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US4242212A Expired / Lapsed US ⏱️ 0.0 years remaining

Mannich additives modified by ditertiary alkyl phenol

Assignee: Ethyl Corp
•
Filing: 1979-04-09
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Granted: 1980-12-30
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Expires: 1999-04-09
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Abstract

Abstract Mannich additives formed from a 2,4- or 2,6-ditertiary alkyl "hindered" phenol, a polyamine, a formaldehyde-yielding reagent and at least one substantially hydrocarbon compound with at least one active or acidic hydrogen selected from the group consisting of a para mono-alkyl phenol, and an oxidized olefinic polymer, are improved Mannich additives for high temperature internal combustion engine lubrication.

Inventors

  • 👤 Joseph B. Hanson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:13
CPC Classifications
C; C10; C10M; C10M159/00; C10M159/12; C10M159/16; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/16; C10L1/1616; C10L1/22; C10L1/221; C10L1/222; C10L1/2222; C10L1/2225; C10L10/00; C10L10/04; C10L10/08; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2217/00; C10M2217/04; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/08; C10M2219/082; C10M2219/087; C10M2219/088; C10M2219/089; C10N; C10N2040/00; C10N2040/25; C10N2040/255; C10N2040/26

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 55 words
A composition comprising the Mannich reaction product of a ditertiary alkylphenol, formaldehyde or a formaldehyde-yielding compound, a polyamine, and a substantially hydrocarbon compound having at least one active or acidic hydrogen comprising a para-mono-alkylphenol or an oxidized olefinic polymer, wherein the reaction product is formed a a temperature of about 30° C. to 300° C.
Claim 2
Dependent Claim 55 words
A composition comprising the Mannich reaction product of a ditertiary alkylphenol, formaldehyde or a formaldehyde-yielding compound, a polyamine, and a substantially hydrocarbon compound having at least one active or acidic hydrogen comprising a para-mono-alkylphenol or an oxidized olefinic polymer, wherein the reaction product is formed a a temperature of about 30° C. to 300° C.
Claim 3
Dependent Claim 29 words
The composition of claim 1 wherein the ditertiary alkyl phenol is reacted with the product of the reaction of the formaldehyde-yielding reagent, the polyamine and the substantially hydrocarbon compound.
Claim 4
Dependent Claim 20 words
The composition of claim 1 wherein the ditertiary alkyl phenol comprises a 2,4-ditertiary alkyl phenol or a 2,6-ditertiary alkyl phenol.
Claim 5
Dependent Claim 37 words
The composition of claim 1 wherein the tertiary alkyl groups of the ditertiary alkyl phenol are independently selected from the group consisting of tertiary butyl, tertiary pentyl, tertiary hexyl, tertiary heptyl, tertiary octyl, tertiary nonyl, tertiary decyl.
Claim 6
Dependent Claim 23 words
The composition of claim 1 wherein the alkyl group in the para-mono-alkyl phenol has a molecular weight from about 120 to about 6,000.
Claim 7
Dependent Claim 33 words
The composition of claim 1 wherein the substantially hydrocarbon compound having at least one acidic or active hydrogen comprises a para alkyl phenol comprising a polybutene substituted phenol or a polypropene substituted phenol.
Claim 8
Dependent Claim 23 words
A lubricant comprising a major proportion of a lubricating oil and an effective anti-deposit and anti-wear amount of the composition of claim 1.
Claim 9
Dependent Claim 15 words
A gasoline containing an effective anti-deposit and anti-wear amount of the lubricant of claim 7.

References Cited (Backward Citations)

US2504742A Cited
US2962531A Cited
US2962442A Cited
US3036003A Cited
US3368972A Cited
US3544520A Cited
US3948619A Cited
US3872019A Cited
US4025316A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-30 1984-06-30 1984-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-30 1988-06-30 1988-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-30 1992-06-30 1992-12-30 $7700.00 Window Closed / Lapsed

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