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US4223073A Expired / Lapsed US ⏱️ 0.0 years remaining

High-temperature damping composite

Assignee: 3M Co
•
Filing: 1978-10-30
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Granted: 1980-09-16
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Expires: 1998-10-30
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Abstract

Abstract Vibration-damping composite comprising one or more structural metal sheets having adhered thereto a viscoelastic polycyanurate polymer which effectively damps vibrations at elevated temperatures after prolonged exposure thereto. A preferred structural sheet is dead-soft aluminum-killed steel.

Inventors

  • 👤 Donald B. Caldwell
  • 👤 Thomas F. Gardeski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 02:03
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; B32B15/06; B32B15/18; F; F01; F01M; F01M11/00; F01M11/0004; F02; F02B; F02B77/00; F02F; F02F7/00; F02F7/0065; F02F7/008; G; G10; G10K; G10K11/00; G10K11/16; G10K11/162; G10K11/168; F01M2011/0008; F01M2011/0091; F05; F05C; F05C2225/00; F05C2225/02; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544; Y10T428/31678; Y10T428/31692; Y10T428/31699

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 289 words
A composite at least 1/2 meter in both width and length of a structural metal sheet and a viscoelastic layer, which composite can be formed to provide components of or facings for machines in order to provide effective damping of vibrations in such machines during prolonged high-temperature operation, said metal sheet having an average plastic strain ratio r of at least 1.3, a strain-hardening exponent n of at least 0.11 in the equation σ=Kε.sup.n where σ is the true stress, K is a constant and ε is the true strain, and a thickness of at least 0.2 mm, and said viscoelastic layer having a thickness of at least 20 micrometers and being a cured polycyanurate polymer comprising the repeating unit ##STR7## wherein each R is the residue after removal of the hydroxyl radicals from one of (a) HO--Ar--OH (b) ##STR8## (c) HOCH 2 --(CH 2 CH 2 ) j (CF 2 CFX) k ] m CH 2 OH (d) HO--CH 2 CF 2 (CF 2 ) h CF 2 CH 2 OH wherein h is 0 or an integer of 1 to 6, j and k are integers whose ratio j/k is 1/1 to 10/1, m is an integer of 1 to 100, n is an integer of 1 to 20, X is fluorine or perfluoroalkyl, --Ar--represents ##STR9## wherein Z represents --S--, --SO 2 --, --O--, ##STR10## wherein R 1 and R 2 represent hydrogen, lower alkyl or ##STR11## wherein ω is an integer from 2 to 6, ##STR12## and the polycyanurate polymer has sufficient crosslinks such that its cyanurate nitrogen comprises 0.5 to 2% of its total weight when the polymer comprises 60% fluorine and 1.0 to 3.5% of its total weight when it is free from fluorine.
Claim 2
Dependent Claim 289 words
A composite at least 1/2 meter in both width and length of a structural metal sheet and a viscoelastic layer, which composite can be formed to provide components of or facings for machines in order to provide effective damping of vibrations in such machines during prolonged high-temperature operation, said metal sheet having an average plastic strain ratio r of at least 1.3, a strain-hardening exponent n of at least 0.11 in the equation σ=Kε.sup.n where σ is the true stress, K is a constant and ε is the true strain, and a thickness of at least 0.2 mm, and said viscoelastic layer having a thickness of at least 20 micrometers and being a cured polycyanurate polymer comprising the repeating unit ##STR7## wherein each R is the residue after removal of the hydroxyl radicals from one of (a) HO--Ar--OH (b) ##STR8## (c) HOCH 2 --(CH 2 CH 2 ) j (CF 2 CFX) k ] m CH 2 OH (d) HO--CH 2 CF 2 (CF 2 ) h CF 2 CH 2 OH wherein h is 0 or an integer of 1 to 6, j and k are integers whose ratio j/k is 1/1 to 10/1, m is an integer of 1 to 100, n is an integer of 1 to 20, X is fluorine or perfluoroalkyl, --Ar--represents ##STR9## wherein Z represents --S--, --SO 2 --, --O--, ##STR10## wherein R 1 and R 2 represent hydrogen, lower alkyl or ##STR11## wherein ω is an integer from 2 to 6, ##STR12## and the polycyanurate polymer has sufficient crosslinks such that its cyanurate nitrogen comprises 0.5 to 2% of its total weight when the polymer comprises 60% fluorine and 1.0 to 3.5% of its total weight when it is free from fluorine.
Claim 3
Dependent Claim 38 words
In a composite as defined in claim 1, the further improvement comprising: the cured polycyanurate polymer further comprises repeating units such that up to 50% of the R groups are residues of monofunctional equivalents of the hydroxyl-terminated compounds.
Claim 4
Dependent Claim 20 words
In a composite as defined in claim 1, the further improvement comprising: the R groups are primarily derived from epsilon-caprolactone.
Claim 5
Dependent Claim 24 words
In a composite as defined in claim 3, the further improvement comprising: an appreciable proportion of the R groups are derived from a diphenol.
Claim 6
Dependent Claim 17 words
In a composite as defined in claim 4, the further improvement comprising: the diphenol is Bisphenol A.
Claim 7
Dependent Claim 18 words
In a composite as defined in claim 1, the further improvement comprising: said drawable sheet is aluminum-killed steel.
Claim 8
Dependent Claim 25 words
In a composite as defined in claim 1, the further improvement comprising: said viscoelastic layer is adhered to the drawable sheet by a thermoset resin.
Claim 9
Dependent Claim 32 words
In a composite as defined in claim 1, the further improvement comprising: said composite is a laminate comprising two sheets of sheet metal of good drawing quality and a central viscoelastic layer.
Claim 10
Dependent Claim 35 words
In a composite as defined in claim 8, the further improvement comprising: said viscoelastic layer is adhered directly to one of said metal sheets and a thermoset resin adheres it to the other metal sheet.
Claim 11
Dependent Claim 22 words
In a composite as defined in claim 8, the further improvement comprising: said viscoelastic layer incorporates a central layer of thermoset resin.
Claim 12
Dependent Claim 12 words
A shaped article formed from a laminate as defined in claim 8.
Claim 13
Dependent Claim 20 words
A machine having a contoured wall to which is bonded said viscoelastic layer of the composite defined in claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-09-16 1984-03-17 1984-09-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-09-16 1988-03-17 1988-09-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-09-16 1992-03-17 1992-09-16 $7700.00 Window Closed / Lapsed

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