US4214019A
Expired / Lapsed
US
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Cavity filling with a hot melt adhesive composition
Assignee: Solutia Inc
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Filing: 1978-10-04
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Granted: 1980-07-22
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Expires: 1998-10-04
Abstract
Abstract A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition and sanding the composition to provide a surface even with the surrounding substrate. The adhesive composition comprises a block copolymer, aluminum powder, glass fiber and hollow inorganic silicate microspheres. The block copolymer is selected from the group consisting of copolyesters, coplyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature above 150 DEG C. and having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments. The weight ratio of block copolymer to aluminum powder, glass fiber and silicate microspheres is in the range of about 3:7 to about 3:2, the weight ratio of block copolymer to glass fiber is at least about 2:1, the weight ratio of glass fiber to aluminum powder is at least about 1:9 and wherein the volume percentage of silicate microspheres is less than about 10.
Inventors
- 👤 Donald D. Donermeyer
- 👤 Joseph G. Martins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 20:49
CPC Classifications
C; C09; C09J; C09J177/00; C09J177/12; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C09J167/00; C09J167/02; C09J5/00; C09J5/06; C08L; C08L2666/00; C08L2666/54
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
185 words
A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition below its crystallization temperature and sanding the adhesive composition to provide a surface even with the surrounding substrate, wherein the adhesive composition comprises a block copolymer, aluminum powder, glass fiber and hollow inorganic silicate microspheres, wherein the block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature of above about 150° C., having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments; wherein the weight ratio of block copolymerto aluminum powder, glass fiber and silicate microspheres is in the range of about 3:7 to about 3:2, wherein the weight ratio of block copolymer to glass fiber is at least about 2:1, wherein the weight ratio of glass fiber to aluminum powder is at least about 1:9 and wherein the volume percentage of silicate microspheres is less than about 10.
Claim 2
Independent Claim
185 words
A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition below its crystallization temperature and sanding the adhesive composition to provide a surface even with the surrounding substrate, wherein the adhesive composition comprises a block copolymer, aluminum powder, glass fiber and hollow inorganic silicate microspheres, wherein the block copolymer is selected from the group consisting of copolyesters, copolyamides, copoly(esteramides) and copoly(ether-esters) melting at a temperature of above about 150° C., having from about 30 to about 70 weight percent of hard segments and from about 70 to about 30 weight percent of soft segments; wherein the weight ratio of block copolymerto aluminum powder, glass fiber and silicate microspheres is in the range of about 3:7 to about 3:2, wherein the weight ratio of block copolymer to glass fiber is at least about 2:1, wherein the weight ratio of glass fiber to aluminum powder is at least about 1:9 and wherein the volume percentage of silicate microspheres is less than about 10.
Claim 3
Dependent Claim
240 words
The method of claim 1 wherein the hard segments of the block copolymer are polyester condensates of an aliphatic or alicyclic diol having from 2 to 10 carbon atoms and an alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms, or polyamide condensates of an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and an aliphatic or alicyclic dicarboxylic acid having from 2 to 12 carbon atoms, or polyamide condensates of an ω-aminocarboxylic acid having from 2 to 12 carbon atoms; and wherein the soft segments of the block copolymer are polyester condensates of an aliphatic or alicyclic diol having from 4 to 10 carbon atoms or a polylactone diol of molecular weight in the range of about 350 to 6000 and an aliphatic, alicyclic or aromatic dicarboxylic acid having from 4 to 54 carbon atoms, or poly(ether-ester) condensates of a poly(alkylene ether) glycol of molecular weight in the range of about 350 to about 6000 in which the alkylene groups have from 2 to 10 carbon atoms and an aliphatic, alicyclic or aromatic dicarboxylic acid having from 4 to 54 carbon atoms, or polyamide condensates of an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and a mixture of an aliphatic or alicyclic dicarboxylic acid having from 4 to 54 carbon atoms containing at least 40 weight percent of an aliphatic dicarboxylic acid having from 18 to 54 carbon atoms.
Claim 4
Dependent Claim
124 words
the method of claim 1 wherein the block copolymer is a copolyester wherein the hard segments are condensed from an aliphatic or alicyclic diol having from 2 to 10 carbon atoms and an alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms and the soft segments are condensed from an aliphatic or alicyclic diol having from 4 to 10 carbon atoms or a polylactone diol of molecular weight in the range of about 350 to about 6000 or a poly(alkylene ether) glycol of molecular weight in the range of about 350 to about 6000 in which the alkylene groups have from 2 to 10 carbon atoms and an aliphaticm alicyclic or aromatic dicarboxylic acid having from 6 to 54 carbon atoms.
Claim 5
Dependent Claim
110 words
The method of claim 1 wherein the block copolymer is a copolyamide wherein the hard segments are condensed from an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and an aliphatic or alicyclic discarboxylic acid having from 2 to 12 carbon atoms or from an ω-aminocarboxylic acid having from 2 to 12 carbon atoms and the soft segments are condensed from an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and a mixture of aliphatic and alicyclic dicarboxylic acids having from 4 to 54 carbon atoms containing at least 40 weight percent of an aliphatic dicarboxylic acid having from 18 to 54 carbon atoms.
Claim 6
Dependent Claim
98 words
The method of claim 1 wherein the block copolymer is a copoly(ester-amide) wherein the hard segments are condensed from an aliphatic or alicyclic diol having from 2 to 10 carbon atoms and an alicyclic or aromatic dicarboxylic acid having from 8 to 20 carbon atoms and the soft segments are condensed from an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and a mixture of aliphatic or alicyclic dicarboxylic acids having from 4 to 54 carbon atoms containing at least 40 weight percent of an aliphatic dicarboxylic acid having from 18 to 54 carbon atoms.
Claim 7
Dependent Claim
45 words
The method of claim 5 wherein the polyester is selected from the group consisting of poly(ethylene terephthalate), poly(tetramethylene terephthalate), co-poly(butylene terephthalate(-(ethylene terephthalate), co-poly(ethylene terephthalate)-(ethylene isophthalate), and copoly(ethylene terephthalate)-(propylene terephthalate) and wherein the polyamide segments are condensed from a C 36 dimer acid and hexamithylene diamine.
Claim 8
Dependent Claim
120 words
The method of claim 1 wherein the block copolymer is a copoly(ester-amide) wherein the hard segments are condensed from an aliphatic or alicyclic diamine having from 2 to 12 carbon atoms and an aliphatic or alicyclic dicarboxylic acid having from 2 to 12 carbon atoms or from an ω-aminocarboxylic acid having from 2 to 12 carbon atoms and the soft segments are condensed from an aliphatic or alicyclic diol having from 4 to 10 carbon atoms or a poly(alkylene ether) glycol of molecular weight in the range of about 350 to about 6000 in which the alkylene groups have from 2 to 10 carbon atoms and an aliphatic, alicyclic or aromatic dicarboxylic acid having from 6 to 54 carbon atoms,
Claim 9
Dependent Claim
31 words
The method of claim 1 wherein the adhesive composition has a melt viscosity at 250° C. of less than about 600,000 centipoise at a shear rate of 4 sec. -1 .
Claim 10
Dependent Claim
48 words
The method of claim 1, 5 or 7, wherein the hard segment prior to incorporation in the block copolymer has a weight average molecular weight in the range of about 400 to about 16,000 and a melting point in the range of about 180° to about 270° C.
Claim 11
Dependent Claim
38 words
The method of claim 9 wherein the block copolymer has a weight average molecular weight in the range of about 5500 to about 30,000 and a glass transition temperature in the range of about -30° to 40° C.
Claim 12
Dependent Claim
27 words
The method of claim 10 wherein the aluminum powder is spheroidal and has an average particle size in the range of about 0.2 to about 150 microns.
Claim 13
Dependent Claim
21 words
The method of claim 11 wherein the glass fiber is milled glass fiber of average length at least about 0.8 mm.
Claim 14
Dependent Claim
38 words
The method of claim 12 wherein the silicate microspheres comprise from about 2 to about 8 volume percent of the adhesive composition and are of averge particle size in the range of about 10 to about 150 microns.
Claim 15
Dependent Claim
27 words
The method of claim 10 wherein the aluminum powder is spheroidal and has an average particle size in the range of about 4 to about 50 microns.
Claim 16
Dependent Claim
21 words
The method of claim 14 wherein the glass fiber is milled glass fiber of average length at least about 0.8 mm.
Claim 17
Dependent Claim
38 words
The method of claim 15 wherein the silicate microspheres comprise from about 2 to about 8 volume percent of the adhesive composition and are of average particle size in the range of about 50 to about 100 microns.
Claim 18
Independent Claim
349 words
A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition below its crystallization temperature and sanding the adhesive composition to provide a surface even with the surrounding substrate, wherein the adhesive composition comprises: (a) a poly(ester-amide) block copolymer of weight aveage molecular weight in the range of about 5500 to about 30,000 and of melting point in the range of about 155° C. to about 225° C., having from about 30 to 70 percent by weight of hard polyester segments selected from the group consisting of poly(ethylene terephthalate), poly(tertramethylene terephthalate), co-poly(butylene terephthalate(-(ethylen terephthalate), co-poly(ethylene terephthalate(-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have a weight average molecular weight in the range of about 400 to about 16,000 and a melting point in the range of about 180 to about 270° C., and from about 70 to about 30 percent by weight of soft polyamide segments of glass transition temperature in the range of about -30° to 40° C., condensed from a C 18 to C 54 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms; (b) spheroidal aluminum powder of average particle size in the range of about 4 to about 50 microns; (c) milled glass fiber of average length in the range of about 1.6 mm to about 6.4 mm; and (d) hollow inorganic silicate microspheres of average particle size in the range of about 10 to about 150 microns; wherein the weight ratio of block copolymer to aluminum powder, glass fiber and silicate microspheres is in the range of about 1:2 to about 1:1, wherein the weight ratio of block copolymer to glass fiber is in the range of about 2:1 to about 10:1 wherein the weight ratio of glass fiber to aluminum powder is in the range of about 1:4 to about 1:1, and wherein the silicate microspheres comprise from about 2 to about 8 volume percent of the adhesive composition.
Claim 19
Independent Claim
349 words
A method of filling a cavity in a substrate which comprises applying excess adhesive composition as a hot melt into the cavity, spreading the adhesive composition to fill the cavity, cooling the adhesive composition below its crystallization temperature and sanding the adhesive composition to provide a surface even with the surrounding substrate, wherein the adhesive composition comprises: (a) a poly(ester-amide) block copolymer of weight aveage molecular weight in the range of about 5500 to about 30,000 and of melting point in the range of about 155° C. to about 225° C., having from about 30 to 70 percent by weight of hard polyester segments selected from the group consisting of poly(ethylene terephthalate), poly(tertramethylene terephthalate), co-poly(butylene terephthalate(-(ethylen terephthalate), co-poly(ethylene terephthalate(-(ethylene isophthalate) and co-poly(ethylene terephthalate)-(propylene terephthalate) which prior to incorporation in the poly(ester-amide), have a weight average molecular weight in the range of about 400 to about 16,000 and a melting point in the range of about 180 to about 270° C., and from about 70 to about 30 percent by weight of soft polyamide segments of glass transition temperature in the range of about -30° to 40° C., condensed from a C 18 to C 54 dibasic acid and an aliphatic or alicyclic diamine containing from 2 to 10 carbon atoms; (b) spheroidal aluminum powder of average particle size in the range of about 4 to about 50 microns; (c) milled glass fiber of average length in the range of about 1.6 mm to about 6.4 mm; and (d) hollow inorganic silicate microspheres of average particle size in the range of about 10 to about 150 microns; wherein the weight ratio of block copolymer to aluminum powder, glass fiber and silicate microspheres is in the range of about 1:2 to about 1:1, wherein the weight ratio of block copolymer to glass fiber is in the range of about 2:1 to about 10:1 wherein the weight ratio of glass fiber to aluminum powder is in the range of about 1:4 to about 1:1, and wherein the silicate microspheres comprise from about 2 to about 8 volume percent of the adhesive composition.
Claim 20
Dependent Claim
31 words
The method of claim 17 wherein the adhesive composition has a melt viscosity at 250° C. of less than about 600,000 centipoise at a shear rate of 4 sec. -1 .
Claim 21
Dependent Claim
21 words
The method of claim 17 wherein the dibasic acid is a C 36 dimer acid and the diamine is hexamethylene diamine.
Claim 22
Dependent Claim
13 words
The method of claim 19 wherein the crystalline polyester segments are poly(ethylene terephthalate).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-07-22 | 1984-01-21 | 1984-07-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-07-22 | 1988-01-21 | 1988-07-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-07-22 | 1992-01-21 | 1992-07-22 | $7700.00 | Window Closed / Lapsed |