US4235965A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Starch hydrolysis at high dry substance
Assignee: Unilever Bestfoods North America
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Filing: 1978-10-16
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Granted: 1980-11-25
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Expires: 1998-10-16
Abstract
Abstract Aqueous slurries of liquefied and at least partially solubilized starch of high solids concentration (substantially greater than 40%, by weight) are prepared directly by adding gradually, to an aqueous starch hydrolysate having not greater than 40% solids, granular starch in the presence of a bacterial α-amylase, under non-gelatinizing conditions, while gradually raising the temperature to not above 90° C. As a final step, the temperature can be brought to 90° C. or higher to liquefy any remaining starch.
Inventors
- 👤 Raoul G. P. Walon
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:14
CPC Classifications
C; C12; C12P; C12P19/00; C12P19/22; C08; C08B; C08B30/00; C08B30/12; C12P19/14
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
159 words
A process for preparing an aqueous slurry of a liquefied and substantially solubilized starch comprising the steps of: (a) preparing an aqueous slurry of starch hydrolyzate having a D.E. of about 1 to about 25 and a solids concentration of less than 40% by weight; (b) gradually adding granular starch to said slurry of starch hydrolyzate, held at a temperature below the normal gelatinization temperature of the starch, in the presence of sufficient bacterial alpha-amylase to liquefy the granular starch; (c) gradually raising the temperature of the mixture from 60° C. to 90° C. during the addition of further increments of starch, maintaining an effective temperature to insure non-gelatinizing conditions for the added starch; (d) termininating the addition of starch when the total dry substance of the slurry is between 47% and 70% by weight; and (e) recovering the slurry when the starch is substantially solubilized and has a dextrose equivalent (D.E.) of from about 9.1 to about 17.5.
Claim 2
Dependent Claim
159 words
A process for preparing an aqueous slurry of a liquefied and substantially solubilized starch comprising the steps of: (a) preparing an aqueous slurry of starch hydrolyzate having a D.E. of about 1 to about 25 and a solids concentration of less than 40% by weight; (b) gradually adding granular starch to said slurry of starch hydrolyzate, held at a temperature below the normal gelatinization temperature of the starch, in the presence of sufficient bacterial alpha-amylase to liquefy the granular starch; (c) gradually raising the temperature of the mixture from 60° C. to 90° C. during the addition of further increments of starch, maintaining an effective temperature to insure non-gelatinizing conditions for the added starch; (d) termininating the addition of starch when the total dry substance of the slurry is between 47% and 70% by weight; and (e) recovering the slurry when the starch is substantially solubilized and has a dextrose equivalent (D.E.) of from about 9.1 to about 17.5.
Claim 3
Dependent Claim
41 words
The process of claim 1, wherein the conditions under which the granular starch is added to the slurry are such as to avoid, at all times during the process, an increase in the viscosity of the starch to above 3,000 cps.
Claim 4
Dependent Claim
32 words
The process of claim 1, and further including the step of raising the temperature of the final slurry to between 90° C. and 150° C. in order to liquefy any remaining starch.
Claim 5
Dependent Claim
39 words
The process of claim 1, wherein the granular starch is gradually added to the slurry in the form of successive increments, and wherein each increment is substantially liquefied and solubilized by the α-amylase before the next increment is added.
Claim 6
Dependent Claim
54 words
The process of claim 1, wherein the initial aqueous slurry is prepared by subjecting an aqueous suspension of granular starch, having a solids content of not more than about 40%, to the action of a bacterial α-amylase, under conditions which liquefy and at least partially solubilize the starch while avoiding gelatinization of the starch.
Claim 7
Dependent Claim
29 words
The process of claim 1, wherein the initial aqueous slurry is prepared by dissolving a malto-dextrin into water, at a solids concentration or not greater than about 40% .
Claim 8
Dependent Claim
15 words
The process of claim 1, wherein the bacterial α-amylase is derived from a Bacillus microorganism.
Claim 9
Dependent Claim
16 words
The process of claim 7, wherein the bacterial α-amylase is derived from a Bacillus licheniformis microorganism.
Claim 10
Dependent Claim
25 words
The process of claim 1, wherein the pH, during the liquefaction of the starch, is maintained within the range of about 5 to about 7.5.
Claim 11
Dependent Claim
13 words
The process of claim 9, wherein the pH is maintained at about 6.
Claim 12
Dependent Claim
32 words
The process of claim 1, wherein Step (c) is accompanied by incremental increases in the temperature from a starting temperature of about 60° C. to a final temperature of about 85° C.
Claim 13
Dependent Claim
27 words
The process of claim 1, wherein the starch employed is selected from the group consisting of corn starch, potato starch, wheat starch, tapioca starch, and waxy starch.
Claim 14
Dependent Claim
24 words
The process of claim 1, including the additional step of subjecting the resulting high solids slurry of liquefied starch to an enzymatic saccharification process.
Claim 15
Dependent Claim
49 words
The process of claim 13, wherein the additional saccharification step is performed by bringing the high solids slurry to a temperature of about 60° C. and a pH of about 5.0, adding β-amylase and incubating for a time sufficient to produce a starch hydrolysate having a high maltose content.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-25 | 1984-05-26 | 1984-11-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-25 | 1988-05-26 | 1988-11-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-25 | 1992-05-26 | 1992-11-25 | $7700.00 | Window Closed / Lapsed |