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US4069055A Expired / Lapsed US ⏱️ 0.0 years remaining

Photocurable epoxy compositions containing group Va onium salts

Assignee: General Electric Co
•
Filing: 1975-12-09
•
Granted: 1978-01-17
•
Expires: 1995-12-09
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Abstract

Abstract Cationic polymerization of epoxy resin such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group Va elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 18:03
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; C; C07; C07C; C07C381/00; C07C381/12; C07F; C07F9/00; C07F9/66; C07F9/68; C07F9/90; C07F9/902; C08; C08F; C08F236/00; C08F236/02; C08F236/04; C08F236/14; C08F236/16; C08G; C08G59/00; C08G59/18; C08G59/68; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C08G85/00; C08L; C08L61/00; C08L61/04; C08L61/06; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/115

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 226 words
Photocurable compositions consisting essentially of A. an epoxy resin polymerizable to a higher molecular weight state, and B. an effective amount of a photodecomposable aromatic onium salt of a Group Va element capable of effecting the cure of (A) when exposed to radiant energy where the photodecomposable aromatic onium salt of a Group Va element has the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+.sub.d [MQ.sub.e ].sup.-(e-f), where R is a monovalent aromatic organic radical selected from carbocyclic radicals and heterocyclic radicals, R 1 is a monovalent organic aliphatic radical selected from alkyl, alkoxy, cycloalkyl and substituted derivatives thereof, R 2 is a polyvalent organic radical forming an aromatic heterocyclic or fused ring structure with X, X is a Group Va element selected from N, P, As, Sb and Bi, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 4 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 to 2 inclusive, and the sum of a + b + c is a value equal to 4 or the valence of X, d = e - f f = valence of M and is an integer equal to from 2 to 7 inclusive e is > f and is an integer having a value up to 8.
Claim 2
Dependent Claim 226 words
Photocurable compositions consisting essentially of A. an epoxy resin polymerizable to a higher molecular weight state, and B. an effective amount of a photodecomposable aromatic onium salt of a Group Va element capable of effecting the cure of (A) when exposed to radiant energy where the photodecomposable aromatic onium salt of a Group Va element has the formula, [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sup.+.sub.d [MQ.sub.e ].sup.-(e-f), where R is a monovalent aromatic organic radical selected from carbocyclic radicals and heterocyclic radicals, R 1 is a monovalent organic aliphatic radical selected from alkyl, alkoxy, cycloalkyl and substituted derivatives thereof, R 2 is a polyvalent organic radical forming an aromatic heterocyclic or fused ring structure with X, X is a Group Va element selected from N, P, As, Sb and Bi, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 4 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 to 2 inclusive, and the sum of a + b + c is a value equal to 4 or the valence of X, d = e - f f = valence of M and is an integer equal to from 2 to 7 inclusive e is > f and is an integer having a value up to 8.
Claim 3
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is a phosphonium salt.
Claim 4
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is an ammonium salt.
Claim 5
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is an arsonium salt.
Claim 6
Dependent Claim 16 words
A photocurable composition in accordance with claim 2, where the phosphonium salt is a phenacylphosphonium salt.
Claim 7
Dependent Claim 17 words
A photocurable composition in accordance with claim 3, where the ammonium salt is a phenacyl ammonium salt.
Claim 8
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is a tetrafluoroborate salt.
Claim 9
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is triphenylphenacylphosphonium fluoroborate.
Claim 10
Dependent Claim 20 words
A photocurable composition in accordance with claim 1, where the complex anion of the aromatic onium salt is a hexafluorophosphate.
Claim 11
Dependent Claim 15 words
A photocurable composition in accordance with claim 7, where the aromatic onium salt is ##STR27##
Claim 12
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the onium salt is prepared in situ.
Claim 13
Dependent Claim 21 words
A photocurable composition in accordance with claim 1, where a mixture of onium salts are employed as a Lewis Acid source.
Claim 14
Dependent Claim 8 words
A printing ink in accordance with claim 1.
Claim 15
Dependent Claim 17 words
A photocurable composition in accordance with claim 1 in the form of a fluid at room temperature.
Claim 16
Dependent Claim 15 words
A photocurable composition in accordance with claim 1 in the form of a free-flowing powder.
Claim 17
Dependent Claim 16 words
Photocurable compositions in accordance with claim 1, where the aromatic onium salt is triphenylphenacyl phosphonium hexafluoroantimonate.
Claim 18
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is triphenylphenacyl phosphonium hexafluoroarsenate.
Claim 19
Dependent Claim 18 words
A photocurable composition in accordance with claim 9, where the aromatic onium salt is a triphenylphenacyl phosphonium hexafluorophosphate.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-16 1981-07-18 1982-01-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-16 1985-07-18 1986-01-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-16 1989-07-18 1990-01-17 $7700.00 Window Closed / Lapsed

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