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US4232103A Expired / Lapsed US ⏱️ 0.0 years remaining

Phenyl benzotriazole stabilized photosensitive device

Assignee: Xerox Corp
•
Filing: 1979-08-27
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Granted: 1980-11-04
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Expires: 1999-08-27
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Abstract

Abstract An imaging member comprising a hole generation layer and a contiguous hole transport layer, said generation layer comprising a photoconductive material exhibiting the capability of photogeneration of holes and injection of said holes, said hole transport layer comprising a transparent electrically inactive polycarbonate resinous material having dispersed therein from about 25 to about 75% by weight of the composition of one or more of the following diamines: ##STR1## and wherein X is independently selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms and chlorine in the ortho, meta or para position, said transport layer also containing a chlorine-containing organic solvent, and a stabilizing proportion of a substituted or unsubstituted 2-(2'-hydroxyphenyl)-benzotriazole.

Inventors

  • 👤 William W. Limburg
  • 👤 Damodar M. Pai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:41
CPC Classifications
C; C07; C07D; C07D249/00; C07D249/16; C07D249/18; C07D249/20; G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0612; G03G5/0614; G03G5/06142; G03G5/06144; G03G5/061443

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 154 words
In an imaging member comprising a hole generation layer and a contiguous hole transport layer, said generation layer comprising a photoconductive material exhibiting the capability of photogeneration of holes and injection of said holes, said hole transport layer comprising a transparent electrically inactive polycarbonate resinous material having dispersed therein from about 25 to about 75% by weight of the composition of one or more of the following diamines: ##STR4## and wherein X is independently selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms and chlorine in the ortho, meta or para position, said transport layer also containing a chlorine-containing organic solvent in an amount less than about 3% by weight of the transport layer, the improvement consisting of stabilizing said transport layer against the deleterious effects of ultraviolet light by the presence in said transport layer of a stabilizing proportion of a substituted or unsubstituted 2-(2'-hydroxyphenyl)-benzotriazole.
Claim 2
Dependent Claim 154 words
In an imaging member comprising a hole generation layer and a contiguous hole transport layer, said generation layer comprising a photoconductive material exhibiting the capability of photogeneration of holes and injection of said holes, said hole transport layer comprising a transparent electrically inactive polycarbonate resinous material having dispersed therein from about 25 to about 75% by weight of the composition of one or more of the following diamines: ##STR4## and wherein X is independently selected from the group consisting of an alkyl group having from 1 to about 4 carbon atoms and chlorine in the ortho, meta or para position, said transport layer also containing a chlorine-containing organic solvent in an amount less than about 3% by weight of the transport layer, the improvement consisting of stabilizing said transport layer against the deleterious effects of ultraviolet light by the presence in said transport layer of a stabilizing proportion of a substituted or unsubstituted 2-(2'-hydroxyphenyl)-benzotriazole.
Claim 3
Dependent Claim 62 words
The member of claim 1 wherein the benzotriazole has the following general formula: ##STR5## wherein R 1 is hydrogen or a C 1 -C 5 alkyl, an aryl, alkaryl, aralkyl, sulfhydryl, NO 2 or a halogen; and R 2 and R 3 are independently selected from the group consisting of hydrogen, a C 1 -C 5 alkyl, aryl, alkaryl or aralkyl group.
Claim 4
Dependent Claim 24 words
The member of claim 2 wherein said transport layer is stabilized by a member selected from the group consisting of 2-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazole; 2-(2'-hydroxy-5'-methylphenyl)-benzotriazole; and 2-(2'-hydroxy-3'-di-tert-butylphenyl)-benzotriazole.
Claim 5
Dependent Claim 17 words
The method of claim 3 wherein said photoconductive material is trigonal selenium and said diamine is N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[1,1'-biphenyl]-4,4'-diamine.
Claim 6
Dependent Claim 22 words
The member of claim 3 wherein the benzotriazole compound is present in from about 0.1-10 percent by weight of the transport molecule.

References Cited (Backward Citations)

GB1337228A Cited
US4072520A Cited
US3997342A Cited
US4053311A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-04 1984-05-05 1984-11-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-04 1988-05-05 1988-11-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-04 1992-05-05 1992-11-04 $7700.00 Window Closed / Lapsed

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