Patent US4223117A successfully refreshed from Google Patents.
US4223117A
Expired / Lapsed
US
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Process for producing olefin polymers
Assignee: Sumitomo Chemical Co Ltd
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Filing: 1978-04-10
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Granted: 1980-09-16
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Expires: 1998-04-10
Abstract
Abstract A process for the polymerization of olefins in the presence of a catalyst comprising a titanium compound and/or vanadium compound supported on a solid carrier and an organoaluminum compound, characterized in that said solid carrier comprises a solid product obtained by the reaction of an organomagnesium compound or a reaction mixture resulting from the organomagnesium compound and at least one compound selected from the group consisting of magnesium hydroxide, calcium hydroxide, zinc hydroxide and aluminum hydroxide, with an aluminum halogenide and/or silicon halogenide, whereby there are produced olefine polymers in an extremely large amount per unit weight of catalyst.
Inventors
- 👤 Takezo Sano
- 👤 Akio Kobayashi
- 👤 Yasuharu Yamada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 14:49
CPC Classifications
C; C08; C08F; C08F10/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
336 words
A process for the preparation of a solid catalyst component for olefin polymerization, which comprises (1) (a) reacting an organomagnesium compound represented by the formula, R 1 MgX and/or (R 1 ) 2 Mg, wherein R 1 is an alkyl group having 1 to 20 carbon atoms, aryl or alkenyl group and X is a halogen atom, with an aluminum halogenide and/or silicon halogenide in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of said organomagnesium compound to said halogenide being 0.1:1 to 10:1, or (1) (b) reacting an organomagnesium compound represented by the formula R 1 MgX and/or (R 1 ) 2 Mg, wherein R 1 and X are as defined above, with at least one hydroxide selected from the group consisting of magnesium hydroxide, calcium hydroxide, zinc hydroxide, and aluminum hydroxide in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of said organomagnesium compound to said hydroxide compound being 1:0.01 to 1:10, and reacting a reaction mixture thus obtained with an aluminum halogenide and/or silicon halogenide being in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of the organomagnesium compound to said halogenide being 0.1:1 to 10:1, (2) filtering and drying the resulting reaction products thereby to obtain a solid carrier containing the adsorbed ether compound, (3) supporting a titanium compound represented by the formula, Ti(OR 5 ) 4-p X p , wherein R 5 is an alkyl group having 1 to 20 carbon atoms, cycloalkyl or phenyl group, X is a halogen atom and p is a number satisfying the formula, 0≦p≦4, and/or a compound selected from the group consisting of vanadium tetrachloride, and oxyvanadium trichloride on said carrier at a temperature of -20° to 150° C., wherein the amount of said titanium and/or vanadium compound supported on said carrier is 0.01 to 30% by weight in terms of titanium and/or vanadium based on the total amount of the supported compound and the solid carrier.
Claim 2
Dependent Claim
336 words
A process for the preparation of a solid catalyst component for olefin polymerization, which comprises (1) (a) reacting an organomagnesium compound represented by the formula, R 1 MgX and/or (R 1 ) 2 Mg, wherein R 1 is an alkyl group having 1 to 20 carbon atoms, aryl or alkenyl group and X is a halogen atom, with an aluminum halogenide and/or silicon halogenide in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of said organomagnesium compound to said halogenide being 0.1:1 to 10:1, or (1) (b) reacting an organomagnesium compound represented by the formula R 1 MgX and/or (R 1 ) 2 Mg, wherein R 1 and X are as defined above, with at least one hydroxide selected from the group consisting of magnesium hydroxide, calcium hydroxide, zinc hydroxide, and aluminum hydroxide in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of said organomagnesium compound to said hydroxide compound being 1:0.01 to 1:10, and reacting a reaction mixture thus obtained with an aluminum halogenide and/or silicon halogenide being in an ethereal solvent at a temperature of -20° to 200° C., the molar ratio of the organomagnesium compound to said halogenide being 0.1:1 to 10:1, (2) filtering and drying the resulting reaction products thereby to obtain a solid carrier containing the adsorbed ether compound, (3) supporting a titanium compound represented by the formula, Ti(OR 5 ) 4-p X p , wherein R 5 is an alkyl group having 1 to 20 carbon atoms, cycloalkyl or phenyl group, X is a halogen atom and p is a number satisfying the formula, 0≦p≦4, and/or a compound selected from the group consisting of vanadium tetrachloride, and oxyvanadium trichloride on said carrier at a temperature of -20° to 150° C., wherein the amount of said titanium and/or vanadium compound supported on said carrier is 0.01 to 30% by weight in terms of titanium and/or vanadium based on the total amount of the supported compound and the solid carrier.
Claim 3
Dependent Claim
52 words
A process according to claim 1, wherein said aluminum halogenide is represented by the formula, (R 3 ) n AlX 3-n wherein R 3 is an alkyl group having 1 to 20 carbon atoms, aryl or alkenyl group, X is a halogen atom and n is a number satisfying the formula, 0≦n<3.
Claim 4
Dependent Claim
13 words
A process according to claim 2, wherein said aluminum halogenide is aluminum chloride.
Claim 5
Dependent Claim
52 words
A process according to claim 1, wherein said silicon halogenide is represented by the formula, (R 4 ) m SiX 4-m wherein R 4 is an alkyl group having 1 to 20 carbon atoms, aryl or alkenyl group, X is a halogen atom and m is a number satisfying the formula, 0≦m<4.
Claim 6
Dependent Claim
13 words
A process according to claim 4, wherein said silicon halogenide in silicon tetrachloride.
Claim 7
Dependent Claim
16 words
A process according to claim 1, wherein said ethereal solvent is diethyl ether or isoamyl ether.
Claim 8
Dependent Claim
25 words
A process according to claim 1, wherein said molar ratio of the organomagnesium compound to the hydroxide is within the range of 1/0.1 to 1/1.
Claim 9
Dependent Claim
29 words
A process according to claim 1, wherein said molar ratio of the organomagnesium compound to the aluminum halogenide and/or silicon halogenide is within the range of 1/1 to 5/1.
Claim 10
Dependent Claim
44 words
A process according to claim 1, wherein said amount of the titanium compound and/or vanadium compounds supported on the solid carrier is 0.1 to 15% by weight interms of titanium and/or vanadium based on the total amount of the supported compound and the carrier.
Claim 11
Dependent Claim
11 words
A solid catalyst component obtained by the method of claim 1.
Claim 12
Dependent Claim
26 words
A process for producing olefin polymers, which comprises polymerizing an olefin in the presence of the solid catalyst component of claim 10 and an organoluminum compound.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-16 | 1984-03-17 | 1984-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-16 | 1988-03-17 | 1988-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-16 | 1992-03-17 | 1992-09-16 | $7700.00 | Window Closed / Lapsed |