Photohardenable composition

Claim 2

A photohardenable composition comprising: (a) about 10 to 80 weight percent of a halogenated oligomeric ester having a molecular weight of less than about 10,000 and a content of halogen attached to carbon of an sp 2 electronic configuration of about 19 to 55 weight percent; (b) about 10 to 80 weight percent of an acrylate or methacrylate monomer compatible with (a); (c) about 0.2 to 10 weight percent of a free radical generating initiator activatible by actinic light or electron beam irradiation; (d) about 2 to 20 weight percent of a compound having an average epoxide functionality of about 1 to 1.8; (e) about 1 to 10 weight percent of a cationic initiator activatible by actinic light or electron beam irradiation.

Claim 3

A photohardenable composition in accordance with claim 1, wherein said halogenated oligomeric ester contains chlorine as the halogen substituent and has a content of chlorine attached to carbon of an sp 2 electronic configuration of about 25 to 44 weight percent.

Claim 4

A photohardenable composition in accordance with claim 1, wherein said halogenated oligomeric ester contains chlorine and bromine as the halogen substituents and has a content of chlorine and bromine attached to carbon of an sp 2 electronic configuration of about 25 to 53 weight percent.

Claim 5

A photohardenable composition in accordance with claim 1, wherein said halogenatic oligomeric ester comprises halogenated acid, nonhalogenated acid and nonhalogenated alcohol components.

Claim 6

A photohardenable composition in accordance with claim 4, wherein said halogenated acid component is selected from the group consisting of tetrachlorophthalic anhydride, hexachloroendomethylene tetrahydrophthalic acid and tetrabromophthalic anhydride.

Claim 7

A photohardenable composition in accordance with claim 4, wherein the nonhalogenated acid component is selected from the group consisting of phthalic anhydride, phthalic acid, adipic acid, azelaic acid, benzoic acid and sebacic acid.

Claim 8

A photohardenable composition in accordance with claim 3, wherein the nonhalogenated alcohol component is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, neopentyl glycol, tripropylene glycol, triethylene glycol and tetraethylene glycol.

Claim 9

A photohardenable composition in accordance with claim 1, wherein said composition comprises about 35 to 65 weight percent of a halogenated oligomeric ester.

Claim 10

A photohardenable composition in accordance with claim 1, wherein said acrylate or methacrylate monomer is selected from the group consisting of 1,6-hexanediol diacrylate, tetraethylene glycol diacrylate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, diethylene glycol diacrylate, diethylene glycol dimethacrylate, ethylene glycol diacrylate and ethylene glycol dimethacrylate.

Claim 11

A photohardenable composition in accordance with claim 1, wherein said acrylate or methacrylate monomer comprises about 20 to 37 weight percent of said composition.

Claim 12

A photohardenable composition in accordance with claim 1, wherein said free-radical generating system is selected from the group consisting of diethoxyacetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2-chlorothioxanthone, fluorescein, benzoin methylether, benzoin ethylether, t-butyl anthraquinone and benzophenone.

Claim 13

A photohardenable composition in accordance with claim 1, wherein said epoxide is selected from the group consisting of glycidyl ether of p-tertiarybutylphenol and 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate.

Claim 14

A photohardenable composition in accordance with claim 1, wherein said cationic initiator is selected from the group consisting of φSφS(φ) 2 SbF 6 (where φ=phenyl), triphenylsulfonium hexafluoroantimonate, triphenylsulfonium hexafluoroantimonate, triphenylsulfonium tetrafluoroborate, triphenylsulfonium hexafluorophosphate, dimethylphenylsulfonium hexafluorophosphate and diphenyliodonium hexafluorophosphate.

Claim 15

A photohardenable composition in accordance with claim 1, wherein said composition further comprises up to about 25 weight percent of an organic polymeric binder soluble in said halogenated oligomeric ester and said acrylate or methacrylate monomer.

Claim 16

A photohardenable composition in accordance with claim 14, wherein said organic polymeric binder is selected from the group consisting of polymethyl methacrylate, polyester, methyl cellulose, ethyl cellulose, benzyl cellulose, cellulose acetate, cellulose acetate succinate, cellulose acetate butyrate, polyvinyl acetate, polyvinyl chloride, polyvinyl butyral, polyvinyl formal, polyurethanes, and copolymers of n-butylmethacrylate/methylmethacrylate, methylmethacrylate/n-butylmethacrylate/hydroxyethylmethacrylate, methylmethacrylate/n-butylmethacrylate/glycidylmethacrylate, vinylidene chloride/methacrylate vinylidene chloride/vinyl acetate, polyvinyl acetate/acrylate, polyvinyl acetate/methacrylate, polyvinyl chloride/acetate, styrene/butadiene and ethylene/vinyl acetate.

Claim 17

A photohardenable composition in accordance with claim 14, wherein said organic polymeric binder comprises about 2 to 10 weight percent of said composition.

Claim 18

The photohardenable composition in accordance with claim 1, said composition further containing up to 40 weight percent of filler.