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US4250144A Expired / Lapsed US ⏱️ 0.0 years remaining

Chlorine dioxide generating system

Assignee: BA BUSINESS CREDIT Inc
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Filing: 1979-06-14
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Granted: 1981-02-10
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Expires: 1999-06-14
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Abstract

Abstract A system for generating chlorine dioxide for use as a disinfectant in water or wastewater treatment, the system output including a percentage of chlorine at an acceptably low level, thereby avoiding the deleterious effect of chlorine in the disinfection process. The system is provided with a source of chlorine gas and a source of aqueous sodium chlorite, both of which are fed into a reactor to generate chloride dioxide therein. The output of the reactor is coupled to an ejector operated by a water stream to create a vacuum which draws chlorine dioxide from the reactor into the ejector to dilute the chlorine dioxide before it is supplied to a process being treated. The resultant negative pressure in the reactor acts to draw the chlorine gas therein from the source through a vacuum regulator which maintains the flow of chlorine gas into the reactor at a constant rate and acts to cut off the supply of chlorine in the absence of negative pressure.

Inventors

  • 👤 Brian J. Ratigan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 16:39
CPC Classifications
C; C01; C01B; C01B11/00; C01B11/02; C01B11/022; C01B11/023; C01B11/024; C02; C02F; C02F1/00; C02F1/72; C02F1/76; C02F2103/00; C02F2103/02; C02F2103/023

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 239 words
A chlorine dioxide generating system for treating a process with chlorine dioxide that is substantially free of chlorine comprising: A. a reactor having two inlets and an outlet, the reactor being constituted by a vertically-positioned packed column, said inlets being at the bottom and said outlet being at the top of the column; B. a supply of aqueous sodium chlorite coupled to one inlet of the reactor; C. an unpressurized supply of chlorine gas coupled to the other inlet of the reactor whereby gas is drawn into the reactor only when a negative pressure exists therein, the chlorine reacting with the sodium chlorite to generate chlorine dioxide; D. an ejector coupled to the outlet of said reactor and operated by a stream of water to produce a vacuum drawing chlorine dioxide from the reactor into the ejector to intermingle with the water stream, whereby the ejector discharges a dilute solution of chlorine dioxide for feeding to the process to be treated, the resultant negative pressure in the reactor drawing chlorine gas therein; and E. a vacuum regulator interposed between the other inlet to the reactor and the chlorine gas supply to effectively disconnect said supply from said reactor in the absence of a negative pressure therein, said regulator supplying chlorine gas at a predetermined constant flow rate to the reactor within a range of negative pressure values, said predetermined constant flow rate being independent of the negative pressure value.
Claim 2
Dependent Claim 239 words
A chlorine dioxide generating system for treating a process with chlorine dioxide that is substantially free of chlorine comprising: A. a reactor having two inlets and an outlet, the reactor being constituted by a vertically-positioned packed column, said inlets being at the bottom and said outlet being at the top of the column; B. a supply of aqueous sodium chlorite coupled to one inlet of the reactor; C. an unpressurized supply of chlorine gas coupled to the other inlet of the reactor whereby gas is drawn into the reactor only when a negative pressure exists therein, the chlorine reacting with the sodium chlorite to generate chlorine dioxide; D. an ejector coupled to the outlet of said reactor and operated by a stream of water to produce a vacuum drawing chlorine dioxide from the reactor into the ejector to intermingle with the water stream, whereby the ejector discharges a dilute solution of chlorine dioxide for feeding to the process to be treated, the resultant negative pressure in the reactor drawing chlorine gas therein; and E. a vacuum regulator interposed between the other inlet to the reactor and the chlorine gas supply to effectively disconnect said supply from said reactor in the absence of a negative pressure therein, said regulator supplying chlorine gas at a predetermined constant flow rate to the reactor within a range of negative pressure values, said predetermined constant flow rate being independent of the negative pressure value.
Claim 3
Dependent Claim 41 words
A system as set forth in claim 1, further including vacuum means to pull said sodium chlorite through a control valve, with a differential pressure regulator to minimize the effects of vacuum variations and provide a steady flow of sodium chlorite.
Claim 4
Dependent Claim 29 words
A system as set forth in claim 1, further including means to effect automatic operation in response to changes in chlorine dioxide demand over a 20:1 range of operation.
Claim 5
Dependent Claim 39 words
A chlorine dioxide generator system as set forth in claim 1, further including a rate valve interposed between said vacuum regulator and said other inlet, said valve being settable to determine the constant flow rate of said chlorine gas.
Claim 6
Dependent Claim 41 words
A chlorine dioxide generator system as set forth in claim 4, further including a backflow valve at said other inlet to prevent the contents of the reactor from flowing out through said other inlet when the reactor is not in operation.
Claim 7
Dependent Claim 43 words
A system as set forth in claim 1, wherein said aqueous sodium chlorite is derived from a source of sodium chlorite and a separate source of water, these sources being both coupled to said one inlet of said reactor through respective positive-displacement pumps.
Claim 8
Dependent Claim 29 words
A system as set forth in claim 6, further including means to control the drive of the pumps to cut off the pumps in the absence of negative pressure.
Claim 9
Dependent Claim 25 words
A system as set forth in claim 7 wherein said means includes an electronic control for the drive which is responsive to the negative pressure.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-10 1984-08-11 1985-02-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-10 1988-08-11 1989-02-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-10 1992-08-11 1993-02-10 $7700.00 Window Closed / Lapsed

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