Patent US4218294A successfully refreshed from Google Patents.
US4218294A
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Radiation curable coating composition
Assignee: Design Cote Corp
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Filing: 1977-09-21
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Granted: 1980-08-19
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Expires: 1997-09-21
Abstract
Abstract Release coatings are provided by including in a liquid monomer or prepolymer polymerizable by electromagnetic or ionizing radiation a waxy material of limited compatibility therein. Upon application of a film of such material by casting, coating or printing, a thin layer of the waxy material migrates to the surface to provide, after cure, the desired release properties. The thin surface layer of waxy material also tends to exclude oxygen from the film to permit radiant curing in air. Preferably the polymerizable liquid comprises acrylate monomers with or without unsaturated prepolymers co-polymerizable therewith dissolved therein. Novel prepolymers especially useful for providing release films and other radiation curable coatings are described, including the reaction product of polyamides, containing primary and secondary amine groups with unsaturated polybasic carboxylic acids and particular reaction products of polyether triols with toluene diisocyanate, modified with unsaturated monomers. Also described is the inclusion in the polymerizable liquid of a dispersed substantially linear polymer as shrink control and re-inforcing agent.
Inventors
- 👤 Karl Brack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 11:11
CPC Classifications
C; C08; C08F; C08F283/00; C08F283/04; C08F290/00; C08F290/02; C08F290/06; C08F290/065; C08F299/00; C08F299/02; C08F299/06; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31522; Y10T428/31652; Y10T428/31663; Y10T428/31678; Y10T428/31681; Y10T428/31725; Y10T428/31765; Y10T428/31786
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
79 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material comprising a reactive amine-containing polyamide prepolymer modified by condensation with a member selected from the group consisting of an unsaturated dicarboxylic acid anhydride or lower ester of such an acid, the portion of the modifying member to the remainder of the polymer being in the range from 10:1 to 1:10; an admixture, with the modified amine-containing polyamide prepolymer, of one or more acrylate or methacrylate monomers; and an aromatic ketone photoinitiator.
Claim 2
Dependent Claim
79 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material comprising a reactive amine-containing polyamide prepolymer modified by condensation with a member selected from the group consisting of an unsaturated dicarboxylic acid anhydride or lower ester of such an acid, the portion of the modifying member to the remainder of the polymer being in the range from 10:1 to 1:10; an admixture, with the modified amine-containing polyamide prepolymer, of one or more acrylate or methacrylate monomers; and an aromatic ketone photoinitiator.
Claim 3
Dependent Claim
37 words
A radiation curable prepolymer material as defined in claim 1 in which: said unsaturated dicarboxylic acid anhydride or ester thereof is a material selected from the group consisting of dimethyl itaconate and 5-norbonene-2, 3, dicarboxylic anhydride thereof.
Claim 4
Dependent Claim
58 words
A radiation curable prepolymer material as defined in claim 1 in which: said acrylate or methacrylate monomers are selected from the group consisting of trimethylolpropane triacrylate, tetraethylene glycol diacrylate and acrylic acid, hydroxyethyl acrylate, neopentyl glycol diacrylate, acrylated epoxidized soybean oil, hexanediol diacrylate, 1, 4-butanediol diacrylate, pentaerythritol triacrylate, butyl acrylate, isodecylacrylate, octadecyl acrylate, corresponding methacrylates, and mixtures thereof.
Claim 5
Dependent Claim
42 words
A radiation curable prepolymer material as defined in claim 1 wherein said aromatic ketone photoiniator is selected from the group consisting of: benzoin lower alkyl ethers, acetophenone, benzophenone, benzil, Michlers ketone, 2,2-diethoxyacetophenone 2,2-dimethoxy-2-phenylacetophenone, "Sandoray-1000" (a homogeneous halogen containing alkylarylketone), and mixtures thereof.
Claim 6
Dependent Claim
25 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 1 in which the amine-containing polyamide prepolymer contains primary and/or secondary amine groups.
Claim 7
Dependent Claim
26 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 1 in which said primary and/or secondary amine groups are positioned internally and/or terminally.
Claim 8
Dependent Claim
44 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 1 in which hydrocarbon wax, oleamide, polysiloxane, silicone or silane, fluoracarbon oil or wax, or any two or more of them, is added to said one or more acrylic or methacrylic monomers.
Claim 9
Dependent Claim
68 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 1 in which the modified polyamide is produced by heating a methyl or ethyl ester, or mixed methyl and ethyl esters, of one or more dicarboxy unsaturated acids, followed by evaporating methanol, ethanol, or both, and excess ethyl or methyl esters, or both, and completing the evaporation in the presence of an inhibitor of premature polymerization.
Claim 10
Dependent Claim
19 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 8 in which the inhibitor is p-methoxyphenol.
Claim 11
Dependent Claim
43 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 8 in which the ester of a dicarboxy unsaturated acid is a substance selected from the group consisting of dimethyl maleate, diethyl maleate, dimethyl fumarate, diethylfumarate, dimethyl itaconate, and mixtures thereof.
Claim 12
Dependent Claim
30 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 8 in which the modified prepolymer is obtained by heating 5-norbornene-2, 3 dicarboxyl anhydride with a polyamide amine.
Claim 13
Dependent Claim
46 words
A radiation curable, film-forming, spreadable unsaturated prepolymer material as defined in claim 8 in which the modified prepolymer is obtained by heating a polyamide polyamine with an ethyl or methyl ester, or both, of an unsaturated dicarboxylic acid, or 5-norbornene-2, 3, dicarboxylic acid and stripping volatiles.
Claim 14
Dependent Claim
22 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 1 in which a pigment is added with stearyl acrylate.
Claim 15
Dependent Claim
37 words
A radiation curable, film-forming, spreadable, unsaturated prepolymer material as defined in claim 13 in which the pigment is selected from the class consisting of lithol rubine, molybdate orange, chrome yellow, phthalocanine blue, carbon black, or a dye.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-08-19 | 1984-02-18 | 1984-08-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-08-19 | 1988-02-18 | 1988-08-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-08-19 | 1992-02-18 | 1992-08-19 | $7700.00 | Window Closed / Lapsed |