, or heterocyclyl group which has ethylenic unsaturation or aromaticity in conjugation with the ethylenic double bond shown, and R 4 is a hydrogen, chlorine, or bromine atom, or an alkyl hydrocarbon group of 1 to 4 carbon atoms.
References Cited (Backward Citations)
GB1007790A
Cited
DE1190184B
Cited
US4025407A
Cited
US3935330A
Cited
US3962184A
Cited
US3943103A
Cited
US4017453A
Cited
BE844389A
Cited
BE844390A
Cited
US4031067A
Cited
US4059567A
Cited
US4066577A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-02 | 1984-09-01 | 1985-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-02 | 1988-09-01 | 1989-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-02 | 1992-09-01 | 1993-03-03 | $7700.00 | Window Closed / Lapsed |