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US4235650A Expired / Lapsed US ⏱️ 0.0 years remaining

Open tube aluminum diffusion

Assignee: General Electric Co
•
Filing: 1978-09-05
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Granted: 1980-11-25
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Expires: 1998-09-05
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Abstract

Abstract A method for forming a p-conductivity type layer in a semiconductor wafer using aluminum as a diffusion source and which can be carried out in an open diffusion tube is described. A variety of aluminum sources can be employed in an open tube. A stream of essentially oxygen-free inert gas provides transport for the dopant and prevents the entry of potentially contaminating ambient into the tube.

Inventors

  • 👤 Mike F. Chang
  • 👤 Alfred Roesch

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:03
CPC Classifications
H; H10; H10P; H10P32/00; H10P32/10; H10P32/12; H10P32/17; H10P32/171; Y; Y10; Y10S; Y10S148/00; Y10S148/033; Y10S252/00; Y10S252/95; Y10S252/951; Y10S438/00; Y10S438/909

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 83 words
A method for diffusing aluminum into a silicon semiconductor wafer comprising the steps of: disposing said wafer within an open diffusion tube; disposing a source of aluminum in said tube, said source being spaced apart from said wafer; providing a flow of non-oxidizing inert gas through said tube at a rate in excess of about 1 liter/min.; heating said tube to a temperature sufficient to create an aluminum vapor in said tube and to cause aluminum atoms to diffuse into said semiconductor wafer.
Claim 2
Independent Claim 83 words
A method for diffusing aluminum into a silicon semiconductor wafer comprising the steps of: disposing said wafer within an open diffusion tube; disposing a source of aluminum in said tube, said source being spaced apart from said wafer; providing a flow of non-oxidizing inert gas through said tube at a rate in excess of about 1 liter/min.; heating said tube to a temperature sufficient to create an aluminum vapor in said tube and to cause aluminum atoms to diffuse into said semiconductor wafer.
Claim 3
Dependent Claim 16 words
The method of claim 1 wherein said source of aluminum comprises a reuseable source of aluminum.
Claim 4
Dependent Claim 15 words
The method of claim 1 wherein said rate is between about 2 and 3 liters/min.
Claim 5
Dependent Claim 16 words
The method of claim 1 wherein said source of aluminum comprises a source of elemental aluminum.
Claim 6
Dependent Claim 16 words
The method of claim 1 wherein said source of aluminum is disposed upstream from said wafer.
Claim 7
Dependent Claim 37 words
The method of claim 1 wherein a plurality of wafers is diffused simultaneously and, further, wherein said source of aluminum comprises a wafer-shaped source of aluminum comprising disposing said wafers and said wafer-shaped sources in alternating fashion.
Claim 8
Dependent Claim 16 words
The method of claim 6 wherein said wafer-shaped source comprises a silicon wafer coated wth aluminum.
Claim 9
Dependent Claim 16 words
The method of claim 6 wherein said wafer-shaped source comprises a silicon wafer having aluminum impurities.
Claim 10
Dependent Claim 15 words
The method of claim 6 wherein said wafer-shaped source comprises an aluminum alloy source wafer.
Claim 11
Independent Claim 87 words
A method for forming a p-conductivity type region in an n-conductivity type silicon semiconductor wafer comprising: disposing said wafer in an open, non sealed diffusion tube; establishing a flow of inert gas in said tube, said flow being at a rate sufficient to substantially prevent ambient atmosphere from entering said tube; disposing a source of aluminum between said wafer and the source of said gas flow; heating said wafer and said source of aluminum within said tube to a temperature sufficient to diffuse aluminum into said wafer.
Claim 12
Independent Claim 87 words
A method for forming a p-conductivity type region in an n-conductivity type silicon semiconductor wafer comprising: disposing said wafer in an open, non sealed diffusion tube; establishing a flow of inert gas in said tube, said flow being at a rate sufficient to substantially prevent ambient atmosphere from entering said tube; disposing a source of aluminum between said wafer and the source of said gas flow; heating said wafer and said source of aluminum within said tube to a temperature sufficient to diffuse aluminum into said wafer.
Claim 13
Dependent Claim 22 words
The method of claim 10 wherein said rate of flow is at least 1 liter/min per 100 mm of inside tube diameter.
Claim 14
Dependent Claim 27 words
The method of claim 11 wherein said flow of inert gas comprises a flow of gas selected from the group consisting of argon gas and nitrogen gas.
Claim 15
Dependent Claim 16 words
The method of claim 11 wherein said source of aluminum comprises a source of elemental aluminum.
Claim 16
Dependent Claim 16 words
The method of claim 11 wherein said source of aluminum comprises a wafer-shaped source of aluminum.
Claim 17
Dependent Claim 27 words
The method of claim 10 for diffusing a plurality of wafers simultaneously comprising disposing said plurality of wafers alternately with a plurality of wafer-shaped sources of aluminum.
Claim 18
Dependent Claim 29 words
The method of claim 10 comprising heating said source and said wafer until a surface impurity concentration in said wafer of at least 10 17 atoms/cm 3 is obtained.
Claim 19
Dependent Claim 29 words
The method of claim 10 comprising heating said source and said wafer until a surface impurity concentration in said wafer of at least 10 18 atoms/cm 3 is obtained.
Claim 20
Dependent Claim 29 words
The method of claim 10 comprising heating said source and said wafer until a surface impurity concentration in said wafer of at least 10 19 atoms/cm 3 is obtained.
Claim 21
Dependent Claim 33 words
The method of claim 10 further comprising at least partially inhibiting said diffusion by introducing oxygen into said flow in an amount between about zero and about 0.5% by volume of said flow.
Claim 22
Dependent Claim 19 words
The method of claim 10 wherein said source of aluminum comprises a wafer of semiconductor material doped with aluminum.
Claim 23
Dependent Claim 26 words
The method of claim 10 wherein said source of aluminum comprises a wafer of semiconductor material having a layer of aluminum alloyed to a surface thereof.
Claim 24
Dependent Claim 20 words
The method of claim 10 wherein said source of aluminum comprises a wafer of semiconductor material having aluminum diffused therein.
Claim 25
Dependent Claim 21 words
The method of claim 10 wherein said source of aluminum comprises a substrate wafer having a layer of aluminum plated thereon.
Claim 26
Dependent Claim 15 words
The method of claim 23 wherein said substrate wafer is a wafer of semiconductor material.
Claim 27
Dependent Claim 10 words
The method of claim 24 wherein said material is silicon.

References Cited (Backward Citations)

US3589953A Cited
US3615945A Cited
US3852128A Cited
US3972838A Cited
US3997379A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-25 1984-05-26 1984-11-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-25 1988-05-26 1988-11-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-25 1992-05-26 1992-11-25 $7700.00 Window Closed / Lapsed

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