Patent US4223073A successfully refreshed from Google Patents.
US4223073A
Expired / Lapsed
US
⏱️ 0.0 years remaining
High-temperature damping composite
Assignee: 3M Co
•
Filing: 1978-10-30
•
Granted: 1980-09-16
•
Expires: 1998-10-30
Abstract
Abstract Vibration-damping composite comprising one or more structural metal sheets having adhered thereto a viscoelastic polycyanurate polymer which effectively damps vibrations at elevated temperatures after prolonged exposure thereto. A preferred structural sheet is dead-soft aluminum-killed steel.
Inventors
- 👤 Donald B. Caldwell
- 👤 Thomas F. Gardeski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 02:03
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; B32B15/06; B32B15/18; F; F01; F01M; F01M11/00; F01M11/0004; F02; F02B; F02B77/00; F02F; F02F7/00; F02F7/0065; F02F7/008; G; G10; G10K; G10K11/00; G10K11/16; G10K11/162; G10K11/168; F01M2011/0008; F01M2011/0091; F05; F05C; F05C2225/00; F05C2225/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31678; Y10T428/31692; Y10T428/31699
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
289 words
A composite at least 1/2 meter in both width and length of a structural metal sheet and a viscoelastic layer, which composite can be formed to provide components of or facings for machines in order to provide effective damping of vibrations in such machines during prolonged high-temperature operation, said metal sheet having an average plastic strain ratio r of at least 1.3, a strain-hardening exponent n of at least 0.11 in the equation σ=Kε.sup.n where σ is the true stress, K is a constant and ε is the true strain, and a thickness of at least 0.2 mm, and said viscoelastic layer having a thickness of at least 20 micrometers and being a cured polycyanurate polymer comprising the repeating unit ##STR7## wherein each R is the residue after removal of the hydroxyl radicals from one of (a) HO--Ar--OH (b) ##STR8## (c) HOCH 2 --(CH 2 CH 2 ) j (CF 2 CFX) k ] m CH 2 OH (d) HO--CH 2 CF 2 (CF 2 ) h CF 2 CH 2 OH wherein h is 0 or an integer of 1 to 6, j and k are integers whose ratio j/k is 1/1 to 10/1, m is an integer of 1 to 100, n is an integer of 1 to 20, X is fluorine or perfluoroalkyl, --Ar--represents ##STR9## wherein Z represents --S--, --SO 2 --, --O--, ##STR10## wherein R 1 and R 2 represent hydrogen, lower alkyl or ##STR11## wherein ω is an integer from 2 to 6, ##STR12## and the polycyanurate polymer has sufficient crosslinks such that its cyanurate nitrogen comprises 0.5 to 2% of its total weight when the polymer comprises 60% fluorine and 1.0 to 3.5% of its total weight when it is free from fluorine.
Claim 2
Dependent Claim
289 words
A composite at least 1/2 meter in both width and length of a structural metal sheet and a viscoelastic layer, which composite can be formed to provide components of or facings for machines in order to provide effective damping of vibrations in such machines during prolonged high-temperature operation, said metal sheet having an average plastic strain ratio r of at least 1.3, a strain-hardening exponent n of at least 0.11 in the equation σ=Kε.sup.n where σ is the true stress, K is a constant and ε is the true strain, and a thickness of at least 0.2 mm, and said viscoelastic layer having a thickness of at least 20 micrometers and being a cured polycyanurate polymer comprising the repeating unit ##STR7## wherein each R is the residue after removal of the hydroxyl radicals from one of (a) HO--Ar--OH (b) ##STR8## (c) HOCH 2 --(CH 2 CH 2 ) j (CF 2 CFX) k ] m CH 2 OH (d) HO--CH 2 CF 2 (CF 2 ) h CF 2 CH 2 OH wherein h is 0 or an integer of 1 to 6, j and k are integers whose ratio j/k is 1/1 to 10/1, m is an integer of 1 to 100, n is an integer of 1 to 20, X is fluorine or perfluoroalkyl, --Ar--represents ##STR9## wherein Z represents --S--, --SO 2 --, --O--, ##STR10## wherein R 1 and R 2 represent hydrogen, lower alkyl or ##STR11## wherein ω is an integer from 2 to 6, ##STR12## and the polycyanurate polymer has sufficient crosslinks such that its cyanurate nitrogen comprises 0.5 to 2% of its total weight when the polymer comprises 60% fluorine and 1.0 to 3.5% of its total weight when it is free from fluorine.
Claim 3
Dependent Claim
38 words
In a composite as defined in claim 1, the further improvement comprising: the cured polycyanurate polymer further comprises repeating units such that up to 50% of the R groups are residues of monofunctional equivalents of the hydroxyl-terminated compounds.
Claim 4
Dependent Claim
20 words
In a composite as defined in claim 1, the further improvement comprising: the R groups are primarily derived from epsilon-caprolactone.
Claim 5
Dependent Claim
24 words
In a composite as defined in claim 3, the further improvement comprising: an appreciable proportion of the R groups are derived from a diphenol.
Claim 6
Dependent Claim
17 words
In a composite as defined in claim 4, the further improvement comprising: the diphenol is Bisphenol A.
Claim 7
Dependent Claim
18 words
In a composite as defined in claim 1, the further improvement comprising: said drawable sheet is aluminum-killed steel.
Claim 8
Dependent Claim
25 words
In a composite as defined in claim 1, the further improvement comprising: said viscoelastic layer is adhered to the drawable sheet by a thermoset resin.
Claim 9
Dependent Claim
32 words
In a composite as defined in claim 1, the further improvement comprising: said composite is a laminate comprising two sheets of sheet metal of good drawing quality and a central viscoelastic layer.
Claim 10
Dependent Claim
35 words
In a composite as defined in claim 8, the further improvement comprising: said viscoelastic layer is adhered directly to one of said metal sheets and a thermoset resin adheres it to the other metal sheet.
Claim 11
Dependent Claim
22 words
In a composite as defined in claim 8, the further improvement comprising: said viscoelastic layer incorporates a central layer of thermoset resin.
Claim 12
Dependent Claim
12 words
A shaped article formed from a laminate as defined in claim 8.
Claim 13
Dependent Claim
20 words
A machine having a contoured wall to which is bonded said viscoelastic layer of the composite defined in claim 1.
References Cited (Backward Citations)
US3087565A
Cited
US3271188A
Cited
US3147314A
Cited
US3007679A
Cited
US3399103A
Cited
US3399104A
Cited
US3562091A
Cited
US3562092A
Cited
US3647891A
Cited
US3733349A
Cited
US3803088A
Cited
US4032089A
Cited
US4082141A
Cited
US4126742A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-16 | 1984-03-17 | 1984-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-16 | 1988-03-17 | 1988-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-16 | 1992-03-17 | 1992-09-16 | $7700.00 | Window Closed / Lapsed |